Lithiation bridged molecular conducting magnets

Wang, Zhongxuan; Huang, Yulong; Gong, Weiyi; Yan, Qimin; Ren, Shenqiang

doi:10.1016/j.apmt.2024.102188

Title: Lithiation bridged molecular conducting magnets

Journal Article · 17 April 2024 · Applied Materials Today

DOI: https://doi.org/10.1016/j.apmt.2024.102188 · OSTI ID:2337762

^[1]; Huang, Yulong ^[2]; Gong, Weiyi ^[3]; Yan, Qimin ^[3];

^[2]

University of Maryland, College Park, MD (United States); University of Maryland
University of Maryland, College Park, MD (United States)
Northeastern University, Boston, MA (United States)

Combining ferromagnetism and metallic conductivity has been extensively studied in contemporary materials science. However, building such multifunctionalities in molecular chemistry is particularly challenging, on which two collective properties are long considered as mutually exclusive. Here, we report molecular conducting magnet consisting of two-dimensional graphene and molecular planar magnetic networks bridged by electrochemical lithiation, exhibiting the co-existence of distinct magnetism and conductivity and magneto-electric coupling effects. Here, the room temperature magnetoresistance and magnetoelectric coupling coefficient of such complex solid reach 10.7% and 1.77 V/Oe cm, respectively, which can be further tailored by modulating the interaction between graphene and molecular magnetic network. In addition, the graphene passivation simultaneously introduces environmental stability of molecular mag-nets. The electrochemical lithiation offers a pathway towards coupling magnetism and conductivity in molecular complexes.

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Research Organization:: University of Maryland, College Park, MD (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: SC0024796

OSTI ID:: 2337762

Journal Information:: Applied Materials Today, Journal Name: Applied Materials Today Vol. 38; ISSN 2352-9407

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (40)

Electrical Conductivity and Ferromagnetism in a Reduced Graphene–Metal Oxide Hybrid Karim, Mohammad Razaul; Shinoda, Hideaki; Nakai, Mina Advanced Functional Materials, Vol. 23, Issue 3 https://doi.org/10.1002/adfm.201201418	journal	August 2012
Reconfigurable Ferromagnetic Resonances by Engineering Inhomogeneous Magnetic Textures in Artificial Magnonic Crystals Ji, Lianze; Zhao, Rongzhi; Hu, Xin Advanced Functional Materials, Vol. 32, Issue 20 https://doi.org/10.1002/adfm.202112956	journal	February 2022
Voltage Tuning of Ferromagnetic Resonance with Bistable Magnetization Switching in Energy-Efficient Magnetoelectric Composites Liu, Ming; Zhou, Ziyao; Nan, Tianxiang Advanced Materials, Vol. 25, Issue 10 https://doi.org/10.1002/adma.201203792	journal	January 2013
Voltage-Impulse-Induced Non-Volatile Ferroelastic Switching of Ferromagnetic Resonance for Reconfigurable Magnetoelectric Microwave Devices Liu, Ming; Howe, Brandon M.; Grazulis, Lawrence Advanced Materials, Vol. 25, Issue 35 https://doi.org/10.1002/adma.201301989	journal	July 2013
Magnetic Proximity Effect in Graphene/CrBr ₃ van der Waals Heterostructures Tang, Chaolong; Zhang, Zhaowei; Lai, Shen Advanced Materials, Vol. 32, Issue 16 https://doi.org/10.1002/adma.201908498	journal	March 2020
Recent Progress in Graphene/Polymer Nanocomposites Sun, Xianxian; Huang, Chuanjin; Wang, Lidong Advanced Materials, Vol. 33, Issue 6 https://doi.org/10.1002/adma.202001105	journal	September 2020
Measuring disorder in graphene with the G and D bands Jorio, Ado; Ferreira, Erlon H. Martins; Moutinho, Marcus V. O. physica status solidi (b), Vol. 247, Issue 11-12 https://doi.org/10.1002/pssb.201000247	journal	August 2010
Two-dimensional bipolar magnetic semiconductors with high Curie-temperature and electrically controllable spin polarization realized in exfoliated Cr(pyrazine)2 monolayers Li, Xiangyang; Lv, Haifeng; Liu, Xiaofeng Science China Chemistry, Vol. 64, Issue 12 https://doi.org/10.1007/s11426-021-1160-7	journal	November 2021
Tunable positive magnetoresistance of magnetic polyaniline nanocomposites Guo, Jiang; Chen, Zhuoran; Abdul, Waras Advanced Composites and Hybrid Materials, Vol. 4, Issue 3 https://doi.org/10.1007/s42114-021-00242-z	journal	April 2021
Electric-field tunable rotation of optical mode ferromagnetic resonance in FeCoB/Ru/FeCoB/PMN-PT multilayers Zhou, Aoran; Li, Yuanzhe; Zhang, Shouheng Journal of Alloys and Compounds, Vol. 901 https://doi.org/10.1016/j.jallcom.2021.163475	journal	April 2022
Magnetic interaction in a 2D solid through hydrogen bonds and π-π stacking González M., M.; Osiry, H.; Martínez, M. Journal of Magnetism and Magnetic Materials, Vol. 471 https://doi.org/10.1016/j.jmmm.2018.09.058	journal	February 2019
Recent breakthroughs in two-dimensional van der Waals magnetic materials and emerging applications Khan, Yahya; Obaidulla, Sk. Md.; Habib, Mohammad Rezwan Nano Today, Vol. 34 https://doi.org/10.1016/j.nantod.2020.100902	journal	October 2020
Anatomy and Giant Enhancement of the Perpendicular Magnetic Anisotropy of Cobalt–Graphene Heterostructures Yang, Hongxin; Vu, Anh Duc; Hallal, Ali Nano Letters, Vol. 16, Issue 1 https://doi.org/10.1021/acs.nanolett.5b03392	journal	December 2015
Magnetic Molecular Conductors Coronado, Eugenio; Day, Peter Chemical Reviews, Vol. 104, Issue 11 https://doi.org/10.1021/cr030641n	journal	November 2004
4f−π Molecular Hybrid Exhibiting Rich Conductive Phases and Slow Relaxation of Magnetization Shen, Yongbing; Cosquer, Goulven; Zhang, Haitao Journal of the American Chemical Society, Vol. 143, Issue 25 https://doi.org/10.1021/jacs.1c03748	journal	June 2021
Controllable N-Doping of Graphene Guo, Beidou; Liu, Qian; Chen, Erdan Nano Letters, Vol. 10, Issue 12 https://doi.org/10.1021/nl103079j	journal	December 2010
Giant Current-Perpendicular-to-Plane Magnetoresistance in Multilayer Graphene as Grown on Nickel Bodepudi, S. C.; Singh, A. P.; Pramanik, S. Nano Letters, Vol. 14, Issue 5 https://doi.org/10.1021/nl4030853	journal	April 2014
Doped Graphene Sheets As Anode Materials with Superhigh Rate and Large Capacity for Lithium Ion Batteries Wu, Zhong-Shuai; Ren, Wencai; Xu, Li ACS Nano, Vol. 5, Issue 7 https://doi.org/10.1021/nn2006249	journal	June 2011
Synthesis of Graphene Sheets with High Electrical Conductivity and Good Thermal Stability by Hydrogen Arc Discharge Exfoliation Wu, Zhong-Shuai; Ren, Wencai; Gao, Libo ACS Nano, Vol. 3, Issue 2, p. 411-417 https://doi.org/10.1021/nn900020u	journal	February 2009
Coexistence of ferromagnetism and metallic conductivity in a molecule-based layered compound Coronado, Eugenio; Galán-Mascarós, José R.; Gómez-García, Carlos J. Nature, Vol. 408, Issue 6811 https://doi.org/10.1038/35044035	journal	November 2000
Coexistence of superconductivity and magnetism by chemical design Coronado, Eugenio; Martí-Gastaldo, Carlos; Navarro-Moratalla, Efrén Nature Chemistry, Vol. 2, Issue 12 https://doi.org/10.1038/nchem.898	journal	November 2010
Approaching the limits of transparency and conductivity in graphitic materials through lithium intercalation Bao, Wenzhong; Wan, Jiayu; Han, Xiaogang Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5224	journal	July 2014
Highly efficient spin transport in epitaxial graphene on SiC Dlubak, Bruno; Martin, Marie-Blandine; Deranlot, Cyrile Nature Physics, Vol. 8, Issue 7 https://doi.org/10.1038/nphys2331	journal	June 2012
Lithium intercalation into bilayer graphene Ji, Kemeng; Han, Jiuhui; Hirata, Akihiko Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-018-07942-z	journal	January 2019
Formation of the layered conductive magnet CrCl2(pyrazine)2 through redox-active coordination chemistry Pedersen, Kasper S.; Perlepe, Panagiota; Aubrey, Michael L. Nature Chemistry, Vol. 10, Issue 10 https://doi.org/10.1038/s41557-018-0107-7	journal	September 2018
Significant Dzyaloshinskii–Moriya interaction at graphene–ferromagnet interfaces due to the Rashba effect Yang, Hongxin; Chen, Gong; Cotta, Alexandre A. C. Nature Materials, Vol. 17, Issue 7 https://doi.org/10.1038/s41563-018-0079-4	journal	May 2018
A hard permanent magnet through molecular design Murphy, Ryan A.; Long, Jeffrey R.; David Harris, T. Communications Chemistry, Vol. 4, Issue 1 https://doi.org/10.1038/s42004-021-00509-y	journal	May 2021
Two-dimensional magnetic Janus monolayers and their van der Waals heterostructures: a review on recent progress Jiang, Jiawei; Mi, Wenbo Materials Horizons, Vol. 10, Issue 3 https://doi.org/10.1039/D2MH01362B	journal	January 2023
Graphene, the new nanocarbon Rao, C. N. R.; Biswas, Kanishka; Subrahmanyam, K. S. Journal of Materials Chemistry, Vol. 19, Issue 17 https://doi.org/10.1039/b815239j	journal	January 2009
Perpendicular magnetic anisotropy of cobalt films intercalated under graphene Rougemaille, N.; N'Diaye, A. T.; Coraux, J. Applied Physics Letters, Vol. 101, Issue 14 https://doi.org/10.1063/1.4749818	journal	October 2012
Spin-filtering, giant magnetoresistance, rectifying and negative differential resistance effects in planar four-coordinate Fe complex with graphene nanoribbon electrodes Zhao, P.; Wu, Q. H.; Liu, D. S. The Journal of Chemical Physics, Vol. 140, Issue 4 https://doi.org/10.1063/1.4862502	journal	January 2014
Raman spectroscopy of graphene and carbon nanotubes Saito, R.; Hofmann, M.; Dresselhaus, G. Advances in Physics, Vol. 60, Issue 3 https://doi.org/10.1080/00018732.2011.582251	journal	June 2011
On the Theory of Ferromagnetic Resonance Absorption Kittel, Charles Physical Review, Vol. 73, Issue 2 https://doi.org/10.1103/PhysRev.73.155	journal	January 1948
Surface-Acoustic-Wave Induced Ferromagnetic Resonance in Fe Thin Films and Magnetic Field Sensing Duquesne, J. -Y.; Rovillain, P.; Hepburn, C. Physical Review Applied, Vol. 12, Issue 2 https://doi.org/10.1103/PhysRevApplied.12.024042	journal	August 2019
Light-induced ferromagnetic resonance shift in magnetoelectric heterostructure Pathak, Pankaj; Kumar, Ajay; Mallick, Dhiman Physical Review Applied, Vol. 20, Issue 4 https://doi.org/10.1103/PhysRevApplied.20.044055	journal	October 2023
Tunneling Spin Injection into Single Layer Graphene Han, Wei; Pi, K.; McCreary, K. M. Physical Review Letters, Vol. 105, Issue 16 https://doi.org/10.1103/PhysRevLett.105.167202	journal	October 2010
Probing Phonon Dispersion Relations of Graphite by Double Resonance Raman Scattering Saito, R.; Jorio, A.; Souza Filho, A. G. Physical Review Letters, Vol. 88, Issue 2 https://doi.org/10.1103/PhysRevLett.88.027401	journal	December 2001
Graphite and Graphene as Perfect Spin Filters Karpan, V. M.; Giovannetti, G.; Khomyakov, P. A. Physical Review Letters, Vol. 99, Issue 17 https://doi.org/10.1103/PhysRevLett.99.176602	journal	October 2007
Metal-organic magnets with large coercivity and ordering temperatures up to 242°C Perlepe, Panagiota; Oyarzabal, Itziar; Mailman, Aaron Science, Vol. 370, Issue 6516 https://doi.org/10.1126/science.abb3861	journal	October 2020
Electrochemical Intercalation Behaviors of Lithium Ions into Graphene-Like Graphite Matsuo, Yoshiaki; Sasaki, Toshiyuki; Maruyama, Shunya Journal of The Electrochemical Society, Vol. 165, Issue 11 https://doi.org/10.1149/2.0131811jes	journal	January 2018

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