DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Halide Superionic Conductors for All-Solid-State Batteries: Effects of Synthesis and Composition on Lithium-Ion Conductivity

Journal Article · · ACS Energy Letters

Not Available

Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-05CH11231
OSTI ID:
2337564
Alternate ID(s):
OSTI ID: 2407300
Journal Information:
ACS Energy Letters, Journal Name: ACS Energy Letters Journal Issue: 5 Vol. 9; ISSN 2380-8195
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (55)

Review on solid electrolytes for all-solid-state lithium-ion batteries journal June 2018
Different interfacial reactivity of lithium metal chloride electrolytes with high voltage cathodes determines solid-state battery performance journal January 2022
Anomalous conductivity prefactors in fast ion conductors journal December 1983
Lithium Chlorides and Bromides as Promising Solid‐State Chemistries for Fast Ion Conductors with Good Electrochemical Stability journal June 2019
High-areal-capacity and long-cycle-life all-solid-state battery enabled by freeze drying technology journal January 2023
Lithium garnets: Synthesis, structure, Li + conductivity, Li + dynamics and applications journal July 2017
Thermodynamic optimization and calculation of the YCl3–ACl (A=Li, Na, K, Rb, Cs) phase diagrams journal December 2012
Tern�re Halogenide vom Typ A3MX6. VI [1]. Tern�re Chloride der Selten-Erd-Elemente mit Lithium, Li3MCl6 (M ? Tb?Lu, Y, Sc): Synthese, Kristallstrukturen und Ionenbewegung journal July 1997
An ultraconformal chemo-mechanical stable cathode interface for high-performance all-solid-state batteries at wide temperatures journal January 2023
Prospects of halide-based all-solid-state batteries: From material design to practical application journal September 2022
Electrochemically Stable Li3–xIn1–xHfxCl6 Halide Solid Electrolytes for All-Solid-State Batteries journal January 2023
Composite Cathode Design for High-Energy All-Solid-State Lithium Batteries with Long Cycle Life journal December 2022
Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries journal January 2020
Kinetically Stabilized Cation Arrangement in Li 3 YCl 6 Superionic Conductor during Solid‐State Reaction journal June 2021
Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction journal December 2015
Challenges in speeding up solid-state battery development journal February 2023
Emerging Halide Superionic Conductors for All-Solid-State Batteries: Design, Synthesis, and Practical Applications journal April 2022
The extraction of ionic conductivities and hopping rates from a.c. conductivity data journal October 1984
High areal capacity, long cycle life 4 V ceramic all-solid-state Li-ion batteries enabled by chloride solid electrolytes journal January 2022
The ‘universal’ dielectric response journal June 1977
Mobile ion concentrations in solid electrolytes from an analysis of a.c. conductivity journal December 1983
Heat treatment protocol for modulating ionic conductivity via structural evolution of Li3-xYb1-xMxCl6 (M = Hf4+, Zr4+) new halide superionic conductors for all-solid-state batteries journal December 2021
Interfaces in all solid state Li-metal batteries: A review on instabilities, stabilization strategies, and scalability journal March 2022
Insights into the Lithium Sub-structure of Superionic Conductors Li 3 YCl 6 and Li 3 YBr 6 journal January 2021
Temperature dependence of the a.c. conductivity of Naβ-alumina journal November 1982
First-principles formulation of spinel-like structured Li(4−3x)YxCl4 as promising solid-state electrolytes to enable superb lithium ion conductivity and matching oxidation potentials to high-voltage cathodes journal January 2021
Tailoring the Cation Lattice for Chloride Lithium‐Ion Conductors journal September 2020
On the origin of the universal dielectric response in condensed matter journal January 1979
Lithium Ytterbium-Based Halide Solid Electrolytes for High Voltage All-Solid-State Batteries journal June 2021
High-Voltage Superionic Halide Solid Electrolytes for All-Solid-State Li-Ion Batteries journal January 2020
Mechanochemical Synthesis: A Tool to Tune Cation Site Disorder and Ionic Transport Properties of Li 3 MCl 6 (M = Y, Er) Superionic Conductors journal December 2019
Enabling a Co-Free, High-Voltage LiNi0.5Mn1.5O4 Cathode in All-Solid-State Batteries with a Halide Electrolyte journal July 2022
Site-Occupation-Tuned Superionic Li x ScCl 3+ x Halide Solid Electrolytes for All-Solid-State Batteries journal March 2020
Editors’ Choice—Review—Designing Defects and Diffusion through Substitutions in Metal Halide Solid Electrolytes journal April 2022
Aging Property of Halide Solid Electrolyte at the Cathode Interface journal June 2023
Role of Interfaces in Solid‐State Batteries journal February 2023
Solid Halide Electrolytes with High Lithium-Ion Conductivity for Application in 4 V Class Bulk-Type All-Solid-State Batteries journal September 2018
Material Design Strategy for Halide Solid Electrolytes Li 3 MX 6 (X = Cl, Br, and I) for All-Solid-State High-Voltage Li-Ion Batteries journal May 2021
Single‐ or Poly‐Crystalline Ni‐Rich Layered Cathode, Sulfide or Halide Solid Electrolyte: Which Will be the Winners for All‐Solid‐State Batteries? journal April 2021
Unraveling Electrochemical Stability and Reversible Redox of Y-Doped Li 2 ZrCl 6 Solid Electrolytes journal January 2023
Stacking Faults Assist Lithium-Ion Conduction in a Halide-Based Superionic Conductor journal March 2022
Under pressure: offering fundamental insight into structural changes on ball milling battery materials journal January 2023
Design of a trigonal halide superionic conductor by regulating cation order-disorder journal November 2023
Neue schnelle Ionenleiter vom Typ MI3MIIICl6 (MI = Li, Na, Ag; MIII = In, Y) journal July 1992
Re-investigating the structure–property relationship of the solid electrolytes Li 3−xIn1−xZrxCl6 and the impact of In–Zr(iv) substitution journal January 2023
Hopping Rate and Migration Entropy as the Origin of Superionic Conduction within Solid-State Electrolytes journal May 2023
A LaCl3-based lithium superionic conductor compatible with lithium metal journal April 2023
Revealing the Pnma crystal structure and ion-transport mechanism of the Li3YCl6 solid electrolyte journal June 2023
New Insights into the Effects of Zr Substitution and Carbon Additive on Li3–xEr1–xZrxCl6 Halide Solid Electrolytes journal February 2022
A Series of Ternary Metal Chloride Superionic Conductors for High‐Performance All‐Solid‐State Lithium Batteries journal April 2022
Lithium-Ion Trapping from Local Structural Distortions in Sodium Super Ionic Conductor (NASICON) Electrolytes journal August 2014
The determination of hopping rates and carrier concentrations in ionic conductors by a new analysis of ac conductivity journal April 1983
A cost-effective and humidity-tolerant chloride solid electrolyte for lithium batteries journal July 2021
Fundamentals of inorganic solid-state electrolytes for batteries journal August 2019
Lithium battery chemistries enabled by solid-state electrolytes journal February 2017