Facet-dependent dispersion and aggregation of aqueous hematite nanoparticles

Zhou, Jianbin; Song, Duo; Mergelsberg, Sebastian T.; Wang, Yining; Adhikari, Narendra M.; Lahiri, Nabajit; Zhao, Yatong; Chen, Ping; Wang, Zheming; Zhang, Xin; Rosso, Kevin M.

doi:10.1126/sciadv.adi7494

Title: Facet-dependent dispersion and aggregation of aqueous hematite nanoparticles

Journal Article · 13 February 2024 · Science Advances

DOI: https://doi.org/10.1126/sciadv.adi7494 · OSTI ID:2336554

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Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Physical and Computational Sciences Directorate

Nanoparticle aggregates in solution controls surface reactivity and function. Complete dispersion often requires additive sorbents to impart a net repulsive interaction between particles. Facet engineering of nanocrystals offers an alternative approach to produce monodisperse suspensions simply based on facet-specific interaction with solvent molecules. Here, we measure the dispersion/aggregation of three morphologies of hematite (α-Fe₂O₃) nanoparticles in varied aqueous solutions using ex situ electron microscopy and in situ small-angle x-ray scattering. We demonstrate a unique tendency of (104) hematite nanoparticles to maintain a monodisperse state across a wide range of solution conditions not observed with (001)- and (116)-dominated particles. Density functional theory calculations reveal an inert, densely hydrogen-bonded first water layer on the (104) facet that favors interparticle dispersion. Results validate the notion that nanoparticle dispersions can be controlled through morphology for specific solvents, which may help in the development of various nanoparticle applications that rely on their interfacial area to be highly accessible in stable suspensions.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER); National Science Foundation (NSF); EU Horizon 2020; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: AC05-76RL01830; AC02-06CH11357; AC02-05CH11231

OSTI ID:: 2336554

Report Number(s):: PNNL-SA--192336

Journal Information:: Science Advances, Journal Name: Science Advances Journal Issue: 7 Vol. 10; ISSN 2375-2548

Publisher:: AAASCopyright Statement

Country of Publication:: United States

Language:: English

References (91)

Efficient pseudopotentials for plane-wave calculations Troullier, N.; Martins, José Luriaas Physical Review B, Vol. 43, Issue 3 https://doi.org/10.1103/PhysRevB.43.1993	journal	January 1991
Crystallization by particle attachment in synthetic, biogenic, and geologic environments De Yoreo, J. J.; Gilbert, P. U. P. A.; Sommerdijk, N. A. J. M. Science, Vol. 349, Issue 6247 https://doi.org/10.1126/science.aaa6760	journal	July 2015
STRUCTURAL BIOLOGY: Choosing the Crystallization Path Less Traveled Weiner, S. Science, Vol. 309, Issue 5737 https://doi.org/10.1126/science.1114920	journal	August 2005
Interactions of Dissolved Organic Matter with Natural and Engineered Inorganic Colloids: A Review Philippe, Allan; Schaumann, Gabriele E. Environmental Science & Technology, Vol. 48, Issue 16 https://doi.org/10.1021/es502342r	journal	August 2014
Ligand Customization and DNA Functionalization of Gold Nanorods via Round-Trip Phase Transfer Ligand Exchange Wijaya, Andy; Hamad-Schifferli, Kimberly Langmuir, Vol. 24, Issue 18 https://doi.org/10.1021/la8019205	journal	August 2008
Natural, incidental, and engineered nanomaterials and their impacts on the Earth system Hochella, Michael F.; Mogk, David W.; Ranville, James Science, Vol. 363, Issue 6434 https://doi.org/10.1126/science.aau8299	journal	March 2019
Stable colloids in molten inorganic salts Zhang, Hao; Dasbiswas, Kinjal; Ludwig, Nicholas B. Nature, Vol. 542, Issue 7641 https://doi.org/10.1038/nature21041	journal	February 2017
Dynamic Stabilization of Metal Oxide–Water Interfaces McBriarty, Martin E.; von Rudorff, Guido Falk; Stubbs, Joanne E. Journal of the American Chemical Society, Vol. 139, Issue 7 https://doi.org/10.1021/jacs.6b13096	journal	February 2017
Controllable synthesis of dual-MOFs nanostructures for pH-responsive artemisinin delivery, magnetic resonance and optical dual-model imaging-guided chemo/photothermal combinational cancer therapy Wang, Dongdong; Zhou, Jiajia; Chen, Ruhui Biomaterials, Vol. 100 https://doi.org/10.1016/j.biomaterials.2016.05.027	journal	September 2016
Small-Angle X-ray Scattering Study of Au Nanoparticles Dispersed in the Ionic Liquids 1-Alkyl-3-methylimidazolium Tetrafluoroborate Hatakeyama, Yoshikiyo; Okamoto, Maimi; Torimoto, Tsukasa The Journal of Physical Chemistry C, Vol. 113, Issue 10 https://doi.org/10.1021/jp807046u	journal	February 2009
Fast Interconversion of Hydrogen Bonding at the Hematite (001)–Liquid Water Interface von Rudorff, Guido Falk; Jakobsen, Rasmus; Rosso, Kevin M. The Journal of Physical Chemistry Letters, Vol. 7, Issue 7 https://doi.org/10.1021/acs.jpclett.6b00165	journal	March 2016
Efficacious Form for Model Pseudopotentials Kleinman, Leonard; Bylander, D. M. Physical Review Letters, Vol. 48, Issue 20 https://doi.org/10.1103/PhysRevLett.48.1425	journal	May 1982
Prediction of absolute crystal-nucleation rate in hard-sphere colloids Auer, Stefan; Frenkel, Daan Nature, Vol. 409, Issue 6823 https://doi.org/10.1038/35059035	journal	February 2001
Polyethylene glycol-based bidentate ligands to enhance quantum dot and gold nanoparticle stability in biological media Mei, Bing C.; Susumu, Kimihiro; Medintz, Igor L. Nature Protocols, Vol. 4, Issue 3 https://doi.org/10.1038/nprot.2008.243	journal	March 2009
Stability of Dispersions and Interactions in Nanostructured Fluids Hamad-Schifferli, Kimberly Colloidal Foundations of Nanoscience https://doi.org/10.1016/B978-0-444-59541-6.00002-3	book	March 2014
NWChem: Past, present, and future Aprà, E.; Bylaska, E. J.; de Jong, W. A. The Journal of Chemical Physics, Vol. 152, Issue 18 https://doi.org/10.1063/5.0004997	journal	May 2020
Toward Informed Design of Nanomaterials: A Mechanistic Analysis of Structure–Property–Function Relationships for Faceted Nanoscale Metal Oxides Rudel, Holly E.; Lane, Mary Kate M.; Muhich, Christopher L. ACS Nano, Vol. 14, Issue 12 https://doi.org/10.1021/acsnano.0c08356	journal	November 2020
Enhanced photoinduced catalytic activity of transition metal ions incorporated TiO2 nanoparticles for degradation of organic dye: Absorption and photoluminescence spectroscopy Singh, Mrityunjay Kumar; Mehata, Mohan Singh Optical Materials, Vol. 109 https://doi.org/10.1016/j.optmat.2020.110309	journal	November 2020
Generalized Gradient Approximation Made Simple [Phys. Rev. Lett. 77, 3865 (1996)] Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 78, Issue 7 https://doi.org/10.1103/PhysRevLett.78.1396	journal	February 1997
Connecting energetics to dynamics in particle growth by oriented attachment using real-time observations Liu, Lili; Nakouzi, Elias; Sushko, Maria L. Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-14719-w	journal	February 2020
Shape Dependence of Pressure-Induced Phase Transition in CdS Semiconductor Nanocrystals Meng, Lingyao; Lane, J. Matthew D.; Baca, Luke Journal of the American Chemical Society, Vol. 142, Issue 14 https://doi.org/10.1021/jacs.0c01906	journal	March 2020
Rutile facet-dependent fibrinogen conformation: Why crystallographic orientation matters Struczyńska, Maja; Firkowska-Boden, Izabela; Scheuer, Karl Colloids and Surfaces B: Biointerfaces, Vol. 215 https://doi.org/10.1016/j.colsurfb.2022.112506	journal	July 2022
Stable Liquid Water Droplet on a Water Monolayer Formed at Room Temperature on Ionic Model Substrates Wang, Chunlei; Lu, Hangjun; Wang, Zhigang Physical Review Letters, Vol. 103, Issue 13 https://doi.org/10.1103/PhysRevLett.103.137801	journal	September 2009
Thermodynamic modelling of nanomorphologies of hematite and goethite Guo, Haibo; Barnard, Amanda S. Journal of Materials Chemistry, Vol. 21, Issue 31 https://doi.org/10.1039/c1jm10381d	journal	January 2011
Evolution of the nitrogen cycle and its influence on the biological sequestration of CO2 in the ocean Falkowski, Paul G. Nature, Vol. 387, Issue 6630 https://doi.org/10.1038/387272a0	journal	May 1997
Generalized norm-conserving pseudopotentials Hamann, D. R. Physical Review B, Vol. 40, Issue 5 https://doi.org/10.1103/PhysRevB.40.2980	journal	August 1989
Superstructures of Functional Colloids: Chemistry on the Nanometer Scale Antonietti, Markus; Göltner, Christine Angewandte Chemie International Edition in English, Vol. 36, Issue 9 https://doi.org/10.1002/anie.199709101	journal	May 1997
First-principles calculation of the structure and magnetic phases of hematite Rollmann, G.; Rohrbach, A.; Entel, P. Physical Review B, Vol. 69, Issue 16 https://doi.org/10.1103/PhysRevB.69.165107	journal	April 2004
Protein Multilayer Formation on Colloids through a Stepwise Self-Assembly Technique Caruso, Frank; Möhwald, Helmuth Journal of the American Chemical Society, Vol. 121, Issue 25 https://doi.org/10.1021/ja990441m	journal	June 1999
BioXTAS RAW : improvements to a free open-source program for small-angle X-ray scattering data reduction and analysis Hopkins, Jesse Bennett; Gillilan, Richard E.; Skou, Soren Journal of Applied Crystallography, Vol. 50, Issue 5 https://doi.org/10.1107/S1600576717011438	journal	September 2017
Toward a Tetravalent Chemistry of Colloids Nelson, David R. Nano Letters, Vol. 2, Issue 10 https://doi.org/10.1021/nl0202096	journal	October 2002
Direction-specific van der Waals attraction between rutile TiO ₂ nanocrystals Zhang, Xin; He, Yang; Sushko, Maria L. Science, Vol. 356, Issue 6336 https://doi.org/10.1126/science.aah6902	journal	April 2017
Controlled colloidal metal nanoparticles and nanoclusters: recent applications as cocatalysts for improving photocatalytic water-splitting activity Kawawaki, Tokuhisa; Mori, Yutaro; Wakamatsu, Kosuke Journal of Materials Chemistry A, Vol. 8, Issue 32 https://doi.org/10.1039/D0TA04750C	journal	January 2020
Advanced hematite nanomaterials for newly emerging applications Wan, Hao; Hu, Linfeng; Liu, Xiaohe Chemical Science, Vol. 14, Issue 11 https://doi.org/10.1039/D3SC00180F	journal	January 2023
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu Grimme, Stefan; Antony, Jens; Ehrlich, Stephan The Journal of Chemical Physics, Vol. 132, Issue 15 https://doi.org/10.1063/1.3382344	journal	April 2010
Perspective: Fifty years of density-functional theory in chemical physics Becke, Axel D. The Journal of Chemical Physics, Vol. 140, Issue 18 https://doi.org/10.1063/1.4869598	journal	May 2014
Large-Scale Plane-Wave-Based Density Functional Theory: Formalism, Parallelization, and Applications Bylaska, Eric; Tsemekhman, Kiril; Govind, Niranjan Computational Methods for Large Systems: Electronic Structure Approaches for Biotechnology and Nanotechnology https://doi.org/10.1002/9780470930779.ch3	book	July 2011
Temperature effect on the stability of bentonite colloids in water García-García, Sandra; Jonsson, Mats; Wold, Susanna Journal of Colloid and Interface Science, Vol. 298, Issue 2 https://doi.org/10.1016/j.jcis.2006.01.018	journal	June 2006
Canonical dynamics: Equilibrium phase-space distributions Hoover, William G. Physical Review A, Vol. 31, Issue 3 https://doi.org/10.1103/PhysRevA.31.1695	journal	March 1985
Water Adsorption on α-Fe ₂ O ₃ (0001) at near Ambient Conditions Yamamoto, Susumu; Kendelewicz, Tom; Newberg, John T. The Journal of Physical Chemistry C, Vol. 114, Issue 5 https://doi.org/10.1021/jp909876t	journal	January 2010
Influence of a Terminal Functionality on the Physical Properties of Surfactant-Stabilized Gold Nanoparticles Johnson, S. R.; Evans, S. D.; Brydson, R. Langmuir, Vol. 14, Issue 23 https://doi.org/10.1021/la9711342	journal	November 1998
Surface Passivation of Luminescent Colloidal Quantum Dots with Poly(Dimethylaminoethyl methacrylate) through a Ligand Exchange Process Wang, Xiao-Song; Dykstra, Tieneke E.; Salvador, Mayrose R. Journal of the American Chemical Society, Vol. 126, Issue 25 https://doi.org/10.1021/ja0489339	journal	June 2004
Interfacial water structure on the (012) surface of hematite: Ordering and reactivity in comparison with corundum Catalano, Jeffrey G.; Fenter, Paul; Park, Changyong Geochimica et Cosmochimica Acta, Vol. 71, Issue 22 https://doi.org/10.1016/j.gca.2007.09.019	journal	November 2007
Perspective: How good is DFT for water? Gillan, Michael J.; Alfè, Dario; Michaelides, Angelos The Journal of Chemical Physics, Vol. 144, Issue 13 https://doi.org/10.1063/1.4944633	journal	April 2016
Chemical catalysis by colloids and clusters Lewis, L. N. Chemical Reviews, Vol. 93, Issue 8 https://doi.org/10.1021/cr00024a006	journal	December 1993
Unified Approach for Molecular Dynamics and Density-Functional Theory Car, R.; Parrinello, M. Physical Review Letters, Vol. 55, Issue 22 https://doi.org/10.1103/PhysRevLett.55.2471	journal	November 1985
Iron Vacancies Accommodate Uranyl Incorporation into Hematite McBriarty, Martin E.; Kerisit, Sebastien; Bylaska, Eric J. Environmental Science & Technology, Vol. 52, Issue 11 https://doi.org/10.1021/acs.est.8b00297	journal	May 2018
Surfactant Removal for Colloidal Nanoparticles from Solution Synthesis: The Effect on Catalytic Performance Li, Dongguo; Wang, Chao; Tripkovic, Dusan ACS Catalysis, Vol. 2, Issue 7 https://doi.org/10.1021/cs300219j	journal	June 2012
Parameters influencing the stealthiness of colloidal drug delivery systems Vonarbourg, Arnaud; Passirani, Catherine; Saulnier, Patrick Biomaterials, Vol. 27, Issue 24 https://doi.org/10.1016/j.biomaterials.2006.03.039	journal	August 2006
Weak interfacial water ordering on isostructural hematite and corundum (001) surfaces Catalano, Jeffrey G. Geochimica et Cosmochimica Acta, Vol. 75, Issue 8 https://doi.org/10.1016/j.gca.2011.01.025	journal	April 2011
Natural colloids and suspended particles in the Whiteshell Research Area, Manitoba, Canada, and their potential effect on radiocolloid formation Vilks, P.; Miller, H. G.; Doern, D. C. Applied Geochemistry, Vol. 6, Issue 5 https://doi.org/10.1016/0883-2927(91)90055-T	journal	January 1991
A unified formulation of the constant temperature molecular dynamics methods Nosé, Shuichi The Journal of Chemical Physics, Vol. 81, Issue 1 https://doi.org/10.1063/1.447334	journal	July 1984
Hematite(001)-liquid water interface from hybrid density functional-based molecular dynamics von Rudorff, Guido Falk; Jakobsen, Rasmus; Rosso, Kevin M. Journal of Physics: Condensed Matter, Vol. 28, Issue 39 https://doi.org/10.1088/0953-8984/28/39/394001	journal	July 2016
Adiabaticity in first-principles molecular dynamics Blöchl, Peter E.; Parrinello, M. Physical Review B, Vol. 45, Issue 16 https://doi.org/10.1103/PhysRevB.45.9413	journal	April 1992
Morphological Evolution and Magnetic Property of Rare‐Earth‐Doped Hematite Nanoparticles: Promising Contrast Agents for T1‐Weighted Magnetic Resonance Imaging Wan, Hao; Rong, Pengfei; Liu, Xiaohe Advanced Functional Materials, Vol. 27, Issue 27 https://doi.org/10.1002/adfm.201606821	journal	June 2017
Understanding Competitive Phosphate and Silicate Adsorption on Goethite by Connecting Batch Experiments with Density Functional Theory Calculations Chen, Ping; Song, Duo; Zhang, Xin Environmental Science & Technology, Vol. 56, Issue 2 https://doi.org/10.1021/acs.est.1c03629	journal	January 2022
NWChem: A comprehensive and scalable open-source solution for large scale molecular simulations Valiev, M.; Bylaska, E. J.; Govind, N. Computer Physics Communications, Vol. 181, Issue 9, p. 1477-1489 https://doi.org/10.1016/j.cpc.2010.04.018	journal	September 2010
Inorganic nanostructures for photoelectrochemical and photocatalytic water splitting Osterloh, Frank E. Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35266D	journal	January 2013
Density-functional theory and strong interactions: Orbital ordering in Mott-Hubbard insulators Liechtenstein, A. I.; Anisimov, V. I.; Zaanen, J. Physical Review B, Vol. 52, Issue 8 https://doi.org/10.1103/PhysRevB.52.R5467	journal	August 1995
Entropy-Mediated Patterning of Surfactant-Coated Nanoparticles and Surfaces Singh, Chetana; Ghorai, Pradip K.; Horsch, Mark A. Physical Review Letters, Vol. 99, Issue 22 https://doi.org/10.1103/PhysRevLett.99.226106	journal	November 2007
A review of dispersion modelling and its application to the dispersion of particles: An overview of different dispersion models available Holmes, N. S.; Morawska, L. Atmospheric Environment, Vol. 40, Issue 30 https://doi.org/10.1016/j.atmosenv.2006.06.003	journal	September 2006
Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites Murray, C. B.; Norris, D. J.; Bawendi, M. G. Journal of the American Chemical Society, Vol. 115, Issue 19, p. 8706-8715 https://doi.org/10.1021/ja00072a025	journal	September 1993
High-Throughput Screening of Silver Nanoparticle Stability and Bacterial Inactivation in Aquatic Media: Influence of Specific Ions Jin, Xue; Li, Minghua; Wang, Jinwen Environmental Science & Technology, Vol. 44, Issue 19 https://doi.org/10.1021/es100854g	journal	October 2010
Fully Dispersed IrO_x Atomic Clusters Enable Record Photoelectrochemical Water Oxidation of Hematite in Acidic Media Yuan, Shao-Yu; Jiang, Li-Wen; Hu, Jin-Song Nano Letters, Vol. 23, Issue 6 https://doi.org/10.1021/acs.nanolett.3c00245	journal	February 2023
Effect of crystal habits on the surface energy and cohesion of crystalline powders Shah, Umang V.; Olusanmi, Dolapo; Narang, Ajit S. International Journal of Pharmaceutics, Vol. 472, Issue 1-2 https://doi.org/10.1016/j.ijpharm.2014.06.014	journal	September 2014
Small Angle X-ray Scattering for Nanoparticle Research Li, Tao; Senesi, Andrew J.; Lee, Byeongdu Chemical Reviews, Vol. 116, Issue 18 https://doi.org/10.1021/acs.chemrev.5b00690	journal	April 2016
Kinetic pathways of crystallization at the nanoscale Ou, Zihao; Wang, Ziwei; Luo, Binbin Nature Materials, Vol. 19, Issue 4 https://doi.org/10.1038/s41563-019-0514-1	journal	October 2019
Boehmite and Gibbsite Nanoplates for the Synthesis of Advanced Alumina Products Zhang, Xin; Huestis, Patricia L.; Pearce, Carolyn I. ACS Applied Nano Materials, Vol. 1, Issue 12 https://doi.org/10.1021/acsanm.8b01969	journal	November 2018
The Stability of Silver Nanoparticles in a Model of Pulmonary Surfactant Leo, Bey Fen; Chen, Shu; Kyo, Yoshihiko Environmental Science & Technology, Vol. 47, Issue 19 https://doi.org/10.1021/es403377p	journal	September 2013
Determination of the regularization parameter in indirect-transform methods using perceptual criteria Svergun, D. I. Journal of Applied Crystallography, Vol. 25, Issue 4, p. 495-503 https://doi.org/10.1107/S0021889892001663	journal	August 1992
Synthesis of 2D Hexagonal Hematite Nanosheets and the Crystal Growth Mechanism Zong, Meirong; Zhang, Xin; Wang, Yining Inorganic Chemistry, Vol. 58, Issue 24 https://doi.org/10.1021/acs.inorgchem.9b02883	journal	November 2019
Irena : tool suite for modeling and analysis of small-angle scattering Ilavsky, Jan; Jemian, Peter R. Journal of Applied Crystallography, Vol. 42, Issue 2 https://doi.org/10.1107/S0021889809002222	journal	February 2009
Revisiting the Growth Mechanism of Hierarchical Semiconductor Nanostructures: The Role of Secondary Nucleation in Branch Formation Liu, Lili; Sushko, Maria L.; Buck, Edgar C. The Journal of Physical Chemistry Letters, Vol. 10, Issue 21 https://doi.org/10.1021/acs.jpclett.9b02110	journal	September 2019
Interplay between Facets and Defects during the Dissociative and Molecular Adsorption of Water on Metal Oxide Surfaces Lahiri, Nabajit; Song, Duo; Zhang, Xin Journal of the American Chemical Society, Vol. 145, Issue 5 https://doi.org/10.1021/jacs.2c11291	journal	January 2023
First Principles Estimation of Geochemically Important Transition Metal Oxide Properties Chen, Ying; Bylaska, Eric; Weare, John Molecular Modeling of Geochemical Reactions https://doi.org/10.1002/9781118845226.ch4	book	June 2016
Direction-specific interaction forces underlying zinc oxide crystal growth by oriented attachment Zhang, X.; Shen, Z.; Liu, J. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00844-6	journal	October 2017
Microemulsions, Micelles, and Functional Gels: How Colloids and Soft Matter Preserve Works of Art Chelazzi, David; Giorgi, Rodorico; Baglioni, Piero Angewandte Chemie International Edition, Vol. 57, Issue 25 https://doi.org/10.1002/anie.201710711	journal	March 2018
Multifunctional Inorganic Nanoparticles for Imaging, Targeting, and Drug Delivery Liong, Monty; Lu, Jie; Kovochich, Michael ACS Nano, Vol. 2, Issue 5 https://doi.org/10.1021/nn800072t	journal	May 2008
Applications of Colloidal Inorganic Nanoparticles: From Medicine to Energy Lohse, Samuel E.; Murphy, Catherine J. Journal of the American Chemical Society, Vol. 134, Issue 38 https://doi.org/10.1021/ja307589n	journal	September 2012
Oriented Gold Nanorod Arrays: Self-Assembly and Optoelectronic Applications Wei, Wenbo; Bai, Feng; Fan, Hongyou Angewandte Chemie International Edition, Vol. 58, Issue 35 https://doi.org/10.1002/anie.201902620	journal	June 2019
The calculation of small molecular interactions by the differences of separate total energies. Some procedures with reduced errors Boys, S.F.; Bernardi, F. Molecular Physics, Vol. 19, Issue 4, p. 553-566 https://doi.org/10.1080/00268977000101561	journal	October 1970
Particle-based hematite crystallization is invariant to initial particle morphology Wang, Yining; Xue, Sichuang; Lin, Qingyun Proceedings of the National Academy of Sciences, Vol. 119, Issue 11 https://doi.org/10.1073/pnas.2112679119	journal	March 2022
Heterogeneous photo-Fenton reaction on hematite (α-Fe ₂ O ₃ ){104}, {113} and {001} surface facets Chan, J. Y. T.; Ang, S. Y.; Ye, E. Y. Physical Chemistry Chemical Physics, Vol. 17, Issue 38 https://doi.org/10.1039/C5CP03332B	journal	January 2015
Growth, stability, optical and photoluminescent properties of aqueous colloidal ZnS nanoparticles in relation to surfactant molecular structure Mehta, S. K.; Kumar, Sanjay; Gradzielski, Michael Journal of Colloid and Interface Science, Vol. 360, Issue 2 https://doi.org/10.1016/j.jcis.2011.04.079	journal	August 2011
Surface potentials of (001), (012), (113) hematite (α-Fe2O3) crystal faces in aqueous solution Chatman, Shawn; Zarzycki, Piotr; Rosso, Kevin M. Physical Chemistry Chemical Physics, Vol. 15, Issue 33 https://doi.org/10.1039/c3cp52592a	journal	January 2013
Self-assembled single-atom nanozyme for enhanced photodynamic therapy treatment of tumor Wang, Dongdong; Wu, Huihui; Phua, Soo Zeng Fiona Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-019-14199-7	journal	January 2020
Erratum: The surface science of nanocrystals Boles, Michael A.; Ling, Daishun; Hyeon, Taeghwan Nature Materials, Vol. 15, Issue 3 https://doi.org/10.1038/nmat4578	journal	February 2016
Structure and reactivity of the hydrated hematite (0001) surface Trainor, Thomas P.; Chaka, Anne M.; Eng, Peter J. Surface Science, Vol. 573, Issue 2 https://doi.org/10.1016/j.susc.2004.09.040	journal	December 2004
Facet-Specific Photocatalytic Degradation of Organics by Heterogeneous Fenton Chemistry on Hematite Nanoparticles Huang, Xiaopeng; Chen, Ying; Walter, Eric Environmental Science & Technology, Vol. 53, Issue 17 https://doi.org/10.1021/acs.est.9b02946	journal	August 2019
Characterization of natural colloids from a river and spring in a karstic basin Atteia, O.; Perret, D.; Adatte, T. Environmental Geology, Vol. 34, Issue 4 https://doi.org/10.1007/s002540050277	journal	June 1998
Monodisperse FePt Nanoparticles and Ferromagnetic FePt Nanocrystal Superlattices Sun, S. Science, Vol. 287, Issue 5460 https://doi.org/10.1126/science.287.5460.1989	journal	March 2000

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