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Title: Spectroscopic and thermodynamic characterization of a cobalt-verdazyl valence tautomeric system. influence of crystal structure, solvent and counterion

Journal Article · · Dalton Transactions
DOI: https://doi.org/10.1039/D4DT00465E · OSTI ID:2335969
ORCiD logo [1];  [1];  [1]; ORCiD logo [2];  [2]
  1. Department of Chemistry, San Jose State University, San Jose, CA 95192, USA
  2. ALBA Synchrotron Light Source, E-08290 Cerdanyola del Vallès, Barcelona, Spain
+ Show Author Affiliations

Valence tautomerization in the cobalt bis verdazyl system [Co(dipyvd) 2 ] 2+ is associated with large ligand geometry changes. As a result the equilibrium is strongly dependent on intermolecular interaction in both solid and solution phases.

Sponsoring Organization:
USDOE
Grant/Contract Number:
NONE; AC02-76SF00515
OSTI ID:
2335969
Journal Information:
Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 17 Vol. 53; ISSN 1477-9226; ISSN ICHBD9
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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