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Title: Site specific redox properties in ligand differentiated di-nickel complexes inspired by the acetyl CoA synthase active site

Journal Article · · Dalton Transactions
DOI: https://doi.org/10.1039/D4DT00306C · OSTI ID:2335831
 [1]; ORCiD logo [1];  [1];  [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of Chemistry, Texas A & M University, College Station, Texas 77843, USA
+ Show Author Affiliations

These complexes, comprised of Ni(N 2 S 2 )–Ni(dithiolene) S-bridged units, serve as a platform to interrogate the positions of added electrons. Tuning of the ligand substituents controls electron uptake in S-bridged dinickel complexes.

Sponsoring Organization:
USDOE
Grant/Contract Number:
NONE; SC0023353
OSTI ID:
2335831
Journal Information:
Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 17 Vol. 53; ISSN 1477-9226; ISSN ICHBD9
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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  • The Journal of Physical Chemistry B, Vol. 113, Issue 18, p. 6378-6396 https://doi.org/10.1021/jp810292n
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