DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Impact of Surface Ligand Identity and Density on the Thermodynamics of H Atom Uptake at Polyoxovanadate-Alkoxide Surfaces

Journal Article · · Inorganic Chemistry

Not Available

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0023465
OSTI ID:
2335820
Alternate ID(s):
OSTI ID: 2339797
Journal Information:
Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 16 Vol. 63; ISSN 0020-1669
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (41)

Increasing Oxide Reducibility: The Role of Metal/Oxide Interfaces in the Formation of Oxygen Vacancies journal August 2017
Bonds over Electrons: Proton Coupled Electron Transfer at Solid–Solution Interfaces journal March 2023
Coordination compounds of polyoxovanadates with a hexametalate core. Chemical and structural characterization of [VV6O13[(OCH2)3CR]2]2-, [VV6O11(OH)2[(OCH2)3CR]2], [VIV4VV2O9(OH)4[(OCH2)3CR]2]2-, and [VIV6O7(OH)6](OCH2)3CR]2]2- journal June 1992
Perturbing the Copper(III)–Hydroxide Unit through Ligand Structural Variation journal December 2015
Coverage-Dependent Rate-Driving Force Relationships: Hydrogen Transfer from Cerium Oxide Nanoparticle Colloids journal November 2022
Solar Water Splitting Cells journal November 2010
Oxygen vacancies in transition metal and rare earth oxides: Current state of understanding and remaining challenges journal June 2007
Nanoparticles for Heterogeneous Catalysis: New Mechanistic Insights journal December 2012
Connecting Thermodynamics and Kinetics of Proton Coupled Electron Transfer at Polyoxovanadate Surfaces Using the Marcus Cross Relation journal September 2022
Selective Hydrogenation of Azobenzene to Hydrazobenzene via Proton-Coupled Electron Transfer from a Polyoxotungstate Cluster journal March 2024
Free Energies of Proton-Coupled Electron Transfer Reagents and Their Applications journal December 2021
Thermodynamics of Oxygen Activation by Macrocyclic Complexes of Rhodium journal November 2007
Practical Aspects of Cyclic Voltammetry: How to Estimate Reduction Potentials When Irreversibility Prevails journal January 2019
Predicting the Energetics of Hydrogen Intercalation in Metal Oxides Using Acid–Base Properties journal September 2020
Density‐functional thermochemistry. III. The role of exact exchange journal April 1993
Oxygen-Atom Defect Formation in Polyoxovanadate Clusters via Proton-Coupled Electron Transfer journal March 2022
Determining Proton-Coupled Standard Potentials and X–H Bond Dissociation Free Energies in Nonaqueous Solvents Using Open-Circuit Potential Measurements journal May 2020
Metal nanoparticles or metal oxide nanoparticles, an efficient and promising family of novel heterogeneous catalysts in organic synthesis journal January 2009
Mechanistic Implications of Proton Transfer Coupled to Electron Transfer journal October 2001
Atomically-precise colloidal nanoparticles of cerium dioxide journal November 2017
Manifesto on the Thermochemistry of Nanoscale Redox Reactions for Energy Conversion journal March 2019
Faceted metal and metal oxide nanoparticles: design, fabrication and catalysis journal January 2015
Decoding Proton-Coupled Electron Transfer with Potential–p K a Diagrams journal January 2017
The Sensitivity of Metal Oxide Electrocatalysis to Bulk Hydrogen Intercalation: Hydrogen Evolution on Tungsten Oxide journal March 2022
Physicochemical implications of surface alkylation of high-valent, Lindqvist-type polyoxovanadate-alkoxide clusters journal January 2021
Thermodynamics of Proton and Electron Transfer in Tetranuclear Clusters with Mn–OH 2 /OH Motifs Relevant to H 2 O Activation by the Oxygen Evolving Complex in Photosystem II journal July 2018
Proton-Coupled Electron Transfer at the Surface of Polyoxovanadate-Alkoxide Clusters journal June 2023
Properties of the oxo/aqua system (bpy)2(py)RuO2+/(bpy)2(py)Ru(OH2)2+ journal February 1981
Colloidal metal oxide nanocrystal catalysis by sustained chemically driven ligand displacement journal January 2016
Accelerated rates of proton coupled electron transfer to oxygen deficient polyoxovanadate–alkoxide clusters journal January 2023
Oxidation of Toluene by [(phen) 2 Mn(μ-O) 2 Mn(phen) 2 ] 4+ via Initial Hydride Abstraction journal December 1999
Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions
  • Marenich, Aleksandr V.; Cramer, Christopher J.; Truhlar, Donald G.
  • The Journal of Physical Chemistry B, Vol. 113, Issue 18, p. 6378-6396 https://doi.org/10.1021/jp810292n
journal May 2009
Nanostructured materials for applications in heterogeneous catalysis journal January 2013
Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications journal December 2010
Solvent Effects on the Oxidation of Ru IV O to ORu VI O by MnO 4 - . Hydrogen-Atom versus Oxygen-Atom Transfer journal October 2007
Proton-coupled electron transfer between [Ru(bpy)2(py)OH2]2+ and [Ru(bpy)2(py)O]2+. A solvent isotope effect (kH2O/kD2O) of 16.1 journal May 1981
Direct Determination of Equilibrium Potentials for Hydrogen Oxidation/Production by Open Circuit Potential Measurements in Acetonitrile journal June 2012
Concerted Multiproton–Multielectron Transfer for the Reduction of O2 to H2O with a Polyoxovanadate Cluster journal September 2021
Nanoparticle O–H Bond Dissociation Free Energies from Equilibrium Measurements of Cerium Oxide Colloids journal February 2021
Coupling Theory to Electrode Design for Electrocatalysis journal May 2019
Isolation of a Terminal Co(III)-Oxo Complex journal August 2018