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Title: Scanning Electrochemical Microscopy Reveals That Model Silicon Anodes Demonstrate Global Solid Electrolyte Interphase Passivation Degradation during Calendar Aging

Journal Article · · ACS Applied Materials and Interfaces
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [4]
  1. Power Sources Technology Group, Sandia National Laboratory, Albuquerque, New Mexico 5800, United States
  2. Materials Characterization and Performance Department, Sandia National Laboratory, Albuquerque, New Mexico 5800, United States
  3. Materials Science Center, National Renewable Energy Laboratory, Golden, Colorado 80401, United States
  4. Department of Chemistry, University of Utah, Salt Lake City, Utah 84112, United States, Kummer Institute Center for Resource Sustainability, Missouri University of Science and Technology, Rolla, Missouri 65409, United States
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Sponsoring Organization:
USDOE
OSTI ID:
2335419
Journal Information:
ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 15 Vol. 16; ISSN 1944-8244
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (38)

25th Anniversary Article: Understanding the Lithiation of Silicon and Other Alloying Anodes for Lithium-Ion Batteries journal August 2013
Surface and Interface Engineering of Silicon-Based Anode Materials for Lithium-Ion Batteries journal July 2017
Mechanical Property Evolution of Silicon Composite Electrodes Studied by Environmental Nanoindentation journal January 2018
Elucidating Degradation Mechanisms of Silicon‐graphite Electrodes in Lithium‐ion Batteries by Local Electrochemistry journal June 2023
Pitch Carbon‐coated Ultrasmall Si Nanoparticle Lithium‐ion Battery Anodes Exhibiting Reduced Reactivity with Carbonate‐based Electrolyte journal July 2023
Analytical Expressions for Quantitative Scanning Electrochemical Microscopy (SECM) journal January 2010
Practical considerations of Si-based anodes for lithium-ion battery applications journal August 2017
Recent progress of analysis techniques for silicon-based anode of lithium-ion batteries journal December 2017
Cycling strategies for optimizing silicon nanowires performance as negative electrode for lithium battery journal March 2015
Investigation of failure mechanisms in silicon based half cells during the first cycle by micro X-ray tomography and radiography journal July 2016
Modulating electrode utilization in lithium-ion cells with silicon-bearing anodes journal November 2020
Pouch cells with 15% silicon calendar-aged for 4 years journal May 2023
Scanning Electrochemical Microscopy: A Comprehensive Review of Experimental Parameters from 1989 to 2015 journal October 2016
Direct Determination of Solid-Electrolyte Interphase Thickness and Composition as a Function of State of Charge on a Silicon Anode journal August 2015
Silicon Anode Design for Lithium-Ion Batteries: Progress and Perspectives journal December 2017
Examining Effects of Negative to Positive Capacity Ratio in Three-Electrode Lithium-Ion Cells with Layered Oxide Cathode and Si Anode journal May 2022
Nonpassivated Silicon Anode Surface journal May 2020
Electrochemical Reactivity and Passivation of Silicon Thin-Film Electrodes in Organic Carbonate Electrolytes journal August 2020
Strain-Induced Lithium Losses in the Solid Electrolyte Interphase on Silicon Electrodes journal August 2017
Robust Solid/Electrolyte Interphase (SEI) Formation on Si Anodes Using Glyme-Based Electrolytes journal April 2021
Half-Cell Cumulative Efficiency Forecasts Full-Cell Capacity Retention in Lithium-Ion Batteries journal February 2021
Temperature-Dependent Solubility of Solid Electrolyte Interphase on Silicon Electrodes journal October 2019
The Effect of the SEI Layer Mechanical Deformation on the Passivity of a Si Anode in Organic Carbonate Electrolytes journal March 2023
Influence of Carbonate Solvents on Solid Electrolyte Interphase Composition over Si Electrodes Monitored by In Situ and Ex Situ Spectroscopies journal October 2021
General Method of Manipulating Formation, Composition, and Morphology of Solid-Electrolyte Interphases for Stable Li-Alloy Anodes journal November 2017
Size-Dependent Fracture of Silicon Nanoparticles During Lithiation journal January 2012
Electronic Origin for the Phase Transition from Amorphous Li x Si to Crystalline Li 15 Si 4 journal June 2013
Hierarchical porous silicon structures with extraordinary mechanical strength as high-performance lithium-ion battery anodes journal March 2020
Calendar aging of silicon-containing batteries journal September 2021
Determination of the Solid Electrolyte Interphase Structure Grown on a Silicon Electrode Using a Fluoroethylene Carbonate Additive journal July 2017
Understanding surface reactivity of Si electrodes in Li-ion batteries by in operando scanning electrochemical microscopy journal January 2016
Breathing and oscillating growth of solid-electrolyte-interphase upon electrochemical cycling journal January 2018
Artificial lithium fluoride surface coating on silicon negative electrodes for the inhibition of electrolyte decomposition in lithium-ion batteries: visualization of a solid electrolyte interphase using in situ AFM journal January 2018
Insights on the cycling behavior of a highly-prelithiated silicon–graphite electrode in lithium-ion cells journal February 2020
Electrochemical Characterization of SEI-Type Passivating Films Using Redox Shuttles journal January 2011
Effect of Temperature and FEC on Silicon Anode Heat Generation Measured by Isothermal Microcalorimetry journal November 2021
Investigation of the Passivation Properties of the Solid Electrolyte Interphase Using a Soluble Redox Couple journal January 2016
Chemical contributions to silicon anode calendar aging are dominant over mechanical contributions journal December 2023

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