DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Tetravalent Cerium Alkyl and Benzyl Complexes

Journal Article · · Journal of the American Chemical Society
 [1]; ORCiD logo [1];  [2]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]
  1. School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332-0400, United States
  2. Department of Chemistry, University of Washington, Seattle, Washington 98195, United States
  3. School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332-0400, United States, Nuclear and Radiological Engineering and Medical Physics Program, School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332-0400, United States, Physical Sciences Division, Pacific Northwest National Laboratory, Richland, Washington 99352, United States

Not Available

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0023455
OSTI ID:
2332913
Alternate ID(s):
OSTI ID: 2337876
Journal Information:
Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 15 Vol. 146; ISSN 0002-7863
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (67)

Unconventional Superconductivity in CeIrI n 5 and CeCoIn 5 : Specific Heat and Thermal Conductivity Studies journal May 2001
Photoreduction of cerium(IV) in octakis(isopropoxo)bis(2-propanol)dicerium. Characterization and structure of Ce4O(OPr-iso)13(iso-PrOH) journal May 1991
The electrochemical behavior of cerium(III/IV) complexes: Thermodynamics, kinetics and applications in synthesis journal February 2014
Two-Electron Oxidations at a Single Cerium Center journal September 2023
Synthesis, Electrochemical, and Computational Studies of Organocerium(III) Complexes with Ce–Aryl Sigma Bonds journal November 2022
Identification of Alkoxy Radicals as Hydrogen Atom Transfer Agents in Ce-Catalyzed C–H Functionalization journal December 2022
State Interaction Linear Response Time-Dependent Density Functional Theory with Perturbative Spin–Orbit Coupling: Benchmark and Perspectives journal February 2023
The chemical and physical properties of tetravalent lanthanides: Pr, Nd, Tb, and Dy journal January 2020
Homoleptic Imidophosphorane Stabilization of Tetravalent Cerium journal March 2019
Tuning Organocerium Electrochemical Potentials by Extending Tris(cyclopentadienyl) Scaffolds with Terminal Halogenido, Siloxy, and Alkoxy Ligands journal May 2021
Renaissance of Homogeneous Cerium Catalysts with Unique     Ce(IV/III) Couple: Redox-Mediated Organic Transformations Involving Homolysis of Ce(IV)–Ligand Covalent Bonds journal April 2021
Stabilization of Cerium(IV) in the Presence of an Iodide Ligand:  Remarkable Effects of Lewis Acidity on Valence State journal December 1999
Divergent Stabilities of Tetravalent Cerium, Uranium, and Neptunium Imidophosphorane Complexes** journal July 2023
Molecular Complex of Tb in the +4 Oxidation State journal June 2019
Accessing the +IV Oxidation State in Molecular Complexes of Praseodymium journal March 2020
Covalency in Lanthanides. An X-ray Absorption Spectroscopy and Density Functional Theory Study of LnCl 6 x ( x = 3, 2) journal February 2015
Giant spin–orbit effects on 1 H and 13 C NMR shifts for uranium( vi ) complexes revisited: role of the exchange–correlation response kernel, bonding analyses, and new predictions journal January 2016
Relativistic Heavy-Neighbor-Atom Effects on NMR Shifts: Concepts and Trends Across the Periodic Table journal June 2020
Elemental chalcogen reactions of a tetravalent uranium imidophosphorane complex: cleavage of dioxygen journal January 2022
Stabilization of the Oxidation State +IV in Siloxide‐Supported Terbium Compounds journal February 2020
Two-Electron Oxidative Atom Transfer at a Homoleptic, Tetravalent Uranium Complex journal April 2020
CeO 2 -based heterogeneous catalysts toward catalytic conversion of CO 2 journal January 2016
Density‐functional thermochemistry. III. The role of exact exchange journal April 1993
Structure, reactivity and luminescence studies of triphenylsiloxide complexes of tetravalent lanthanides journal January 2022
Isolation and redox reactivity of cerium complexes in four redox states journal January 2023
The duality of electron localization and covalency in lanthanide and actinide metallocenes journal January 2020
Organolanthanide Complexes Containing Ln–CH3 σ-bonds: Unexpectedly Similar Hydrolysis Rates for Trivalent and Tetravalent Organocerium journal November 2023
Facile Oxidation of Ce(III) to Ce(IV) Using Cu(I) Salts journal March 2024
Quantifying Actinide–Carbon Bond Covalency in a Uranyl–Aryl Complex Utilizing Solution 13C NMR Spectroscopy journal October 2023
Isolation and Characterization of Elusive Tetrabenzylthorium Complexes journal August 2023
Tetravalent Terbium Chelates: Stability Enhancement and Property Tuning journal October 2023
Structural distortion by alkali metal cations modulates the redox and electronic properties of Ce3+ imidophosphorane complexes journal January 2023
Photocatalytic C–H activation and the subtle role of chlorine radical complexation in reactivity journal May 2021
Addition-Elimination Reactions across the M−C Bond of Metal N-Heterocyclic Carbenes journal March 2010
The inverse-trans-influence in tetravalent lanthanide and actinide bis(carbene) complexes journal February 2017
In Pursuit of Homoleptic Actinide Alkyl Complexes journal June 2012
Isolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift journal March 2021
Relativistic Spin–Orbit Heavy Atom on the Light Atom NMR Chemical Shifts: General Trends Across the Periodic Table Explained journal April 2018
NMR‐spektroskopische Untersuchungen zur Konstitution von Benzyl‐ und 1‐Napthylmethyl‐Verbindungen des Titaniums, Zirconiums und Hafniums journal August 1987
Design, Isolation, and Spectroscopic Analysis of a Tetravalent Terbium Complex journal July 2019
Synthesis and Analysis of a Family of Cerium(IV) Halide and Pseudohalide Compounds journal May 2014
Highly Variable Zr–CH2–Ph Bond Angles in Tetrabenzylzirconium: Analysis of Benzyl Ligand Coordination Modes journal November 2012
Synthesis of Titanium, Zirconium, and Hafnium Complexes That Contain the [(MesitylN-o-C6H4)2O]2- Ligand journal May 2000
Giant Spin-Orbit Effects on NMR Shifts in Diamagnetic Actinide Complexes: Guiding the Search of Uranium(VI) Hydride Complexes in the Correct Spectral Range journal September 2012
High-Frequency and -Field Electron Paramagnetic Resonance Spectroscopic Analysis of Metal–Ligand Covalency in a 4f 7 Valence Series (Eu 2+ , Gd 3+ , and Tb 4+ ) journal June 2021
Comparison of tetravalent cerium and terbium ions in a conserved, homoleptic imidophosphorane ligand field journal January 2020
Emergence of comparable covalency in isostructural cerium( iv )– and uranium( iv )–carbon multiple bonds journal January 2016
13Ccarbene nuclear magnetic resonance chemical shift analysis confirms CeIVC double bonding in cerium(iv)–diphosphonioalkylidene complexes journal January 2024
Tripodal tris(siloxide) ligand supported trivalent rare-earth metal complexes and redox reactivity journal January 2023
High-Temperature Superconducting Phases in Cerium Superhydride with a T c up to 115 K below a Pressure of 1 Megabar journal September 2021
Antiferromagnetism and crystalline electric field excitations in tetragonal NaCeO 2 journal January 2021
Structure and dynamic behavior of solvated neopentyllithium monomers, dimers, and tetramers: proton, carbon-13 and lithium-6 NMR journal August 1990
Tuning Reactivity and Electronic Properties through Ligand Reorganization within a Cerium Heterobimetallic Framework journal December 2013
Tetravalent cerium carbene complexes journal January 2007
A tetravalent praseodymium complex with field-induced slow magnetic relaxation journal January 2024
Organopotassium‐Catalyzed Silylation of Benzylic C(sp3)−H Bonds journal June 2023
Ligand Control of Oxidation and Crystallographic Disorder in the Isolation of Hexavalent Uranium Mono-Oxo Complexes journal January 2023
Spectroscopic and electrochemical characterization of a Pr4+ imidophosphorane complex and the redox chemistry of Nd3+ and Dy3+ complexes journal January 2022
Multiwfn: A multifunctional wavefunction analyzer journal December 2011
How Do Spin-Orbit-Induced Heavy-Atom Effects on NMR Chemical Shifts Function? Validation of a Simple Analogy to Spin-Spin Coupling by Density Functional Theory (DFT) Calculations on Some Iodo Compounds journal January 1998
Cationic Zirconium Complexes that Contain Mesityl-Substituted Diamido/Donor Ligands. Decomposition via CH Activation and Its Influence on 1-Hexene Polymerization journal July 2001
The difficult search for organocerium( iv ) compounds journal January 2017
13 C NMR Shifts as an Indicator of U–C Bond Covalency in Uranium(VI) Acetylide Complexes: An Experimental and Computational Study journal March 2019
Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis journal July 2018
Synthesis, Electrochemistry, and Reactivity of Cerium(III/IV) Methylene-Bis-Phenolate Complexes journal April 2013
A Cerium(IV)-Carbon Multiple Bond journal October 2013
Fundamentals and Catalytic Applications of CeO 2 -Based Materials journal April 2016