Elucidating the Role of Reduction Kinetics in the Phase-Controlled Growth on Preformed Nanocrystal Seeds: A Case Study of Ru

Nguyen, Quynh N.; Kim, Eun Mi; Ding, Yong; Janssen, Annemieke; Wang, Chenxiao; Li, Kei Kwan; Kim, Junseok; Fichthorn, Kristen A.; Xia, Younan

doi:10.1021/jacs.4c01725

Title: Elucidating the Role of Reduction Kinetics in the Phase-Controlled Growth on Preformed Nanocrystal Seeds: A Case Study of Ru

Journal Article · 29 March 2024 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.4c01725 · OSTI ID:2331317

^[1]; Kim, Eun Mi ^[2]; Ding, Yong ^[3];

^[1];

^[1]; Li, Kei Kwan ^[1]; Kim, Junseok ^[2];

^[2];

^[4]

School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332, United States
Department of Chemical Engineering, The Pennsylvania State University, University Park, Pennsylvania 16803, United States
School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, United States
School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, Georgia 30332, United States, The Wallace H. Coulter Department of Biomedical Engineering, Georgia Institute of Technology and Emory University, Atlanta, Georgia 30332, United States

Not Available

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-07ER46414

OSTI ID:: 2331317

Alternate ID(s):: OSTI ID: 2345199; OSTI ID: 2395938

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 17 Vol. 146; ISSN 0002-7863

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (60)

Quantitative Analysis of Different Formation Modes of Platinum Nanocrystals Controlled by Ligand Chemistry Yin, Xi; Shi, Miao; Wu, Jianbo Nano Letters, Vol. 17, Issue 10 https://doi.org/10.1021/acs.nanolett.7b02751	journal	September 2017
Noble-Metal Nanocrystals with Controlled Shapes for Catalytic and Electrocatalytic Applications Shi, Yifeng; Lyu, Zhiheng; Zhao, Ming Chemical Reviews, Vol. 121, Issue 2 https://doi.org/10.1021/acs.chemrev.0c00454	journal	July 2020
On the role of surface diffusion in determining the shape or morphology of noble-metal nanocrystals Xia, X.; Xie, S.; Liu, M. Proceedings of the National Academy of Sciences, Vol. 110, Issue 17 https://doi.org/10.1073/pnas.1222109110	journal	April 2013
Chemical Insights into the Design and Development of Face-Centered Cubic Ruthenium Catalysts for Fischer–Tropsch Synthesis Li, Wei-Zhen; Liu, Jin-Xun; Gu, Jun Journal of the American Chemical Society, Vol. 139, Issue 6 https://doi.org/10.1021/jacs.6b10375	journal	February 2017
Use of Reduction Rate as a Quantitative Knob for Controlling the Twin Structure and Shape of Palladium Nanocrystals Wang, Yi; Peng, Hsin-Chieh; Liu, Jingyue Nano Letters, Vol. 15, Issue 2 https://doi.org/10.1021/acs.nanolett.5b00158	journal	January 2015
Shape‐Controlled Synthesis of Colloidal Metal Nanocrystals by Replicating the Surface Atomic Structure on the Seed Gilroy, Kyle D.; Yang, Xuan; Xie, Shuifen Advanced Materials, Vol. 30, Issue 25 https://doi.org/10.1002/adma.201706312	journal	April 2018
Closest Packing Polymorphism Interfaced Metastable Transition Metal for Efficient Hydrogen Evolution Tan, Xinyue; Geng, Shize; Ji, Yujin Advanced Materials, Vol. 32, Issue 40 https://doi.org/10.1002/adma.202002857	journal	August 2020
Facile Synthesis of Ru-Based Octahedral Nanocages with Ultrathin Walls in a Face-Centered Cubic Structure Zhao, Ming; Elnabawy, Ahmed O.; Vara, Madeline Chemistry of Materials, Vol. 29, Issue 21 https://doi.org/10.1021/acs.chemmater.7b03092	journal	October 2017
Robust Phase Control through Hetero-Seeded Epitaxial Growth for Face-Centered Cubic Pt@Ru Nanotetrahedrons with Superior Hydrogen Electro-Oxidation Activity Gu, Jun; Guo, Yu; Jiang, Ying-Ying The Journal of Physical Chemistry C, Vol. 119, Issue 31 https://doi.org/10.1021/acs.jpcc.5b04587	journal	July 2015
Phase-Selective Epitaxial Growth of Heterophase Nanostructures on Unconventional 2H-Pd Nanoparticles Ge, Yiyao; Huang, Zhiqi; Ling, Chongyi Journal of the American Chemical Society, Vol. 142, Issue 44 https://doi.org/10.1021/jacs.0c09461	journal	October 2020
Preparation of Au@Pd Core–Shell Nanorods with fcc-2H-fcc Heterophase for Highly Efficient Electrocatalytic Alcohol Oxidation Zhou, Xichen; Ma, Yangbo; Ge, Yiyao Journal of the American Chemical Society, Vol. 144, Issue 1 https://doi.org/10.1021/jacs.1c11313	journal	December 2021
Synthesis of hexagonal close-packed gold nanostructures Huang, Xiao; Li, Shaozhou; Huang, Yizhong Nature Communications, Vol. 2, Issue 1 https://doi.org/10.1038/ncomms1291	journal	April 2011
Observation of the Formation Processes of Hexagonal Close-packed and Face-centered Cubic Ru Nanoparticles Araki, Naoki; Kusada, Kohei; Yoshioka, Satoru Chemistry Letters, Vol. 48, Issue 9 https://doi.org/10.1246/cl.190338	journal	September 2019
Ru Nanoframes with an fcc Structure and Enhanced Catalytic Properties Ye, Haihang; Wang, Qingxiao; Catalano, Massimo Nano Letters, Vol. 16, Issue 4 https://doi.org/10.1021/acs.nanolett.6b00607	journal	March 2016
Ligand-Assisted Phase Engineering of Nanomaterials Yun, Qinbai; Ge, Yiyao; Huang, Biao Accounts of Chemical Research, Vol. 56, Issue 13 https://doi.org/10.1021/acs.accounts.3c00121	journal	June 2023
Tutorial on Powder X-ray Diffraction for Characterizing Nanoscale Materials Holder, Cameron F.; Schaak, Raymond E. ACS Nano, Vol. 13, Issue 7 https://doi.org/10.1021/acsnano.9b05157	journal	July 2019
Synthesis of Colloidal Metal Nanocrystals: A Comprehensive Review on the Reductants Rodrigues, Thenner S.; Zhao, Ming; Yang, Tung‐Han Chemistry – A European Journal, Vol. 24, Issue 64 https://doi.org/10.1002/chem.201802194	journal	July 2018
Ambient Synthesis of High-Quality Ruthenium Nanowires and the Morphology-Dependent Electrocatalytic Performance of Platinum-Decorated Ruthenium Nanowires and Nanoparticles in the Methanol Oxidation Reaction Koenigsmann, Christopher; Semple, Dara Bobb; Sutter, Eli ACS Applied Materials & Interfaces, Vol. 5, Issue 12 https://doi.org/10.1021/am4007462	journal	June 2013
Phase engineering of nanomaterials Chen, Ye; Lai, Zhuangchai; Zhang, Xiao Nature Reviews Chemistry, Vol. 4, Issue 5 https://doi.org/10.1038/s41570-020-0173-4	journal	April 2020
Kinetic Analysis of Thermal Decomposition of Unirradiated and γ-Irradiated Tris(ACEtylacetonato)-Ruthenium(III) [Ru(acac)₃] Mahfouz, R. M.; Siddiqui, M. R. H.; Al-Ahmari, Sh. A. Progress in Reaction Kinetics and Mechanism, Vol. 32, Issue 1 https://doi.org/10.3184/146867807X217337	journal	July 2007
Preparation of thin films of platinum group metals by pulsed MOCVD. II. Deposition of Ru layers Morozova, N. B.; Gelfond, N. V.; Semyannikov, P. P. Journal of Structural Chemistry, Vol. 53, Issue 4 https://doi.org/10.1134/S0022476612040154	journal	July 2012
Using Reduction Kinetics to Control and Predict the Outcome of a Colloidal Synthesis of Noble-Metal Nanocrystals Nguyen, Quynh N.; Chen, Ruhui; Lyu, Zhiheng Inorganic Chemistry, Vol. 60, Issue 7 https://doi.org/10.1021/acs.inorgchem.0c03576	journal	February 2021
Intermetallic Nanoparticles: Synthetic Control and Their Enhanced Electrocatalysis Li, Junrui; Sun, Shouheng Accounts of Chemical Research, Vol. 52, Issue 7 https://doi.org/10.1021/acs.accounts.9b00172	journal	March 2019
Ruthenium Nanoframes in the Face-Centered Cubic Phase: Facile Synthesis and Their Enhanced Catalytic Performance Zhao, Ming; Hood, Zachary D.; Vara, Madeline ACS Nano, Vol. 13, Issue 6 https://doi.org/10.1021/acsnano.9b02890	journal	May 2019
Charge self-regulation upon changing the oxidation state of transition metals in insulators Raebiger, Hannes; Lany, Stephan; Zunger, Alex Nature, Vol. 453, Issue 7196 https://doi.org/10.1038/nature07009	journal	June 2008
Surface and Interface Control in Nanoparticle Catalysis Xie, Chenlu; Niu, Zhiqiang; Kim, Dohyung Chemical Reviews, Vol. 120, Issue 2 https://doi.org/10.1021/acs.chemrev.9b00220	journal	October 2019
Three-Dimensional Branched and Faceted Gold-Ruthenium Nanoparticles: Using Nanostructure to Improve Stability in Oxygen Evolution Electrocatalysis Gloag, Lucy; Benedetti, Tania M.; Cheong, Soshan Angewandte Chemie International Edition, Vol. 57, Issue 32 https://doi.org/10.1002/anie.201806300	journal	July 2018
Size Effect of Ruthenium Nanoparticles in Catalytic Carbon Monoxide Oxidation Joo, Sang Hoon; Park, Jeong Y.; Renzas, J. Russell Nano Letters, Vol. 10, Issue 7 https://doi.org/10.1021/nl101700j	journal	July 2010
Controlling the Morphology of Rhodium Nanocrystals by Manipulating the Growth Kinetics with a Syringe Pump Zhang, Hui; Li, Weiyang; Jin, Mingshang Nano Letters, Vol. 11, Issue 2 https://doi.org/10.1021/nl104347j	journal	February 2011
Seed-Mediated Growth of Colloidal Metal Nanocrystals Xia, Younan; Gilroy, Kyle D.; Peng, Hsin-Chieh Angewandte Chemie International Edition, Vol. 56, Issue 1 https://doi.org/10.1002/anie.201604731	journal	December 2016
Facile Synthesis of Palladium‐Based Nanocrystals with Different Crystal Phases and a Comparison of Their Catalytic Properties Janssen, Annemieke; Pawlik, Veronica; von Rueden, Alexander D. Advanced Materials, Vol. 33, Issue 49 https://doi.org/10.1002/adma.202103801	journal	October 2021
Tests of functionals for systems with fractional electron number Vydrov, Oleg A.; Scuseria, Gustavo E.; Perdew, John P. The Journal of Chemical Physics, Vol. 126, Issue 15 https://doi.org/10.1063/1.2723119	journal	April 2007
Phase-Controlled Synthesis of Ru Nanocrystals via Template-Directed Growth: Surface Energy versus Bulk Energy Janssen, Annemieke; Lyu, Zhiheng; Figueras-Valls, Marc Nano Letters, Vol. 22, Issue 9 https://doi.org/10.1021/acs.nanolett.1c05009	journal	April 2022
Crystal Structure Control of CdSe Nanocrystals in Growth and Nucleation: Dominating Effects of Surface versus Interior Structure Gao, Yuan; Peng, Xiaogang Journal of the American Chemical Society, Vol. 136, Issue 18 https://doi.org/10.1021/ja5020025	journal	April 2014
Seed-Mediated Growth of Au Nanospheres into Hexagonal Stars and the Emergence of a Hexagonal Close-Packed Phase Huo, Da; Cao, Zhenming; Li, Jun Nano Letters, Vol. 19, Issue 5 https://doi.org/10.1021/acs.nanolett.9b00534	journal	March 2019
Strain and Surface Engineering of Multicomponent Metallic Nanomaterials with Unconventional Phases Yao, Qing; Yu, Zhiyong; Li, Leigang Chemical Reviews, Vol. 123, Issue 15 https://doi.org/10.1021/acs.chemrev.3c00252	journal	July 2023
Kinetically Controlled Synthesis of Rhodium Nanocrystals with Different Shapes and a Comparison Study of Their Thermal and Catalytic Properties Zhao, Ming; Chen, Zitao; Shi, Yifeng Journal of the American Chemical Society, Vol. 143, Issue 16 https://doi.org/10.1021/jacs.1c02734	journal	April 2021
Discovery of Face-Centered-Cubic Ruthenium Nanoparticles: Facile Size-Controlled Synthesis Using the Chemical Reduction Method Kusada, Kohei; Kobayashi, Hirokazu; Yamamoto, Tomokazu Journal of the American Chemical Society, Vol. 135, Issue 15 https://doi.org/10.1021/ja311261s	journal	April 2013
Toward a Quantitative Understanding of Crystal-Phase Engineering of Ru Nanocrystals Lin, Jui-Tai; Liu, Yi-Hong; Tsao, Chi-Yen Chemistry of Materials, Vol. 35, Issue 11 https://doi.org/10.1021/acs.chemmater.3c00326	journal	May 2023
Theoretical study of O adlayers on Ru(0001) Stampfl, C.; Scheffler, M. Physical Review B, Vol. 54, Issue 4 https://doi.org/10.1103/PhysRevB.54.2868	journal	July 1996
Cubic-Core Hexagonal-Branch Mechanism To Synthesize Bimetallic Branched and Faceted Pd–Ru Nanoparticles for Oxygen Evolution Reaction Electrocatalysis Gloag, Lucy; Benedetti, Tania M.; Cheong, Soshan Journal of the American Chemical Society, Vol. 140, Issue 40 https://doi.org/10.1021/jacs.8b09402	journal	September 2018
Synthesis and Characterization of Ru Cubic Nanocages with a Face-Centered Cubic Structure by Templating with Pd Nanocubes Zhao, Ming; Figueroa-Cosme, Legna; Elnabawy, Ahmed O. Nano Letters, Vol. 16, Issue 8 https://doi.org/10.1021/acs.nanolett.6b02795	journal	August 2016
Toward a Quantitative Understanding of the Reduction Pathways of a Salt Precursor in the Synthesis of Metal Nanocrystals Yang, Tung-Han; Peng, Hsin-Chieh; Zhou, Shan Nano Letters, Vol. 17, Issue 1 https://doi.org/10.1021/acs.nanolett.6b04151	journal	December 2016
Thermolysis of Ru(acac)3 supported on silica and alumina Plyuto, Yuri V.; V. Babich, Igor; Sharanda, Lyudmila F. Thermochimica Acta, Vol. 335, Issue 1-2 https://doi.org/10.1016/S0040-6031(99)00148-3	journal	September 1999
Synthesis of Ru Icosahedral Nanocages with a Face-Centered-Cubic Structure and Evaluation of Their Catalytic Properties Zhao, Ming; Xu, Lang; Vara, Madeline ACS Catalysis, Vol. 8, Issue 8 https://doi.org/10.1021/acscatal.8b00910	journal	May 2018
Colloidal Synthesis of Metal Nanocrystals: From Asymmetrical Growth to Symmetry Breaking Nguyen, Quynh N.; Wang, Chenxiao; Shang, Yuxin Chemical Reviews, Vol. 123, Issue 7 https://doi.org/10.1021/acs.chemrev.2c00468	journal	December 2022
Characterization of Structural and Electronic Transitions During Reduction and Oxidation of Ru(acac)₃ Flow Battery Electrolytes by using X‐ray Absorption Spectroscopy Kucharyson, Jonathan F.; Gaudet, Jason R.; Wyvratt, Brian M. ChemElectroChem, Vol. 3, Issue 11 https://doi.org/10.1002/celc.201600360	journal	August 2016
Phase Engineering of a Ruthenium Nanostructure toward High-Performance Bifunctional Hydrogen Catalysis Li, Leigang; Liu, Cheng; Liu, Shangheng ACS Nano, Vol. 16, Issue 9 https://doi.org/10.1021/acsnano.2c05776	journal	August 2022
Size- and shape-dependent catalytic performances of oxidation and reduction reactions on nanocatalysts Cao, Shaowen; Tao, Franklin (Feng); Tang, Yu Chemical Society Reviews, Vol. 45, Issue 17 https://doi.org/10.1039/C6CS00094K	journal	January 2016
Ru Octahedral Nanocrystals with a Face-Centered Cubic Structure, {111} Facets, Thermal Stability up to 400 °C, and Enhanced Catalytic Activity Zhao, Ming; Chen, Zitao; Lyu, Zhiheng Journal of the American Chemical Society, Vol. 141, Issue 17 https://doi.org/10.1021/jacs.9b01640	journal	April 2019
Autocatalytic surface reduction and its role in controlling seed-mediated growth of colloidal metal nanocrystals Yang, Tung-Han; Zhou, Shan; Gilroy, Kyle D. Proceedings of the National Academy of Sciences, Vol. 114, Issue 52 https://doi.org/10.1073/pnas.1713907114	journal	December 2017
Shape Control from Thermodynamic Growth Conditions: The Case of hcp Ruthenium Hourglass Nanocrystals Watt, John; Yu, Chenlong; Chang, Shery L. Y. Journal of the American Chemical Society, Vol. 135, Issue 2 https://doi.org/10.1021/ja311366k	journal	December 2012
Phase-Controlled Deposition of Ru on Pd Nanocrystal Templates: Effects of Particle Shape and Size Janssen, Annemieke; Nguyen, Quynh N.; Lyu, Zhiheng The Journal of Physical Chemistry C, Vol. 127, Issue 2 https://doi.org/10.1021/acs.jpcc.2c08825	journal	January 2023
The surface energy of metals Vitos, L.; Ruban, A. V.; Skriver, H. L. Surface Science, Vol. 411, Issue 1-2 https://doi.org/10.1016/S0039-6028(98)00363-X	journal	August 1998
Epitaxial growth of unusual 4H hexagonal Ir, Rh, Os, Ru and Cu nanostructures on 4H Au nanoribbons Fan, Zhanxi; Chen, Ye; Zhu, Yihan Chemical Science, Vol. 8, Issue 1 https://doi.org/10.1039/C6SC02953A	journal	January 2017
Ru Nanocrystals with Shape-Dependent Surface-Enhanced Raman Spectra and Catalytic Properties: Controlled Synthesis and DFT Calculations Yin, An-Xiang; Liu, Wen-Chi; Ke, Jun Journal of the American Chemical Society, Vol. 134, Issue 50 https://doi.org/10.1021/ja3090934	journal	December 2012
Modulating fcc and hcp Ruthenium on the Surface of Palladium–Copper Alloy through Tunable Lattice Mismatch Yao, Yancai; He, Dong Sheng; Lin, Yue Angewandte Chemie International Edition, Vol. 55, Issue 18 https://doi.org/10.1002/anie.201601016	journal	March 2016
Crystal-phase and surface-structure engineering of ruthenium nanocrystals Zhao, Ming; Xia, Younan Nature Reviews Materials, Vol. 5, Issue 6 https://doi.org/10.1038/s41578-020-0183-3	journal	March 2020
Template Synthesis of Noble Metal Nanocrystals with Unusual Crystal Structures and Their Catalytic Applications Fan, Zhanxi; Zhang, Hua Accounts of Chemical Research, Vol. 49, Issue 12 https://doi.org/10.1021/acs.accounts.6b00527	journal	November 2016
Colloidal Metal Nanocrystals with Metastable Crystal Structures Janssen, Annemieke; Nguyen, Quynh N.; Xia, Younan Angewandte Chemie International Edition, Vol. 60, Issue 22 https://doi.org/10.1002/anie.202017076	journal	February 2021

Similar Records

A VO-seeded Approach for the Growth of Star-shaped VO2 and V2O5 Nanocrystals: Facile Synthesis Structural Characterization and Elucidation of Electronic Structure

Journal Article · 2011 · CrystEngComm · OSTI ID:1042251

Whittaker, L; Velazquez, J; Banerjee, S

Theoretical Perspectives on the Influence of Solution-Phase Additives in Shape-Controlled Nanocrystal Synthesis

Journal Article · 2018 · Journal of Physical Chemistry. C · OSTI ID:1539242

Qi, Xin; Balankura, Tonnam; Fichthorn, Kristen A.

Theory of the thermodynamic influence of solution-phase additives in shape-controlled nanocrystal synthesis

Journal Article · 2017 · Nanoscale · OSTI ID:1539946

Qi, Xin; Fichthorn, Kristen A.

Title: Elucidating the Role of Reduction Kinetics in the Phase-Controlled Growth on Preformed Nanocrystal Seeds: A Case Study of Ru

Citation Formats

References (60)

Similar Records

Related Subjects