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Title: Coordination of copper within a crystalline carbon nitride and its catalytic reduction of CO 2

Journal Article · · Dalton Transactions
DOI: https://doi.org/10.1039/D4DT00359D · OSTI ID:2329342
 [1];  [1];  [1];  [1];  [2];  [1];  [2];  [1];  [3]; ORCiD logo [4];  [5]; ORCiD logo [5];  [4];  [4];  [3]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [1]
  1. North Carolina State University, Department of Chemistry, Raleigh, NC 27695, USA
  2. North Carolina State University, Department of Chemical Engineering, Raleigh, NC 27695, USA
  3. University of North Carolina-Chapel Hill, Department of Chemistry, Chapel Hill, NC 27599, USA, University of North Carolina-Chapel Hill, Departments of Physics and Astronomy, Chapel Hill, NC 27599, USA
  4. University of North Carolina-Chapel Hill, Department of Chemistry, Chapel Hill, NC 27599, USA
  5. Yale University, Department of Chemistry, New Haven, CT 06520, USA
+ Show Author Affiliations

Crystallites of Cu-coordinated poly(triazine imide) were synthesized by flux methods and deposited from particle suspensions onto electrodes, yielding sizable current densities for the electrocatalytic reduction of CO 2 .

Sponsoring Organization:
USDOE
Grant/Contract Number:
NONE; SC0021173
OSTI ID:
2329342
Journal Information:
Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 15 Vol. 53; ISSN 1477-9226; ISSN ICHBD9
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (38)

Influence of the Metal Center in M–N–C Catalysts on the CO 2 Reduction Reaction on Gas Diffusion Electrodes journal April 2021
Special points for Brillouin-zone integrations journal June 1976
Calculation of One-Electron Redox Potentials Revisited. Is It Possible to Calculate Accurate Potentials with Density Functional Methods? journal June 2009
Photoelectrochemical Reduction of Carbon Dioxide with a Copper Graphitic Carbon Nitride Photocathode journal July 2021
Electrochemical reduction of CO2 at metal-porphyrin supported gas diffusion electrodes under high pressure CO2 journal June 1999
Energy‐adjusted a b i n i t i o pseudopotentials for the first row transition elements journal January 1987
Unveiling the complex configurational landscape of the intralayer cavities in a crystalline carbon nitride journal January 2022
Poly(triazine imide) with Intercalation of Lithium and Chloride Ions [(C 3 N 3 ) 2 (NH x Li 1− x ) 3 ⋅LiCl]: A Crystalline 2D Carbon Nitride Network journal February 2011
Determination of Crystal Structure of Graphitic Carbon Nitride: Ab Initio Evolutionary Search and Experimental Validation journal March 2017
Progress and Perspectives of Electrochemical CO 2 Reduction on Copper in Aqueous Electrolyte journal April 2019
Spatial confinement of copper single atoms into covalent triazine-based frameworks for highly efficient and selective photocatalytic CO2 reduction journal June 2022
Fast hybrid density-functional computations using plane-wave basis sets journal February 2019
Rationale for mixing exact exchange with density functional approximations journal December 1996
Optimized norm-conserving Vanderbilt pseudopotentials journal August 2013
A brief review of electrocatalytic reduction of CO 2 —Materials, reaction conditions, and devices journal June 2021
Continuous surface charge polarizable continuum models of solvation. I. General formalism journal March 2010
Contracted Gaussian basis sets for molecular calculations. I. Second row atoms, Z=11–18 journal May 1980
Electrochemical CO 2 Reduction: Recent Advances and Current Trends journal September 2014
Development of Molecular Electrocatalysts for CO2 Reduction and H2 Production/Oxidation journal December 2009
A Tour‐Guide through Carbon Nitride‐Land: Structure‐ and Dimensionality‐Dependent Properties for Photo(Electro)Chemical Energy Conversion and Storage journal July 2021
Electronic excitations: density-functional versus many-body Green’s-function approaches journal June 2002
Discovery of a Hybrid System for Photocatalytic CO2 Reduction via Attachment of a Molecular Cobalt-Quaterpyridine Complex to a Crystalline Carbon Nitride journal October 2023
BerkeleyGW: A massively parallel computer package for the calculation of the quasiparticle and optical properties of materials and nanostructures journal June 2012
Unraveling the Structure of the Poly(triazine imide)/LiCl Photocatalyst: Cooperation of Facile Syntheses and a Low-Temperature Synchrotron Approach journal November 2019
Crystalline Carbon Nitride Supported Copper Single Atoms for Photocatalytic CO 2 Reduction with Nearly 100% CO Selectivity journal July 2020
Copper and platinum dual-single-atoms supported on crystalline graphitic carbon nitride for enhanced photocatalytic CO2 reduction journal February 2022
Self‐consistent molecular orbital methods. XX. A basis set for correlated wave functions journal January 1980
Dual‐Single‐Atom Tailoring with Bifunctional Integration for High‐Performance CO2 Photoreduction journal October 2021
Electrochemical Reduction of CO 2 on Metal-Nitrogen-Doped Carbon Catalysts journal June 2019
A review on fundamentals and applications of electrophoretic deposition (EPD) journal January 2007
Carbon nitride embedded with transition metals for selective electrocatalytic CO2 reduction journal July 2020
Solving the Hydrogen and Lithium Substructure of Poly(triazine imide)/LiCl Using NMR Crystallography journal October 2016
Electrophoretic Deposition of Carbon Nitride Layers for Photoelectrochemical Applications journal May 2016
Optimization algorithm for the generation of ONCV pseudopotentials journal November 2015
First-Principles Theory of Quasiparticles: Calculation of Band Gaps in Semiconductors and Insulators journal September 1985
Formation of an ion-free crystalline carbon nitride and its reversible intercalation with ionic species and molecular water journal January 2019
Electrochemical CO2 Reduction Catalyzed by Copper Molecular Complexes: The Influence of Ligand Structure journal April 2022
Advanced analysis of copper X-ray photoelectron spectra: Advanced analysis of copper X-ray photoelectron spectra journal May 2017

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