Stress and Curvature Effects in Layered 2D Ferroelectric CuInP2S6

Liu, Yongtao; Morozovska, Anna N.; Ghosh, Ayana; Kelley, Kyle P.; Eliseev, Eugene A.; Yao, Jinyuan; Liu, Ying; Kalinin, Sergei

doi:10.1021/acsnano.3c08603

Title: Stress and Curvature Effects in Layered 2D Ferroelectric CuInP₂S₆

Journal Article · 02 November 2023 · ACS Nano

DOI: https://doi.org/10.1021/acsnano.3c08603 · OSTI ID:2326314

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^[1]; Eliseev, Eugene A. ^[2];

^[3]; Liu, Ying ^[3]; Kalinin, Sergei ^[4]

Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
National Academy of Sciences of Ukraine (NASU), Kyiv (Ukraine)
Pennsylvania State Univ., University Park, PA (United States)
Univ. of Tennessee, Knoxville, TN (United States)

Nanoscale ferroelectric 2D materials offer the opportunity to investigate curvature and strain effects on materials functionalities. Among these, CuInP₂S₆ (CIPS) has attracted tremendous research interest in recent years due to combination of room temperature ferroelectricity, scalability to a few layers thickness, and ferrielectric properties due to coexistence of 2 polar sublattices. Here, we explore the local curvature and strain effect on polarization in CIPS via piezoresponse force microscopy and spectroscopy. To explain the observed behaviors and decouple the curvature and strain effects in 2D CIPS, we introduce the finite element Landau–Ginzburg–Devonshire model, revealing strong changes in hysteresis characteristics in regions subjected to tensile and compressive strain. The piezoresponse force microscopy (PFM) results show that bending induces ferrielectric domains in CIPS, and the polarization-voltage hysteresis loops differ in bending and nonbending regions. Furthermore, these studies offer insights into the fabrication of curvature-engineered nanoelectronic devices.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Pennsylvania State Univ., University Park, PA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF); National Science Foundation (NSF)

Grant/Contract Number:: AC05-00OR22725; SC0021118; DMR-1539916; DMR-2039351

OSTI ID:: 2326314

Alternate ID(s):: OSTI ID: 2229373

Journal Information:: ACS Nano, Vol. 17, Issue 21; ISSN 1936-0851

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CuInP2S6
ferroelectric
flexoelectric
strain
curvature
2D materials
piezoresponse force microscopy
electric fields
layers
phase transition
polarization
stress

Title: Stress and Curvature Effects in Layered 2D Ferroelectric CuInP2S6

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References (45)

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Title: Stress and Curvature Effects in Layered 2D Ferroelectric CuInP₂S₆