Time-resolved quantification of key species and mechanistic insights in low-temperature tetrahydrofuran oxidation

Demireva, Maria; Au, Kendrew; Hansen, Nils; Sheps, Leonid

doi:10.1039/D3CP06227A

Title: Time-resolved quantification of key species and mechanistic insights in low-temperature tetrahydrofuran oxidation

Journal Article · 26 March 2024 · Physical Chemistry Chemical Physics. PCCP

DOI: https://doi.org/10.1039/D3CP06227A · OSTI ID:2325539

^[1]; Au, Kendrew ^[1];

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Combustion Research Facility, Sandia National Laboratories, Livermore, California 94551, USA

Time-resolved photoionization mass spectrometry quantifies key reaction intermediates in tetrahydrofuran oxidation. Comparison with simulations reveals the critical role of competing isomerization and bond scission reactions of ROO, QOOH, and OOQOOH.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; AC02-05CH11231

OSTI ID:: 2325539

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Issue: 13 Vol. 26; ISSN 1463-9076; ISSN PPCPFQ

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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