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Title: A novel digital lifecycle for Material‐Process‐Microstructure‐Performance relationships of thermoplastic olefins foams manufactured via supercritical fluid assisted foam injection molding

Journal Article · · Polymer Engineering and Science
DOI: https://doi.org/10.1002/pen.26700 · OSTI ID:2324721
ORCiD logo [1]; ORCiD logo [2];  [3];  [4];  [4];  [5];  [6]; ORCiD logo [7]
  1. Center for Composite Materials University of Delaware Newark Delaware USA
  2. Center for Composite Materials University of Delaware Newark Delaware USA, Department of Mechanical Engineering University of Delaware Newark Delaware USA
  3. Center for Composite Materials University of Delaware Newark Delaware USA, Department of Materials Science and Engineering University of Delaware Newark Delaware USA
  4. Department of Automotive Engineering Clemson University Greenville South Carolina USA
  5. Polymers Center for Excellence Charlotte North Carolina USA
  6. Department of Mechanical Engineering Clemson University Clemson South Carolina USA
  7. Center for Composite Materials University of Delaware Newark Delaware USA, Department of Mechanical Engineering University of Delaware Newark Delaware USA, Department of Materials Science and Engineering University of Delaware Newark Delaware USA, Department of Chemical and Biomolecular Engineering University of Delaware Newark Delaware USA

Abstract This research significantly enhances the applicability of thermoplastic olefins (TPOs) in the automotive industry using supercritical N 2 as a physical foaming agent, effectively addressing the limitations of traditional chemical agents. It merges experimental results with simulations to establish detailed material‐process‐microstructure‐performance (MP2) relationships, targeting 5–20% weight reductions. This innovative approach labeled digital lifecycle (DLC) helps accurately predict tensile, flexural, and impact properties based on the foam microstructure, along with experimentally demonstrating improved paintability. The study combines process simulations with finite element models to develop a comprehensive digital model for accurately predicting mechanical properties. Our findings demonstrate a strong correlation between simulated and experimental data, with about a 5% error across various weight reduction targets, marking significant improvements over existing analytical models. This research highlights the efficacy of physical foaming agents in TPO enhancement and emphasizes the importance of integrating experimental and simulation methods to capture the underlying foaming mechanism to establish material‐process‐microstructure‐performance (MP2) relationships. Highlights Establishes a material‐process‐microstructure‐performance (MP2) for TPO foams Sustainably produces TPO foams using supercritical (ScF) N 2 with 20% lightweighting Shows enhanced paintability for TPO foam improved surface aesthetics Digital lifecycle (DLC) that predicts both foam microstructure and properties DLC maps process effects & microstructure onto FEA mesh for precise prediction

Sponsoring Organization:
USDOE
OSTI ID:
2324721
Journal Information:
Polymer Engineering and Science, Journal Name: Polymer Engineering and Science; ISSN 0032-3888
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
United States
Language:
English

References (36)

Development of high void fraction polylactide composite foams using injection molding: Mechanical and thermal insulation properties journal January 2014
Hydrostatic high strain rate loading response of closed-cell polymeric foams as a function of mass density journal December 2022
Analysis and Validation of Varied Simulation Parameters in the Context of Thermoplastic Foams and Special Injection Molding Processes journal April 2023
Occurrence of Surface Defects in TPO Injected Foam Parts journal July 2007
A novel technique in the foaming process of EPDM/PP via microwave radiation: the effect of blend compatibilization and additive encapsulation journal January 2016
Thermoplastic elastomers containing antimicrobial and antiviral additives for mobility applications journal August 2022
A novel method of producing lightweight microcellular injection molded parts with improved ductility and toughness journal January 2015
Influence of relative low gas counter pressure on melt foaming behavior and surface quality of molded parts in microcellular injection molding process journal March 2014
Automotive Applications of Plastics: Past, Present, and Future book September 2016
Experimental observation and modeling of fiber rotation and translation during foam injection molding of polymer composites journal September 2016
Micromechanical models for porous and cellular materials in linear elasticity and viscoelasticity journal April 2013
Overview and comparison of modelling methods for foams journal December 2020
Solubility measurements of N2 and CO2 in polypropylene and ethene/octene copolymer journal December 2006
Strategies for achieving ultra low-density polypropylene foams journal July 2002
Compressive behavior and deformation mechanisms of rigid polymeric foams: A review journal March 2023
Effect of Processing Parameters on the Mechanical Properties of Injection Molded Thermoplastic Polyolefin (TPO) Cellular Foams journal July 2008
Development and Application of a Reduced Thermal Expansion Polycarbonate/ABS Engineering Thermoplastic Blend for Automotive Exterior Body Panels conference February 1991
Theoretical evaluation of tensile and flexural moduli of structural polymer foams journal February 2014
Comparative study of chemical and physical foaming methods for injection-molded thermoplastic polyurethane journal June 2016
Experimental and numerical studies on the effects of pressure release rate on number density of bubbles and bubble growth in a polymeric foaming process journal July 2008
Elastic Properties of Hollow-Sphere-Reinforced Composites journal February 1970
Experiment and simulation of foaming injection molding of polypropylene/nano-calcium carbonate composites by supercritical carbon dioxide journal January 2016
Surface Defects of TPO Injected Foam Parts for Automotive Applications journal May 2007
The Relationship of Mold Temperatures and Swirl Marks on the Surface of Microcellular Plastics journal June 2005
Thermoplastic olefin/clay nanocomposites: Morphology and mechanical properties journal February 2004
Scratch resistance of mineral‐filled polypropylene materials journal April 2000
The effect of dispersed elastomer particle size on heterogeneous nucleation of TPO with N2 foaming journal August 2011
Microcellular Foam Injection Molding Process book March 2012
Thermoplastics Foams: An Automotive Perspective book June 2017
Enhancing cell nucleation of thermoplastic polyolefin foam blown with nitrogen journal August 2010
Balancing the toughness and strength in polypropylene composites journal October 2021
High-strength, flexible and cycling-stable piezo-resistive polymeric foams derived from thermoplastic polyurethane and multi-wall carbon nanotubes journal October 2020
Microcellular Injection Molding book July 2010
A novel method for improving the surface quality of microcellular injection molded parts journal March 2011
From gas release to foam synthesis, the second breath of blowing agents journal November 2020
Characterization and modeling of stain-rate-dependent behavior of polymeric foams journal February 2013