Title: Participation of electrochemically inserted protons in the hydrogen evolution reaction on tungsten oxides

Journal Article · · Chemical Science
DOI: https://doi.org/10.1039/D4SC00102H · OSTI ID:2323977

Tungsten oxides undergo a significant increase in their hydrogen evolution reaction activity upon proton-insertion coupled electron transfer.

Research Organization:
North Carolina State University, Raleigh, NC (United States); Stanford University, CA (United States); Univ. of Pittsburgh, PA (United States); University of Pittsburgh, PA (United States)
Sponsoring Organization:
National Science Foundation (NSF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-76SF00515; SC0020234; SC0023465
OSTI ID:
2323977
Journal Information:
Chemical Science, Journal Name: Chemical Science Journal Issue: 14 Vol. 15; ISSN 2041-6520; ISSN CSHCBM
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (74)

Intercalation Reaction of Molybdenum Trioxide Cathode for Rechargeable Ion Batteries journal April 2023
Hydrogen evolution reaction on Titanium and oxide‐covered titanium electrodes journal October 1991
The Renaissance of Proton Batteries journal February 2021
Kristallisierte Wolframblauverbindungen; Wasserstoffanaloga der Wolframbronzen HxWO3 journal July 1951
Voltametric behaviour of Ti n O2n−1 ceramic electrodes close to the hydrogen evolution reaction journal October 1993
Electrochemical and structural characteristics of tungstic acids as cathode materials for lithium batteries journal July 1989
Electrochemical characteristics and structural changes of molybdenum trioxide hydrates as cathode materials for lithium batteries journal November 1988
Hydrogen insertion compounds of transition metal oxides journal November 1981
Infrared and X-ray studies of hydrogen intercalation in different tungsten trioxides and tungsten trioxide hydrates journal November 1997
A study of hydrated nanostructured tungsten trioxide as an electroactive material for pseudocapacitors journal May 2012
Interband transitions of semiconducting oxides determined from photoelectrolysis spectra journal May 1979
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal July 1996
Interfacial processes involving electrocatalytic evolution and oxidation of H2, and the role of chemisorbed H journal August 2002
Work function, electronegativity, and electrochemical behaviour of metals journal September 1972
Investigations of the electronic structure of d0 transition metal oxides belonging to the perovskite family journal October 2003
Proton conductivity of tungsten trioxide hydrates at intermediate temperature journal October 2000
Predicting catalytic activity in hydrogen evolution reaction journal October 2022
The TOPAS tool for particle simulation, a Monte Carlo simulation tool for physics, biology and clinical research journal April 2020
Progress in aqueous rechargeable batteries journal January 2018
Evidence of Bulk Proton Insertion in Nanostructured Anatase and Amorphous TiO 2 Electrodes journal April 2021
Transition from Battery to Pseudocapacitor Behavior via Structural Water in Tungsten Oxide journal April 2017
Understanding Density-Driven Errors for Reaction Barrier Heights journal January 2023
Accurate and Numerically Efficient r 2 SCAN Meta-Generalized Gradient Approximation journal September 2020
In Situ Study of Silicon Electrode Lithiation with X-ray Reflectivity journal November 2016
Mechanism and Micro Kinetic Model for Electroreduction of CO2 on Pd/C: The Role of Different Palladium Hydride Phases journal May 2021
Understanding Cation Effects on the Hydrogen Evolution Reaction journal December 2022
Confined Interlayer Water Promotes Structural Stability for High-Rate Electrochemical Proton Intercalation in Tungsten Oxide Hydrates journal October 2019
Testing the r2SCAN Density Functional for the Thermodynamic Stability of Solids with and without a van der Waals Correction journal November 2022
Energy Storage in Nanomaterials – Capacitive, Pseudocapacitive, or Battery-like? journal March 2018
Operando Atomic Force Microscopy Reveals Mechanics of Structural Water Driven Battery-to-Pseudocapacitor Transition journal May 2018
Electrical Properties of the Tungsten Bronzes book January 1963
Tafel Kinetics of Electrocatalytic Reactions: From Experiment to First-Principles journal November 2014
Ag/AgBr/WO3·H2O: Visible-Light Photocatalyst for Bacteria Destruction journal October 2009
The Tungstic Acids journal August 1959
The Sensitivity of Metal Oxide Electrocatalysis to Bulk Hydrogen Intercalation: Hydrogen Evolution on Tungsten Oxide journal March 2022
Insights on the Proton Insertion Mechanism in the Electrode of Hexagonal Tungsten Oxide Hydrate journal September 2018
Efficient Electrocatalytic Hydrogenation with a Palladium Membrane Reactor journal April 2019
Electronic and Structural Properties of WO 3 : A Systematic Hybrid DFT Study journal April 2011
X-ray and Neutron Diffraction Studies of a Tetragonal Hydrogen Bronze HxWO3 journal September 1967
Self-hydrogenated shell promoting photocatalytic H2 evolution on anatase TiO2 journal July 2018
Bayesian data analysis reveals no preference for cardinal Tafel slopes in CO2 reduction electrocatalysis journal January 2021
Reversible hydrogen spillover in Ru-WO3-x enhances hydrogen evolution activity in neutral pH water splitting journal September 2022
Designing modern aqueous batteries journal November 2022
Complete electron economy by pairing electrolysis with hydrogenation journal June 2018
Modulating electric field distribution by alkali cations for CO2 electroreduction in strongly acidic medium journal April 2022
Reaction environment impacts charge transfer but not chemical reaction steps in hydrogen evolution catalysis journal April 2023
Metal oxide-based materials as an emerging family of hydrogen evolution electrocatalysts journal January 2020
Revealing hydrogen spillover pathways in reducible metal oxides journal January 2022
H2Ti6O13, a new protonated titanate prepared by Li+/H+ ion exchange: synthesis, crystal structure and electrochemical Li insertion properties journal January 2012
Interlayer separation in hydrogen titanates enables electrochemical proton intercalation journal January 2020
Recent advances in exsolved perovskite oxide construction: exsolution theory, modulation, challenges, and prospects journal January 2023
The rate of electrolytic hydrogen evolution and the heat of adsorption of hydrogen journal January 1958
A climbing image nudged elastic band method for finding saddle points and minimum energy paths journal December 2000
Electrolytic Hydrogen Evolution Kinetics and Its Relation to the Electronic and Adsorptive Properties of the Metal journal March 1957
A generalized solid-state nudged elastic band method journal February 2012
Communication: From graphite to diamond: Reaction pathways of the phase transition journal September 2012
Physical origin of the high reactivity of subsurface hydrogen in catalytic hydrogenation journal July 1999
Electrochemical proton insertion modulates the hydrogen evolution reaction on tungsten oxides journal February 2022
Understanding band gaps of solids in generalized Kohn–Sham theory journal March 2017
Simple coulometer for studying protonic conduction in crystals journal December 1965
The electrolytic behaviour of thin films. Part I.—Hydrogen
  • Bowden, Frank Philip; Rideal, Eric Keightley
  • Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character, Vol. 120, Issue 784, p. 59-79 https://doi.org/10.1098/rspa.1928.0135
journal August 1928
The adsorption and diffusion of electrolytic hydrogen in palladium
  • Devanathan, M. A. V.; Stachurski, Z.
  • Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, Vol. 270, Issue 1340, p. 90-102 https://doi.org/10.1098/rspa.1962.0205
journal October 1962
Workhorse minimally empirical dispersion-corrected density functional with tests for weakly bound systems: r2SCAN+rVV10 journal August 2022
Simplified method for calculating the energy of weakly interacting fragments journal February 1985
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium journal May 1994
Projector augmented-wave method journal December 1994
Nonlocal van der Waals density functional made simple and efficient journal January 2013
Mechanism of the CaIrO 3 post-perovskite phase transition under pressure journal October 2013
Strongly Constrained and Appropriately Normed Semilocal Density Functional journal July 2015
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data journal October 2011
A new type of electro-optic effect in semiconducting WO3 journal December 1974
TOPAS: An innovative proton Monte Carlo platform for research and clinical applications: TOPAS: An innovative proton Monte Carlo platform journal October 2012
The Chemistry of Bulk Hydrogen: Reaction of Hydrogen Embedded in Nickel with Adsorbed CH3 journal July 1992
Global Hydrogen Review 2022 book October 2022