Advances in in situ/operando techniques for catalysis research: enhancing insights and discoveries

Chen, Linfeng; Ding, Xinzhi; Wang, Zheren; Xu, Shutao; Jiang, Qike; Dun, Chaochao; Urban, Jeffrey J.

doi:10.1007/s44251-024-00038-5

Title: Advances in in situ/operando techniques for catalysis research: enhancing insights and discoveries

Journal Article · 13 March 2024 · Surface Science and Technology

DOI: https://doi.org/10.1007/s44251-024-00038-5 · OSTI ID:2323946

Chen, Linfeng; Ding, Xinzhi; Wang, Zheren; Xu, Shutao; Jiang, Qike;

; Urban, Jeffrey J.

Abstract Catalysis research has witnessed remarkable progress with the advent of in situ and operando techniques. These methods enable the study of catalysts under actual operating conditions, providing unprecedented insights into catalytic mechanisms and dynamic catalyst behavior. This review discusses key in situ techniques and their applications in catalysis research. Advances in in situ electron microscopy allow direct visualization of catalysts at the atomic scale under reaction conditions. In situ spectroscopy techniques like X-ray absorption spectroscopy and nuclear magnetic resonance spectroscopy can track chemical states and reveal transient intermediates. Synchrotron-based techniques offer enhanced capabilities for in situ studies. The integration of in situ methods with machine learning and computational modeling provides a powerful approach to accelerate catalyst optimization. However, challenges remain regarding radiation damage, instrumentation limitations, and data interpretation. Overall, continued development of multi-modal in situ techniques is pivotal for addressing emerging challenges and opportunities in catalysis research and technology.

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2323946

Journal Information:: Surface Science and Technology, Journal Name: Surface Science and Technology Journal Issue: 1 Vol. 2; ISSN 2731-7838

Publisher:: Springer Science + Business MediaCopyright Statement

Country of Publication:: Country unknown/Code not available

Language:: English

References (114)

Activation of Cu(111) surface by decomposition into nanoclusters driven by CO adsorption Eren, B.; Zherebetskyy, D.; Patera, L. L. Science, Vol. 351, Issue 6272 https://doi.org/10.1126/science.aad8868	journal	January 2016
Revealing the roles of hydrocarbon pool mechanism in ethanol-to-hydrocarbons reaction Zeng, Shu; Zhang, Wenna; Li, Junjie Journal of Catalysis, Vol. 413 https://doi.org/10.1016/j.jcat.2022.07.002	journal	September 2022
Germanium-enriched double-four-membered-ring units inducing zeolite-confined subnanometric Pt clusters for efficient propane dehydrogenation Ma, Yue; Song, Shaojia; Liu, Changcheng Nature Catalysis, Vol. 6, Issue 6 https://doi.org/10.1038/s41929-023-00968-7	journal	June 2023
Evolution of Oxygen–Metal Electron Transfer and Metal Electronic States During Manganese Oxide Catalyzed Water Oxidation Revealed with In Situ Soft X‐Ray Spectroscopy Tesch, Marc F.; Bonke, Shannon A.; Jones, Travis E. Angewandte Chemie, Vol. 131, Issue 11 https://doi.org/10.1002/ange.201810825	journal	March 2019
Ambient pressure X-ray photoelectron spectroscopy study of room-temperature oxygen adsorption on Cu(1 0 0) and Cu(1 1 1) Liu, Bo-Hong; Huber, Maximilian; van Spronsen, Matthijs A. Applied Surface Science, Vol. 583 https://doi.org/10.1016/j.apsusc.2022.152438	journal	May 2022
In Situ and Emerging Transmission Electron Microscopy for Catalysis Research Chao, Hsin-Yun; Venkatraman, Kartik; Moniri, Saman Chemical Reviews, Vol. 123, Issue 13 https://doi.org/10.1021/acs.chemrev.2c00880	journal	June 2023
Beyond fossil fuel–driven nitrogen transformations Chen, Jingguang G.; Crooks, Richard M.; Seefeldt, Lance C. Science, Vol. 360, Issue 6391 https://doi.org/10.1126/science.aar6611	journal	May 2018
Operando Spectroscopy: the Knowledge Bridge to Assessing Structure-Performance Relationships in Catalyst Nanoparticles Bañares, Miguel A. Advanced Materials, Vol. 23, Issue 44 https://doi.org/10.1002/adma.201101803	journal	September 2011
NiCu single atom alloys catalyze the C H bond activation in the selective non- oxidative ethanol dehydrogenation reaction Shan, Junjun; Liu, Jilei; Li, Mengwei Applied Catalysis B: Environmental, Vol. 226 https://doi.org/10.1016/j.apcatb.2017.12.059	journal	June 2018
Spontaneous Bulk-Surface Charge Separation of TiO₂-{001} Nanocrystals Leads to High Activity in Photocatalytic Methane Combustion Fu, Cong; Li, Fei; Yang, Jianlong ACS Catalysis, Vol. 12, Issue 11 https://doi.org/10.1021/acscatal.2c01706	journal	May 2022
Conversion of Propan-2-ol on Zeolites LaNaY and HY Investigated by Gas Chromatography andin SituMAS NMR Spectroscopy under Continuous-Flow Conditions Hunger, Michael; Horvath, Thomas Journal of Catalysis, Vol. 167, Issue 1 https://doi.org/10.1006/jcat.1997.1562	journal	April 1997
In-situ and operando spectroscopies for the characterization of catalysts and of mechanisms of catalytic reactions Zaera, Francisco Journal of Catalysis, Vol. 404 https://doi.org/10.1016/j.jcat.2021.08.013	journal	December 2021
⁵⁷ Fe Mössbauer Spectroscopy Characterization of Electrocatalysts Kramm, Ulrike I.; Ni, Lingmei; Wagner, Stephan Advanced Materials, Vol. 31, Issue 31 https://doi.org/10.1002/adma.201805623	journal	December 2018
The development of the electron microscope and of electron microscopy Ruska, Ernst Reviews of Modern Physics, Vol. 59, Issue 3 https://doi.org/10.1103/RevModPhys.59.627	journal	July 1987
Insights into Heterogeneous Catalysts under Reaction Conditions by In Situ/Operando Electron Microscopy Cheng, Han‐Wen; Wang, Shan; Chen, Guanyu Advanced Energy Materials, Vol. 12, Issue 38 https://doi.org/10.1002/aenm.202202097	journal	August 2022
Multifunctional metal–organic framework catalysts: synergistic catalysis and tandem reactions Huang, Yuan-Biao; Liang, Jun; Wang, Xu-Sheng Chemical Society Reviews, Vol. 46, Issue 1 https://doi.org/10.1039/C6CS00250A	journal	January 2017
Investigation of Ethanol Conversion on H-ZSM-5 Zeolite by in Situ Solid-State NMR Zeng, Shu; Li, Junjie; Wang, Nan Energy & Fuels, Vol. 35, Issue 15 https://doi.org/10.1021/acs.energyfuels.1c02151	journal	July 2021
Advances in atomic resolution in situ environmental transmission electron microscopy and 1Å aberration corrected in situ electron microscopy Gai, Pratibha L.; Boyes, Edward D. Microscopy Research and Technique, Vol. 72, Issue 3 https://doi.org/10.1002/jemt.20668	journal	March 2009
Unveiling the High‐valence Oxygen Degradation Across the Delithiated Cathode Surface Li, Qinghao; Liang, Qi; Zhang, Hui Angewandte Chemie, Vol. 135, Issue 5 https://doi.org/10.1002/ange.202215131	journal	December 2022
Design and Optimization of Catalysts Based on Mechanistic Insights Derived from Quantum Chemical Reaction Modeling Ahn, Seihwan; Hong, Mannkyu; Sundararajan, Mahesh Chemical Reviews, Vol. 119, Issue 11 https://doi.org/10.1021/acs.chemrev.9b00073	journal	October 2018
Machine Learning for Catalysis Informatics: Recent Applications and Prospects Toyao, Takashi; Maeno, Zen; Takakusagi, Satoru ACS Catalysis, Vol. 10, Issue 3 https://doi.org/10.1021/acscatal.9b04186	journal	December 2019
miR-218 is essential to establish motor neuron fate as a downstream effector of Isl1–Lhx3 Thiebes, Karen P.; Nam, Heejin; Cambronne, Xiaolu A. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8718	journal	July 2015
Motif-mediated Au25(SPh)5(PPh3)10X2 nanorods with conjugated electron delocalization Zheng, Kai; Zhang, Jiangwei; Zhao, Dan Nano Research, Vol. 12, Issue 3 https://doi.org/10.1007/s12274-018-2147-0	journal	August 2018
Synchrotron infrared nano-spectroscopy and -imaging Bechtel, Hans A.; Johnson, Samuel C.; Khatib, Omar Surface Science Reports, Vol. 75, Issue 3 https://doi.org/10.1016/j.surfrep.2020.100493	journal	August 2020
Catalytic Synergy on PtNi Bimetal Catalysts Driven by Interfacial Intermediate Structures Kim, Taek-Seung; Kim, Jeongjin; Song, Hee Chan ACS Catalysis, Vol. 10, Issue 18 https://doi.org/10.1021/acscatal.0c02467	journal	August 2020
Mechanistic investigations of the methanol-to-olefin (MTO) process on acidic zeolite catalysts by in situ solid-state NMR spectroscopy Wang, Wei; Jiang, Yijiao; Hunger, Michael Catalysis Today, Vol. 113, Issue 1-2 https://doi.org/10.1016/j.cattod.2005.11.015	journal	March 2006
Variable Temperature and Pressure Operando MAS NMR for Catalysis Science and Related Materials Jaegers, Nicholas R.; Mueller, Karl T.; Wang, Yong Accounts of Chemical Research, Vol. 53, Issue 3 https://doi.org/10.1021/acs.accounts.9b00557	journal	January 2020
High-spatial-resolution mapping of catalytic reactions on single particles Wu, Chung-Yeh; Wolf, William J.; Levartovsky, Yehonatan Nature, Vol. 541, Issue 7638 https://doi.org/10.1038/nature20795	journal	January 2017
Characterization of Electrocatalytic Water Splitting and CO ₂ Reduction Reactions Using In Situ/Operando Raman Spectroscopy Deng, Yilin; Yeo, Boon Siang ACS Catalysis, Vol. 7, Issue 11 https://doi.org/10.1021/acscatal.7b02561	journal	October 2017
Understanding heterogeneous electrocatalytic carbon dioxide reduction through operando techniques Handoko, Albertus D.; Wei, Fengxia Nature Catalysis, Vol. 1, Issue 12 https://doi.org/10.1038/s41929-018-0182-6	journal	December 2018
Heterogeneous Catalysis Schlögl, Robert Angewandte Chemie International Edition, Vol. 54, Issue 11 https://doi.org/10.1002/anie.201410738	journal	February 2015
Dynamic Evolution of Solid–Liquid Electrochemical Interfaces over Single-Atom Active Sites Su, Hui; Zhou, Wanlin; Zhang, Hui Journal of the American Chemical Society, Vol. 142, Issue 28 https://doi.org/10.1021/jacs.0c04231	journal	June 2020
Promoting effect of MoO3 on the NOx reduction by NH3 over CeO2/TiO2 catalyst studied with in situ DRIFTS Liu, Zhiming; Zhang, Shaoxuan; Li, Junhua Applied Catalysis B: Environmental, Vol. 144 https://doi.org/10.1016/j.apcatb.2013.06.036	journal	January 2014
In Situ Studies of Chemistry and Structure of Materials in Reactive Environments Tao, F.; Salmeron, M. Science, Vol. 331, Issue 6014 https://doi.org/10.1126/science.1197461	journal	January 2011
A Viewpoint on X-ray Tomography Imaging in Electrocatalysis Chen, Yechuan; Stelmacovich, Genevieve; Mularczyk, Adrian ACS Catalysis, Vol. 13, Issue 15 https://doi.org/10.1021/acscatal.3c01453	journal	July 2023
Catalysis on Singly Dispersed Rh Atoms Anchored on an Inert Support Zhang, Shiran; Tang, Yan; Nguyen, Luan ACS Catalysis, Vol. 8, Issue 1 https://doi.org/10.1021/acscatal.7b01788	journal	December 2017
High-Level Spectroscopy, Quantum Chemistry, and Catalysis: Not just a Passing Fad Neese, Frank Angewandte Chemie International Edition, Vol. 56, Issue 37 https://doi.org/10.1002/anie.201701163	journal	August 2017
In Situ Scanning Tunneling Microscopy of Cobalt‐Phthalocyanine‐Catalyzed CO ₂ Reduction Reaction Wang, Xiang; Cai, Zhen‐Feng; Wang, Yu‐Qi Angewandte Chemie International Edition, Vol. 59, Issue 37 https://doi.org/10.1002/anie.202005242	journal	July 2020
Theory-driven design of high-valence metal sites for water oxidation confirmed using in situ soft X-ray absorption Zheng, Xueli; Zhang, Bo; De Luna, Phil Nature Chemistry, Vol. 10, Issue 2 https://doi.org/10.1038/nchem.2886	journal	November 2017
Toward Combined Carbon Capture and Recycling: Addition of an Amine Alters Product Selectivity from CO to Formic Acid in Manganese Catalyzed Reduction of CO ₂ Bhattacharya, Moumita; Sebghati, Sepehr; VanderLinden, Ryan T. Journal of the American Chemical Society, Vol. 142, Issue 41 https://doi.org/10.1021/jacs.0c07763	journal	September 2020
Probing the Evolution of Adsorption on Nanoporous Solids by In Situ Solid-State NMR Spectroscopy Xu, Mingcan; Harris, Kenneth D. M.; Thomas, John Meurig ChemPhysChem, Vol. 8, Issue 9 https://doi.org/10.1002/cphc.200700218	journal	June 2007
Probing the active site in single-atom oxygen reduction catalysts via operando X-ray and electrochemical spectroscopy Lien, Hsiang-Ting; Chang, Sun-Tang; Chen, Po-Tuan Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-17975-y	journal	August 2020
In situ identification of active sites during electrocatalytic hydrogen evolution Wang, Dongge; Wu, Juanxia; Jiao, Liying Nano Research, Vol. 16, Issue 12 https://doi.org/10.1007/s12274-023-5686-y	journal	May 2023
In Situ Structure of a Mo-Doped Pt–Ni Catalyst during Electrochemical Oxygen Reduction Resolved from Machine Learning-Based Grand Canonical Global Optimization Li, Ji-Li; Li, Ye-Fei; Liu, Zhi-Pan JACS Au, Vol. 3, Issue 4 https://doi.org/10.1021/jacsau.3c00038	journal	March 2023
Evidence for an Initiation of the Methanol-to-Olefin Process by Reactive Surface Methoxy Groups on Acidic Zeolite Catalysts Wang, Wei; Buchholz, Andreas; Seiler, Michael Journal of the American Chemical Society, Vol. 125, Issue 49 https://doi.org/10.1021/ja0304244	journal	December 2003
The concept of active site in heterogeneous catalysis Vogt, Charlotte; Weckhuysen, Bert M. Nature Reviews Chemistry, Vol. 6, Issue 2 https://doi.org/10.1038/s41570-021-00340-y	journal	January 2022
Discovering Catalytic Reaction Networks Using Deep Reinforcement Learning from First-Principles Lan, Tian; An, Qi Journal of the American Chemical Society, Vol. 143, Issue 40 https://doi.org/10.1021/jacs.1c08794	journal	October 2021
Sub-10 nm Platinum Nanocrystals with Size and Shape Control: Catalytic Study for Ethylene and Pyrrole Hydrogenation Tsung, Chia-Kuang; Kuhn, John N.; Huang, Wenyu Journal of the American Chemical Society, Vol. 131, Issue 16 https://doi.org/10.1021/ja809936n	journal	April 2009
Soft XAS as an in situ technique for the study of heterogeneous catalysts Beaumont, Simon K. Physical Chemistry Chemical Physics, Vol. 22, Issue 34 https://doi.org/10.1039/D0CP00657B	journal	January 2020
Molecular Factors of Catalytic Selectivity Somorjai, Gabor A.; Park, Jeong Y. Angewandte Chemie International Edition, Vol. 47, Issue 48 https://doi.org/10.1002/anie.200803181	journal	November 2008
Operando Surface Spectroscopy and Microscopy during Catalytic Reactions: From Clusters via Nanoparticles to Meso‐Scale Aggregates Rupprechter, Günther Small, Vol. 17, Issue 27 https://doi.org/10.1002/smll.202004289	journal	March 2021
In situ electron paramagnetic resonance spectroscopy for catalysis Bonke, Shannon A.; Risse, Thomas; Schnegg, Alexander Nature Reviews Methods Primers, Vol. 1, Issue 1 https://doi.org/10.1038/s43586-021-00031-4	journal	May 2021
“Inverting” X-ray Absorption Spectra of Catalysts by Machine Learning in Search for Activity Descriptors Timoshenko, Janis; Frenkel, Anatoly I. ACS Catalysis, Vol. 9, Issue 11 https://doi.org/10.1021/acscatal.9b03599	journal	September 2019
Probing Active Sites in Cu _x Pd _y Cluster Catalysts by Machine-Learning-Assisted X-ray Absorption Spectroscopy Liu, Yang; Halder, Avik; Seifert, Soenke ACS Applied Materials & Interfaces, Vol. 13, Issue 45 https://doi.org/10.1021/acsami.1c06714	journal	July 2021
Infrared Spectroscopy: Fundamentals and Applications Stuart, Barbara H. Analytical Techniques in the Sciences https://doi.org/10.1002/0470011149	book	June 2004
The first carbon-carbon bond formation mechanism in methanol-to-hydrocarbons process over chabazite zeolite Sun, Tantan; Chen, Wei; Xu, Shutao Chem, Vol. 7, Issue 9 https://doi.org/10.1016/j.chempr.2021.05.023	journal	September 2021
High-Pressure Scanning Tunneling Microscopy Salmeron, Miquel; Eren, Baran Chemical Reviews, Vol. 121, Issue 2 https://doi.org/10.1021/acs.chemrev.0c00429	journal	December 2020
In situ/operando Mössbauer spectroscopy for probing heterogeneous catalysis Zeng, Yaqiong; Li, Xuning; Wang, Junhu Chem Catalysis, Vol. 1, Issue 6 https://doi.org/10.1016/j.checat.2021.08.013	journal	November 2021
Perspectives on in situ electron microscopy Zheng, Haimei; Zhu, Yimei Ultramicroscopy, Vol. 180 https://doi.org/10.1016/j.ultramic.2017.03.022	journal	September 2017
Platinum group metal-free NiMo hydrogen oxidation catalysts: high performance and durability in alkaline exchange membrane fuel cells Kabir, Sadia; Lemire, Kenneth; Artyushkova, Kateryna Journal of Materials Chemistry A, Vol. 5, Issue 46 https://doi.org/10.1039/C7TA08718G	journal	January 2017
Applications of extended X-ray absorption fine-structure spectroscopy to studies of bimetallic nanoparticle catalysts Frenkel, Anatoly I. Chemical Society Reviews, Vol. 41, Issue 24 https://doi.org/10.1039/c2cs35174a	journal	January 2012
Adsorbate-driven reactive interfacial Pt-NiO 1− x nanostructure formation on the Pt 3 Ni(111) alloy surface Kim, Jeongjin; Park, Woong Hyeon; Doh, Won Hui Science Advances, Vol. 4, Issue 7 https://doi.org/10.1126/sciadv.aat3151	journal	July 2018
The Dynamical Nature of Enzymatic Catalysis Callender, Robert; Dyer, R. Brian Accounts of Chemical Research, Vol. 48, Issue 2 https://doi.org/10.1021/ar5002928	journal	December 2014
Visualizing Catalytic Dynamics Processes via Synchrotron Radiation Multitechniques Cao, Dengfeng; Xu, Wenjie; Chen, Shuangming Advanced Materials, Vol. 35, Issue 30 https://doi.org/10.1002/adma.202205346	journal	June 2023
Data‐Driven Machine Learning for Understanding Surface Structures of Heterogeneous Catalysts Li, Haobo; Jiao, Yan; Davey, Kenneth Angewandte Chemie, Vol. 135, Issue 9 https://doi.org/10.1002/ange.202216383	journal	January 2023
Formation of cyclic compounds and carbenium ions by conversion of methanol on weakly dealuminated zeolite H-ZSM-5 investigated via a novel in situ CF MAS NMR/UV-Vis technique Hunger, Michael; Wang, Wei Chemical Communications, Issue 5 https://doi.org/10.1039/b315779b	journal	January 2004
Environmental high resolution electron microscopy and applications to chemical science Boyes, E. D.; Gai, P. L. Ultramicroscopy, Vol. 67, Issue 1-4 https://doi.org/10.1016/S0304-3991(96)00099-X	journal	June 1997
Operando Electrochemical Liquid-Cell Scanning Transmission Electron Microscopy (EC-STEM) Studies of Evolving Cu Nanocatalysts for CO₂ Electroreduction Yang, Yao; Shao, Yu-Tsun; Jin, Jianbo ACS Sustainable Chemistry & Engineering, Vol. 11, Issue 10 https://doi.org/10.1021/acssuschemeng.2c06542	journal	February 2023
In Situ Transmission Electron Microscopy on Energy‐Related Catalysis Hwang, Sooyeon; Chen, Xiaobo; Zhou, Guangwen Advanced Energy Materials https://doi.org/10.1002/aenm.201902105	journal	December 2019
Understanding X-ray absorption spectra by means of descriptors and machine learning algorithms Guda, A. A.; Guda, S. A.; Martini, A. npj Computational Materials, Vol. 7, Issue 1 https://doi.org/10.1038/s41524-021-00664-9	journal	December 2021
3D structure of individual nanocrystals in solution by electron microscopy Park, J.; Elmlund, H.; Ercius, P. Science, Vol. 349, Issue 6245 https://doi.org/10.1126/science.aab1343	journal	July 2015
Recent Developments in APXPS at the Shanghai Synchrotron Radiation Facility Zhang, Hui; Li, Xiaobao; Yu, Yi Synchrotron Radiation News, Vol. 35, Issue 3 https://doi.org/10.1080/08940886.2022.2082178	journal	May 2022
Directly Probing the Local Coordination, Charge State, and Stability of Single Atom Catalysts by Advanced Electron Microscopy: A Review Tieu, Peter; Yan, Xingxu; Xu, Mingjie Small, Vol. 17, Issue 16 https://doi.org/10.1002/smll.202006482	journal	February 2021
Bimetallic synergy in cobalt–palladium nanocatalysts for CO oxidation Wu, Cheng Hao; Liu, Chang; Su, Dong Nature Catalysis, Vol. 2, Issue 1 https://doi.org/10.1038/s41929-018-0190-6	journal	December 2018
Operando studies reveal active Cu nanograins for CO2 electroreduction Yang, Yao; Louisia, Sheena; Yu, Sunmoon Nature, Vol. 614, Issue 7947 https://doi.org/10.1038/s41586-022-05540-0	journal	February 2023
Real-time imaging of adatom-promoted graphene growth on nickel Patera, Laerte L.; Bianchini, Federico; Africh, Cristina Science, Vol. 359, Issue 6381 https://doi.org/10.1126/science.aan8782	journal	March 2018
Operando Identification of the Dynamic Behavior of Oxygen Vacancy-Rich Co ₃ O ₄ for Oxygen Evolution Reaction Xiao, Zhaohui; Huang, Yu-Cheng; Dong, Chung-Li Journal of the American Chemical Society, Vol. 142, Issue 28 https://doi.org/10.1021/jacs.0c00257	journal	June 2020
Reactivity of Surface Alkoxy Species on Acidic Zeolite Catalysts Wang, Wei; Hunger, Michael Accounts of Chemical Research, Vol. 41, Issue 8 https://doi.org/10.1021/ar700210f	journal	August 2008
In Situ Transmission Electron Microscopy for Energy Applications Li, Jing; Johnson, Grayson; Zhang, Sen Joule, Vol. 3, Issue 1 https://doi.org/10.1016/j.joule.2018.12.007	journal	January 2019
First-principle-data-integrated machine-learning approach for high-throughput searching of ternary electrocatalyst toward oxygen reduction reaction Chun, Hoje; Lee, Eunjik; Nam, Kyungju Chem Catalysis, Vol. 1, Issue 4 https://doi.org/10.1016/j.checat.2021.06.001	journal	September 2021
In Situ Characterization of Catalysis and Electrocatalysis Using APXPS Han, Yong; Zhang, Hui; Yu, Yi ACS Catalysis, Vol. 11, Issue 3 https://doi.org/10.1021/acscatal.0c04251	journal	January 2021
Capturing Manganese Oxide Intermediates in Electrochemical Water Oxidation at Neutral pH by In Situ Raman Spectroscopy Cho, Kang Hee; Park, Sunghak; Seo, Hongmin Angewandte Chemie International Edition, Vol. 60, Issue 9 https://doi.org/10.1002/anie.202014551	journal	January 2021
Operando Surface Characterization on Catalytic and Energy Materials from Single Crystals to Nanoparticles Choi, Joong Il Jake; Kim, Taek-Seung; Kim, Daeho ACS Nano, Vol. 14, Issue 12 https://doi.org/10.1021/acsnano.0c07549	journal	November 2020
Synthesis of Ru Icosahedral Nanocages with a Face-Centered-Cubic Structure and Evaluation of Their Catalytic Properties Zhao, Ming; Xu, Lang; Vara, Madeline ACS Catalysis, Vol. 8, Issue 8 https://doi.org/10.1021/acscatal.8b00910	journal	May 2018
Enhanced In situ Continuous-Flow MAS NMR for Reaction Kinetics in the Nanocages Xu, Shutao; Zhang, Weiping; Liu, Xianchun Journal of the American Chemical Society, Vol. 131, Issue 38 https://doi.org/10.1021/ja904304h	journal	September 2009
Imaging the dynamics of catalysed surface reactions by in situ scanning electron microscopy Barroo, Cédric; Wang, Zhu-Jun; Schlögl, Robert Nature Catalysis, Vol. 3, Issue 1 https://doi.org/10.1038/s41929-019-0395-3	journal	December 2019
Formation of Different Rh–O Species on Rh(110) and Their Reaction with CO Cai, Jun; Ling, Yunjian; Zhang, Hui ACS Catalysis, Vol. 13, Issue 1 https://doi.org/10.1021/acscatal.2c04463	journal	December 2022
Molecular oxygen enhances H2O2 utilization for the photocatalytic conversion of methane to liquid-phase oxygenates Sun, Xiao; Chen, Xuanye; Fu, Cong Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-34563-4	journal	November 2022
Elucidating the Nature of Fe Species during Pyrolysis of the Fe-BTC MOF into Highly Active and Stable Fischer–Tropsch Catalysts Wezendonk, Tim A.; Santos, Vera P.; Nasalevich, Maxim A. ACS Catalysis, Vol. 6, Issue 5 https://doi.org/10.1021/acscatal.6b00426	journal	April 2016
Homogeneous Catalysis--New Approaches to Catalyst Separation, Recovery, and Recycling Cole-Hamilton, David J. Science, Vol. 299, Issue 5613, p. 1702-1706 https://doi.org/10.1126/science.1081881	journal	March 2003
In Situ Surface Structures of PdAg Catalyst and Their Influence on Acetylene Semihydrogenation Revealed by Machine Learning and Experiment Li, Xiao-Tian; Chen, Lin; Shang, Cheng Journal of the American Chemical Society, Vol. 143, Issue 16 https://doi.org/10.1021/jacs.1c02471	journal	April 2021
In Situ/Operando Techniques for Characterization of Single-Atom Catalysts Li, Xuning; Yang, Xiaofeng; Zhang, Junming ACS Catalysis, Vol. 9, Issue 3 https://doi.org/10.1021/acscatal.8b04937	journal	February 2019
Opportunities and challenges in liquid cell electron microscopy Ross, F. M. Science, Vol. 350, Issue 6267 https://doi.org/10.1126/science.aaa9886	journal	December 2015
Deciphering the Structural and Chemical Transformations of Oxide Catalysts during Oxygen Evolution Reaction Using Quick X-ray Absorption Spectroscopy and Machine Learning Timoshenko, Janis; Haase, Felix T.; Saddeler, Sascha Journal of the American Chemical Society, Vol. 145, Issue 7 https://doi.org/10.1021/jacs.2c11824	journal	February 2023
Pushing the limits of SPM Frenken, Joost W. M.; Oosterkamp, Tjerk H.; Hendriksen, Bas L. M. Materials Today, Vol. 8, Issue 5 https://doi.org/10.1016/S1369-7021(05)00842-4	journal	May 2005
In-situ Scanning Transmission X-Ray Microscopy of Catalytic Solids and Related Nanomaterials de Groot, Frank M. F.; de Smit, Emiel; van Schooneveld, Matti M. ChemPhysChem, Vol. 11, Issue 5 https://doi.org/10.1002/cphc.200901023	journal	March 2010
The development and applications of CAVERN methods for in situ NMR studies of reactions on solid acids Xu, T.; Haw, J. F. Topics in Catalysis, Vol. 4, Issue 1/2, p. 109-118 https://doi.org/10.1023/A:1019163500342	journal	January 1997
Identification of the Electronic and Structural Dynamics of Catalytic Centers in Single-Fe-Atom Material Li, Xuning; Cao, Chang-Su; Hung, Sung-Fu Chem, Vol. 6, Issue 12 https://doi.org/10.1016/j.chempr.2020.10.027	journal	December 2020
Direct Mechanism of the First Carbon–Carbon Bond Formation in the Methanol‐to‐Hydrocarbons Process Wu, Xinqiang; Xu, Shutao; Zhang, Wenna Angewandte Chemie, Vol. 129, Issue 31 https://doi.org/10.1002/ange.201703902	journal	May 2017
Revealing the Active Phase of Copper during the Electroreduction of CO ₂ in Aqueous Electrolyte by Correlating In Situ X-ray Spectroscopy and In Situ Electron Microscopy Velasco-Velez, Juan-Jesus; Mom, Rik V.; Sandoval-Diaz, Luis-Ernesto ACS Energy Letters, Vol. 5, Issue 6 https://doi.org/10.1021/acsenergylett.0c00802	journal	May 2020
Investigation of solid/vapor interfaces using ambient pressure X-ray photoelectron spectroscopy Starr, D. E.; Liu, Z.; Hävecker, M. Chemical Society Reviews, Vol. 42, Issue 13 https://doi.org/10.1039/c3cs60057b	journal	January 2013
The discovery of synchrotron radiation Pollock, Herbert C. American Journal of Physics, Vol. 51, Issue 3 https://doi.org/10.1119/1.13289	journal	March 1983
Characterization of Solid Catalysts in the Functioning State by Nuclear Magnetic Resonance Spectroscopy Hunger, M.; Wang, W. Advances in Catalysis , Vol. 50 https://doi.org/10.1016/S0360-0564(06)50004-5	book	May 2006
Revealing the Atomic Restructuring of Pt–Co Nanoparticles Xin, Huolin L.; Alayoglu, Selim; Tao, Runzhe Nano Letters, Vol. 14, Issue 6 https://doi.org/10.1021/nl500553a	journal	May 2014
Operando methodology: combination of in situ spectroscopy and simultaneous activity measurements under catalytic reaction conditions Bañares, Miguel A. Catalysis Today, Vol. 100, Issue 1-2 https://doi.org/10.1016/j.cattod.2004.12.017	journal	February 2005
Crystal-phase and surface-structure engineering of ruthenium nanocrystals Zhao, Ming; Xia, Younan Nature Reviews Materials, Vol. 5, Issue 6 https://doi.org/10.1038/s41578-020-0183-3	journal	March 2020
Identification of single-atom active sites in carbon-based cobalt catalysts during electrocatalytic hydrogen evolution Cao, Linlin; Luo, Qiquan; Liu, Wei Nature Catalysis, Vol. 2, Issue 2 https://doi.org/10.1038/s41929-018-0203-5	journal	December 2018
Four-Dimensional Scanning Transmission Electron Microscopy (4D-STEM): From Scanning Nanodiffraction to Ptychography and Beyond Ophus, Colin Microscopy and Microanalysis, Vol. 25, Issue 3 https://doi.org/10.1017/S1431927619000497	journal	May 2019
Mapping XANES spectra on structural descriptors of copper oxide clusters using supervised machine learning Liu, Yang; Marcella, Nicholas; Timoshenko, Janis The Journal of Chemical Physics, Vol. 151, Issue 16 https://doi.org/10.1063/1.5126597	journal	October 2019
Progress in the theory and interpretation of XANES Rehr, J. J.; Ankudinov, A. L. Coordination Chemistry Reviews, Vol. 249, Issue 1-2 https://doi.org/10.1016/j.ccr.2004.02.014	journal	January 2005
Single-atom catalysis of CO oxidation using Pt1/FeOx Qiao, Botao; Wang, Aiqin; Yang, Xiaofeng Nature Chemistry, Vol. 3, Issue 8 https://doi.org/10.1038/nchem.1095	journal	July 2011
CHGNet as a pretrained universal neural network potential for charge-informed atomistic modelling Deng, Bowen; Zhong, Peichen; Jun, KyuJung Nature Machine Intelligence, Vol. 5, Issue 9 https://doi.org/10.1038/s42256-023-00716-3	journal	September 2023
Data-Centric Heterogeneous Catalysis: Identifying Rules and Materials Genes of Alkane Selective Oxidation Foppa, Lucas; Rüther, Frederik; Geske, Michael Journal of the American Chemical Society, Vol. 145, Issue 6 https://doi.org/10.1021/jacs.2c11117	journal	February 2023
Structure Sensitivity of Au‐TiO ₂ Strong Metal–Support Interactions Zhang, Yunshang; Liu, Jin‐Xun; Qian, Kun Angewandte Chemie International Edition, Vol. 60, Issue 21 https://doi.org/10.1002/anie.202101928	journal	April 2021

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