High entropy ceramics for applications in extreme environments

Ward, T. Z.; Wilkerson, R. P.; Musicó, B. L.; Foley, A.; Brahlek, M.; Weber, W. J.; Sickafus, K. E.; Mazza, A. R.

doi:10.1088/2515-7639/ad2ec5

Title: High entropy ceramics for applications in extreme environments

Journal Article · 11 March 2024 · JPhys Materials

DOI: https://doi.org/10.1088/2515-7639/ad2ec5 · OSTI ID:2323354

;

; Sickafus, K. E.;

Abstract Compositionally complex materials have demonstrated extraordinary promise for structural robustness in extreme environments. Of these, the most commonly thought of are high entropy alloys, where chemical complexity grants uncommon combinations of hardness, ductility, and thermal resilience. In contrast to these metal–metal bonded systems, the addition of ionic and covalent bonding has led to the discovery of high entropy ceramics (HECs). These materials also possess outstanding structural, thermal, and chemical robustness but with a far greater variety of functional properties which enable access to continuously controllable magnetic, electronic, and optical phenomena. In this experimentally focused perspective, we outline the potential for HECs in functional applications under extreme environments, where intrinsic stability may provide a new path toward inherently hardened device design. Current works on high entropy carbides, actinide bearing ceramics, and high entropy oxides are reviewed in the areas of radiation, high temperature, and corrosion tolerance where the role of local disorder is shown to create pathways toward self-healing and structural robustness. In this context, new strategies for creating future electronic, magnetic, and optical devices to be operated in harsh environments are outlined.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: 89233218CNA000001; AC05-00OR22725

OSTI ID:: 2323354

Report Number(s):: LA-UR--23-32255

Journal Information:: JPhys Materials, Journal Name: JPhys Materials Journal Issue: 2 Vol. 7; ISSN 2515-7639

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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Direct observation of elemental fluctuation and oxygen octahedral distortion-dependent charge distribution in high entropy oxides Su, Lei; Huyan, Huaixun; Sarkar, Abhishek Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-30018-y	journal	April 2022
Plasmonic high-entropy carbides Calzolari, Arrigo; Oses, Corey; Toher, Cormac Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-33497-1	journal	October 2022
Discovery of high-entropy ceramics via machine learning Kaufmann, Kevin; Maryanovsky, Daniel; Mellor, William M. npj Computational Materials, Vol. 6, Issue 1 https://doi.org/10.1038/s41524-020-0317-6	journal	May 2020
High-entropy ceramics Oses, Corey; Toher, Cormac; Curtarolo, Stefano Nature Reviews Materials, Vol. 5, Issue 4 https://doi.org/10.1038/s41578-019-0170-8	journal	February 2020
Machine learning for alloys Hart, Gus L. W.; Mueller, Tim; Toher, Cormac Nature Reviews Materials, Vol. 6, Issue 8 https://doi.org/10.1038/s41578-021-00340-w	journal	July 2021
Materials for extreme environments Eswarappa Prameela, Suhas; Pollock, Tresa M.; Raabe, Dierk Nature Reviews Materials, Vol. 8, Issue 2 https://doi.org/10.1038/s41578-022-00496-z	journal	November 2022
High-entropy ferroelectric materials Qi, He; Chen, Liang; Deng, Shiqing Nature Reviews Materials, Vol. 8, Issue 6 https://doi.org/10.1038/s41578-023-00544-2	journal	February 2023
Giant Enhancement of Exchange Coupling in Entropy-Stabilized Oxide Heterostructures Meisenheimer, P. B.; Kratofil, T. J.; Heron, J. T. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-13810-5	journal	October 2017
Robustness of superconductivity to external pressure in high-entropy-alloy-type metal telluride AgInSnPbBiTe5 Kasem, Md. Riad; Nakahira, Yuki; Yamaoka, Hitoshi Scientific Reports, Vol. 12, Issue 1 https://doi.org/10.1038/s41598-022-11862-w	journal	May 2022
Functional two-dimensional high-entropy materials Nemani, Srinivasa Kartik; Torkamanzadeh, Mohammad; Wyatt, Brian C. Communications Materials, Vol. 4, Issue 1 https://doi.org/10.1038/s43246-023-00341-y	journal	February 2023
Super-strong materials for temperatures exceeding 2000 °C Silvestroni, Laura; Kleebe, Hans-Joachim; Fahrenholtz, William G. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep40730	journal	January 2017
Room temperature lithium superionic conductivity in high entropy oxides Bérardan, D.; Franger, S.; Meena, A. K. Journal of Materials Chemistry A, Vol. 4, Issue 24 https://doi.org/10.1039/C6TA03249D	journal	January 2016
Magnetic properties of high entropy oxides Sarkar, Abhishek; Kruk, Robert; Hahn, Horst Dalton Transactions, Vol. 50, Issue 6 https://doi.org/10.1039/D0DT04154H	journal	January 2021
High entropy metal chalcogenides: synthesis, properties, applications and future directions Buckingham, Mark A.; Ward-O’Brien, Brendan; Xiao, Weichen Chemical Communications, Vol. 58, Issue 58 https://doi.org/10.1039/D2CC01796B	journal	January 2022
Nuclear waste disposal—pyrochlore (A2B2O7): Nuclear waste form for the immobilization of plutonium and “minor” actinides Ewing, Rodney C.; Weber, William J.; Lian, Jie Journal of Applied Physics, Vol. 95, Issue 11 https://doi.org/10.1063/1.1707213	journal	June 2004
Epitaxial stabilization of ultra thin films of high entropy perovskite Patel, Ranjan Kumar; Ojha, Shashank Kumar; Kumar, Siddharth Applied Physics Letters, Vol. 116, Issue 7 https://doi.org/10.1063/1.5133710	journal	February 2020
Reversibly tuning the band structure of high entropy oxides Patrick, Chris Scilight, Vol. 2020, Issue 21 https://doi.org/10.1063/10.0001325	journal	May 2020
Role of intermediate 4 f states in tuning the band structure of high entropy oxides Sarkar, Abhishek; Eggert, Benedikt; Velasco, Leonardo APL Materials, Vol. 8, Issue 5 https://doi.org/10.1063/5.0007944	journal	May 2020
Exchange interactions and long-range magnetic order in the (Mg,Co,Cu,Ni,Zn)O entropy-stabilized oxide: A theoretical investigation Rák, Zs.; Brenner, D. W. Journal of Applied Physics, Vol. 127, Issue 18 https://doi.org/10.1063/5.0008258	journal	May 2020
Topological materials by molecular beam epitaxy Brahlek, Matthew; Lapano, Jason; Lee, Joon Sue Journal of Applied Physics, Vol. 128, Issue 21 https://doi.org/10.1063/5.0022948	journal	December 2020
What is in a name: Defining “high entropy” oxides Brahlek, Matthew; Gazda, Maria; Keppens, Veerle APL Materials, Vol. 10, Issue 11 https://doi.org/10.1063/5.0122727	journal	November 2022
Hole doping in compositionally complex correlated oxide enables tunable exchange biasing Mazza, Alessandro R.; Skoropata, Elizabeth; Lapano, Jason APL Materials, Vol. 11, Issue 3 https://doi.org/10.1063/5.0142224	journal	March 2023
High performance top-gated multilayer WSe ₂ field effect transistors Pudasaini, Pushpa Raj; Stanford, Michael G.; Oyedele, Akinola Nanotechnology, Vol. 28, Issue 47 https://doi.org/10.1088/1361-6528/aa8081	journal	October 2017
Will high-entropy carbides and borides be enabling materials for extreme environments? Wang, Fei; Monteverde, Frederic; Cui, Bai International Journal of Extreme Manufacturing, Vol. 5, Issue 2 https://doi.org/10.1088/2631-7990/acbd6e	journal	March 2023
Charge doping effects on magnetic properties of single-crystal La 1 − x Sr x ( Cr 0.2 Mn 0.2 Fe 0.2 Co 0.2 Ni 0.2 ) O 3 ( 0 ≤ x ≤ 0.5 ) high-entropy perovskite oxides Mazza, Alessandro R.; Skoropata, Elizabeth; Lapano, Jason Physical Review B, Vol. 104, Issue 9 https://doi.org/10.1103/PhysRevB.104.094204	journal	September 2021
Weak ferromagnetism in Tb(Fe0.2Mn0.2Co0.2Cr0.2Ni0.2)O3 high-entropy oxide perovskite thin films Farhan, Alan; Stramaglia, Federico; Cocconcelli, Maria Physical Review B, Vol. 106, Issue 6 https://doi.org/10.1103/PhysRevB.106.L060404	journal	August 2022
Tuning the Metal-Insulator Transition in Manganite Films through Surface Exchange Coupling with Magnetic Nanodots Ward, T. Z.; Gai, Z.; Xu, X. Y. Physical Review Letters, Vol. 106, Issue 15 https://doi.org/10.1103/PhysRevLett.106.157207	journal	April 2011
Single-crystal high entropy perovskite oxide epitaxial films Sharma, Yogesh; Musico, Brianna L.; Gao, Xiang Physical Review Materials, Vol. 2, Issue 6 https://doi.org/10.1103/PhysRevMaterials.2.060404	journal	June 2018
Tunable magnetic ordering through cation selection in entropic spinel oxides Musicó, Brianna; Wright, Quinton; Ward, T. Zac Physical Review Materials, Vol. 3, Issue 10 https://doi.org/10.1103/PhysRevMaterials.3.104416	journal	October 2019
Magnetic frustration control through tunable stereochemically driven disorder in entropy-stabilized oxides Meisenheimer, Peter B.; Williams, Logan D.; Sung, Suk Hyun Physical Review Materials, Vol. 3, Issue 10 https://doi.org/10.1103/PhysRevMaterials.3.104420	journal	October 2019
Magnetic anisotropy in single-crystal high-entropy perovskite oxide La ( C r 0.2 M n 0.2 F e 0.2 C o 0.2 N i 0.2 ) O 3 films Sharma, Yogesh; Zheng, Qiang; Mazza, Alessandro R. Physical Review Materials, Vol. 4, Issue 1 https://doi.org/10.1103/PhysRevMaterials.4.014404	journal	January 2020
Unexpected crystalline homogeneity from the disordered bond network in La ( C r 0.2 M n 0.2 F e 0.2 C o 0.2 N i 0.2 ) O 3 films Brahlek, Matthew; Mazza, Alessandro R.; Pitike, Krishna Chaitanya Physical Review Materials, Vol. 4, Issue 5 https://doi.org/10.1103/PhysRevMaterials.4.054407	journal	May 2020
Property and cation valence engineering in entropy-stabilized oxide thin films Kotsonis, George N.; Meisenheimer, Peter B.; Miao, Leixin Physical Review Materials, Vol. 4, Issue 10 https://doi.org/10.1103/PhysRevMaterials.4.100401	journal	October 2020
Synthesis, characterization, and single-crystal growth of a high-entropy rare-earth pyrochlore oxide Kinsler-Fedon, Candice; Zheng, Qiang; Huang, Qing Physical Review Materials, Vol. 4, Issue 10 https://doi.org/10.1103/PhysRevMaterials.4.104411	journal	October 2020
Adsorption-controlled growth of MnTe ( Bi 2 Te 3 ) n by molecular beam epitaxy exhibiting stoichiometry-controlled magnetism Lapano, Jason; Nuckols, Lauren; Mazza, Alessandro R. Physical Review Materials, Vol. 4, Issue 11 https://doi.org/10.1103/PhysRevMaterials.4.111201	journal	November 2020
High-entropy silicide superconductors with W5Si3 -type structure Liu, Bin; Yang, Wuzhang; Xiao, Guorui Physical Review Materials, Vol. 7, Issue 1 https://doi.org/10.1103/PhysRevMaterials.7.014805	journal	January 2023
Comprehensive analysis on the effect of ionic size and size disorder parameter in high entropy stabilized ferromagnetic manganite perovskite Das, Radhamadhab; Pal, Sudip; Bhattacharya, Sudipa Physical Review Materials, Vol. 7, Issue 2 https://doi.org/10.1103/PhysRevMaterials.7.024411	journal	February 2023
Element-sensitive x-ray absorption spectroscopy and magnetometry of Lu(Fe0.2Mn0.2Co0.2Cr0.2Ni0.2)O3 high-entropy oxide perovskite thin films Farhan, Alan; Cocconcelli, Maria; Stramaglia, Federico Physical Review Materials, Vol. 7, Issue 4 https://doi.org/10.1103/PhysRevMaterials.7.044402	journal	April 2023
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(Hf _0.2 Zr _0.2 Ta _0.2 Nb _0.2 Ti _0.2 )C high‐entropy ceramics with low thermal conductivity Yan, Xueliang; Constantin, Loic; Lu, Yongfeng Journal of the American Ceramic Society, Vol. 101, Issue 10 https://doi.org/10.1111/jace.15779	journal	May 2018
Microstructural evolution and mechanical properties of (Mg,Co,Ni,Cu,Zn)O high‐entropy ceramics Hong, Weichen; Chen, Fei; Shen, Qiang Journal of the American Ceramic Society https://doi.org/10.1111/jace.16075	journal	October 2018
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Crystal growth and phase formation of high‐entropy rare‐earth monoclinic aluminates Pianassola, Matheus; Loveday, Madeline; Lalk, Rebecca Journal of the American Ceramic Society, Vol. 106, Issue 11 https://doi.org/10.1111/jace.19320	journal	July 2023
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High-entropy-stabilized chalcogenides with high thermoelectric performance Jiang, Binbin; Yu, Yong; Cui, Juan Science, Vol. 371, Issue 6531 https://doi.org/10.1126/science.abe1292	journal	February 2021
High-Entropy Ultra-High-Temperature Borides and Carbides: A New Class of Materials for Extreme Environments Feng, Lun; Fahrenholtz, William G.; Brenner, Donald W. Annual Review of Materials Research, Vol. 51, Issue 1 https://doi.org/10.1146/annurev-matsci-080819-121217	journal	July 2021
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Reduced He ion irradiation damage in ZrC-based high-entropy ceramics Xin, Xiao-Ting; Bao, Weichao; Wang, Xin-Gang Journal of Advanced Ceramics, Vol. 12, Issue 5 https://doi.org/10.26599/JAC.2023.9220727	journal	May 2023
High-Entropy Borides under Extreme Environment of Pressures and Temperatures Iwan, Seth; Lin, Chia-Min; Perreault, Christopher Materials, Vol. 15, Issue 9 https://doi.org/10.3390/ma15093239	journal	April 2022
High-Pressure Synthesis of High-Entropy Metal Disulfides with Pyrite-Type Structure Laila, Anna Z.; Fronzi, Marco; Kumegai, Shinya Journal of the Physical Society of Japan, Vol. 91, Issue 8 https://doi.org/10.7566/JPSJ.91.084802	journal	August 2022

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