High entropy ceramics for applications in extreme environments

Ward, T. Zac; Wilkerson, Ryan Patrick; Musicó, Brianna Leigh; Foley, Ariana Audrey Renee; Brahlek, Matthew; Weber, William J.; Sickafus, Kurt Edward; Mazza, Alessandro R.

doi:10.1088/2515-7639/ad2ec5

Title: High entropy ceramics for applications in extreme environments

Journal Article · 12 March 2024 · JPhys Materials

DOI: https://doi.org/10.1088/2515-7639/ad2ec5 · OSTI ID:2323354

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Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Univ. of Tennessee, Knoxville, TN (United States)

Compositionally complex materials have demonstrated extraordinary promise for structural robustness in extreme environments. Of these, the most commonly thought of are high entropy alloys, where chemical complexity grants uncommon combinations of hardness, ductility, and thermal resilience. In contrast to these metal–metal bonded systems, the addition of ionic and covalent bonding has led to the discovery of high entropy ceramics (HECs). These materials also possess outstanding structural, thermal, and chemical robustness but with a far greater variety of functional properties which enable access to continuously controllable magnetic, electronic, and optical phenomena. In this experimentally focused perspective, we outline the potential for HECs in functional applications under extreme environments, where intrinsic stability may provide a new path toward inherently hardened device design. Current works on high entropy carbides, actinide bearing ceramics, and high entropy oxides are reviewed in the areas of radiation, high temperature, and corrosion tolerance where the role of local disorder is shown to create pathways toward self-healing and structural robustness. In this context, new strategies for creating future electronic, magnetic, and optical devices to be operated in harsh environments are outlined.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); USDOE National Nuclear Security Administration (NNSA); USDOE Laboratory Directed Research and Development (LDRD) Program; National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; 89233218CNA000001; DMR-2104228

OSTI ID:: 2323354

Alternate ID(s):: OSTI ID: 2316067; OSTI ID: 2329576; OSTI ID: 2335756

Report Number(s):: LA-UR-23-32255

Journal Information:: JPhys Materials, Vol. 7, Issue 2; ISSN 2515-7639

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

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