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Title: Activation of Small Molecules by Modified Dodecaborate Anions

Journal Article · · Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory

Not Available

Sponsoring Organization:
USDOE
Grant/Contract Number:
FG02-96ER45579; AC02-05CH11231
OSTI ID:
2320291
Alternate ID(s):
OSTI ID: 2326154
Journal Information:
Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory, Journal Name: Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory Journal Issue: 11 Vol. 128; ISSN 1089-5639
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (34)

Electronic Structure and Stability of [B 12 X 12 ] 2– (X = F–At): A Combined Photoelectron Spectroscopic and Theoretical Study journal October 2017
B12X11(H2): exploring the limits of isotopologue selectivity of hydrogen adsorption journal January 2021
Polyhedral skeletal electron pair approach journal September 1984
Superelectrophilic Behavior of an Anion Demonstrated by the Spontaneous Binding of Noble Gases to [B 12 Cl 11 ] journal May 2017
Adsorption and activation of molecular oxygen over atomic copper(I/II) site on ceria journal August 2020
Size and charge effects on the binding of CO to late transition metal clusters journal May 2006
Steric Hindrance of NH3 Diffusion on Pt(111) by Co-Adsorbed O-Atoms journal November 2022
THE ISOLATION OF THE ICOSAHEDRAL B 12 H 12 -2 ION journal June 1960
Boron clusters as broadband membrane carriers journal March 2022
Relevance of π‐Backbonding for the Reactivity of Electrophilic Anions [B 12 X 11 ] (X=F, Cl, Br, I, CN) journal June 2021
On the Oxidation of the Three-Dimensional Aromatics [B 12 X 12 ] 2− (X=F, Cl, Br, I) journal March 2014
Infrared-Driven Charge Transfer in Transition Metal B 12 F 12 Clusters journal July 2015
Synthesis, Crystal Structure, and Reactivity of the Strong Methylating Agent Me2B12Cl12 journal April 2010
Chemistry of Boranes. XXV. Synthesis andc Chemistry of Base Derivatives of B10H102- and B12H122- journal August 1965
Synthesis and Applications of Perfunctionalized Boron Clusters journal February 2018
Ab Initio Study of the Hypercloso Boron Hydrides B n H n and B n H n - . Exceptional Stability of Neutral B 13 H 13 journal May 2000
The structural significance of the number of skeletal bonding electron-pairs in carboranes, the higher boranes and borane anions, and various transition-metal carbonyl cluster compounds journal January 1971
Chemistry of closo-Dodecaborate Anion [B12H12]2-: A Review journal January 2002
Rational design of an argon-binding superelectrophilic anion journal April 2019
Efficient direct fluorination of the B12H11(NH3)− anion in acetonitrile and comparison of the structures of Na(H2O)4(B12F11(NH3)), Na(H3O)(H2O)3(B12F12), and Na2(H2O)4(B12F12) journal November 2017
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density journal January 1988
Reaction Intermediates during the Dehydrogenation of Metal Borohydrides: A Cluster Perspective journal September 2010
STRUCTURE OF B 12 H 12 - 2 ION journal August 1960
Collision-induced gas-phase reactions of perhalogenated closo-dodecaborate clusters – a comparative study journal January 2011
The electronic structure of an icosahedron of boron atoms
  • Longuet-Higgins, Hugh Christopher; Roberts, M. De V.
  • Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, Vol. 230, Issue 1180, p. 110-119 https://doi.org/10.1098/rspa.1955.0115
journal June 1955
A benchmark photoelectron spectroscopic and theoretical study of the electronic stability of [B 12 H 12 ] 2− journal April 2019
Gas phase fragmentation of adducts between dioxygen and closo-borate radical anions journal February 2019
A Unifying Electron-Counting Rule for Macropolyhedral Boranes, Metallaboranes, and Metallocenes
  • Jemmis, Eluvathingal D.; Balakrishnarajan, Musiri M.; Pancharatna, Pattath D.
  • Journal of the American Chemical Society, Vol. 123, Issue 18 https://doi.org/10.1021/ja003233z
journal May 2001
Catalytic Potential of [B12X11]2– (X = F, Cl, Br, I, CN) Dianions journal September 2023
Unusually high stability of B 12 (BO) 12 2− achieved by boronyl ligand manipulation: Theoretical investigation journal April 2018
Synthesis, Electronic Properties and Reactivity of [B 12 X 11 (NO 2 )] 2− (X=F–I) Dianions journal October 2020
Chemistry of Boranes. XIV. Amination of B10H10-2 and B12H12-2 with Hydroxylamine-O-sulfonic Acid journal September 1964
Role of ligands in the stability of B n X n and CB n−1 X n (n = 5–10; X = H, F, CN) and their potential as building blocks of electrolytes in lithium ion batteries journal January 2017
Stability of B 12 (CN) 12 2− : Implications for Lithium and Magnesium Ion Batteries journal February 2016