Substitution of Pb with (Li1/2Bi1/2) in PbZrO3-based antiferroelectric ceramics

Liu, Binzhi; Gaur, Anand P. S.; Cui, Jun; Tan, Xiaoli

doi:10.1142/s2010135x23500224

Title: Substitution of Pb with (Li_1/2Bi_1/2) in PbZrO₃-based antiferroelectric ceramics

Journal Article · 30 October 2023 · Journal of Advanced Dielectrics

DOI: https://doi.org/10.1142/s2010135x23500224 · OSTI ID:2319033

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Iowa State University, Ames, IA (United States); Iowa State University
Iowa State University, Ames, IA (United States)

PbZrO₃-based antiferroelectric (AFE) ceramics are promising dielectrics for high-energy-density capacitors due to their reversible phase transitions during charge–discharge cycles. In this work, a new composition series, [Pb_0.93–xLa_0.02(Li_1/2Bi_1/2)_xSr_0.04][Zr_0.57Sn_0.34Ti_0.09]O₃, with Li⁺ and Bi³⁺ substitution of Pb²⁺ at x=0 , 0.04, 0.08, 0.12, 0.16 is investigated for the microstructure evolution, ferroelectric (FE) and dielectric properties. It is found that Li⁺ and Bi³⁺ substitution can significantly reduce the sintering temperature and simultaneously enhance the dielectric breakdown strength. An ultrahigh energy efficiency (94.0%) and a large energy density (3.22J/cm³) are achieved in the composition of x = 0.12 with a low sintering temperature (1075°C).

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Research Organization:: Iowa State University, Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Materials & Manufacturing Technologies Office (AMMTO)

Grant/Contract Number:: EE0009105

OSTI ID:: 2319033

Journal Information:: Journal of Advanced Dielectrics, Journal Name: Journal of Advanced Dielectrics Journal Issue: 01 Vol. 14; ISSN 2010-135X

Publisher:: World ScientificCopyright Statement

Country of Publication:: United States

Language:: English

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energy efficiency

Title: Substitution of Pb with (Li1/2Bi1/2) in PbZrO3-based antiferroelectric ceramics

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References (48)

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Title: Substitution of Pb with (Li_1/2Bi_1/2) in PbZrO₃-based antiferroelectric ceramics