Uptake of arsenic and selenium on iron-doped Pb resin

Kmak, Kelly N.; Despotopulos, John D.; Scielzo, Nicholas D.

doi:10.1007/s10967-023-09304-6

Title: Uptake of arsenic and selenium on iron-doped Pb resin

Journal Article · 03 January 2024 · Journal of Radioanalytical and Nuclear Chemistry

DOI: https://doi.org/10.1007/s10967-023-09304-6 · OSTI ID:2315091

^[1]; Despotopulos, John D. ^[1]; Scielzo, Nicholas D. ^[1]

Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States). Nuclear and Chemical Sciences Division

We report the uptake of the radioisotopes ⁷³As and ⁷⁵Se was characterized on Fe³⁺-doped Pb resin (Eichrom Technologies) from pH 1 to 12. There is good uptake of arsenic and selenium over a wide pH range (~ 1 to 10) with a decrease only at high pH (~ 12). Column experiments were performed to demonstrate the separations of these elements from solutions with near neutral pH values (~ 6 to 8) with high yields and high radiopurity. These separations may be relevant for a wide variety of applications especially isotope harvesting research.

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Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 2315091

Report Number(s):: LLNL--JRNL-849863; 1075722

Journal Information:: Journal of Radioanalytical and Nuclear Chemistry, Journal Name: Journal of Radioanalytical and Nuclear Chemistry Journal Issue: no. 1 Vol. vol. 333; ISSN 0236-5731

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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