Structural and reactive evolution of oxidatively grafted Pd catalysts on MnO2 for the low-temperature oxidation of CO

Hall, Jacklyn N.; Kropf, A. Jeremy; Kanbur, Uddhav; Dogan, Fulya; Byron, Carly; Wen, Jianguo; Delferro, Massimiliano; Kaphan, David M.

doi:10.1039/d3cc01094e

Title: Structural and reactive evolution of oxidatively grafted Pd catalysts on MnO₂ for the low-temperature oxidation of CO

Journal Article · 10 May 2023 · ChemComm

DOI: https://doi.org/10.1039/d3cc01094e · OSTI ID:2311816

Hall, Jacklyn N. ^[1];

^[1]; Kanbur, Uddhav ^[1]; Dogan, Fulya ^[1]; Byron, Carly ^[1];

^[2];

^[1];

^[1]

Argonne National Laboratory (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
Argonne National Laboratory (ANL), Argonne, IL (United States). Center for Nanoscale Materials (CNM)

We report Isolated Pd atoms supported on high surface area MnO₂, prepared by the oxidative grafting of (bis(tricyclohexylphosphine-palladium(0)), catalyze (>50 turnovers, 17 h) the low temperature (≤325 K) oxidation of CO (7.7 kPa O₂, 2.6 kPa CO) with results of in situ/operando and ex situ spectroscopic characterization signifying a synergistic role of Pd and MnO₂ in facilitating redox turnovers.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2311816

Alternate ID(s):: OSTI ID: 1974076

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 45 Vol. 59; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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