Hierarchical Self-Assembly of Carbon Dots into High-Aspect-Ratio Nanowires

Habteyes, Terefe G.; Westphal, Eric Robert; Plackowski, Kenneth Michael; Kotula, Paul G.; Meyerson, Melissa Lynn; White, Stephanie L.; Corbin, William Cody; Ghosh, Koushik; Grey, John Kenneth

doi:10.1021/acs.nanolett.3c02977

Title: Hierarchical Self-Assembly of Carbon Dots into High-Aspect-Ratio Nanowires

Journal Article · 13 October 2023 · Nano Letters

DOI: https://doi.org/10.1021/acs.nanolett.3c02977 · OSTI ID:2311341

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^[2]; Plackowski, Kenneth Michael ^[3]; Kotula, Paul G. ^[2];

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Univ. of New Mexico, Albuquerque, NM (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Univ. of New Mexico, Albuquerque, NM (United States)

Here, we report a spontaneous and hierarchical self-assembly mechanism of carbon dots prepared from citric acid and urea into nanowire structures with large aspect ratios (>50). Scattering-type scanning near-field optical microscopy (s-SNOM) with broadly tunable mid-IR excitation was used to interrogate details of the self-assembly process by generating nanoscopic chemical maps of local wire morphology and composition. s-SNOM images capture the evolution of wire formation and the complex interplay between different chemical constituents directing assembly over the nano- to microscopic length scales. We propose that residual citrate promotes tautomerization of melamine surface functionalities to produce supramolecular shape synthons comprised of melamine-cyanurate adducts capable of forming long-range and highly directional hydrogen-bonding networks. This intrinsic, heterogeneity-driven self-assembly mechanism reflects synergistic combinations of high chemical specificity and long-range cooperativity that may be harnessed to reproducibly fabricate functional structures on arbitrary surfaces.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Laboratory Directed Research and Development (LDRD) Program; National Science Foundation (NSF)

Grant/Contract Number:: NA0003525; 2154617

OSTI ID:: 2311341

Report Number(s):: SAND-2023-13189J

Journal Information:: Nano Letters, Vol. 23, Issue 20; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (39)

Photoinduced Self‐Assembly of Carbon Nitride Quantum Dots Xing, Zheng; Dong, Kaituo; Pavlopoulos, Nick Angewandte Chemie International Edition, Vol. 60, Issue 35 https://doi.org/10.1002/anie.202107079	journal	July 2021
Synthesis of Carbon Dots with Multiple Color Emission by Controlled Graphitization and Surface Functionalization Miao, Xiang; Qu, Dan; Yang, Dongxue Advanced Materials, Vol. 30, Issue 1 https://doi.org/10.1002/adma.201704740	journal	November 2017
Graphitic carbon nitride nanotubes: a new material for emerging applications Stroyuk, Oleksandr; Raievska, Oleksandra; Zahn, Dietrich R. T. RSC Advances, Vol. 10, Issue 56 https://doi.org/10.1039/D0RA05580H	journal	January 2020
Infrared Spectroscopic Mapping of Single Nanoparticles and Viruses at Nanoscale Resolution Brehm, Markus; Taubner, Thomas; Hillenbrand, Rainer Nano Letters, Vol. 6, Issue 7 https://doi.org/10.1021/nl0610836	journal	July 2006
Discrete boronate ester ladders from the dynamic covalent self-assembly of oligo(phenylene ethynylene) derivatives and phenylenebis(boronic acid) Drogkaris, Vasileios; Northrop, Brian H. Organic Chemistry Frontiers, Vol. 7, Issue 9 https://doi.org/10.1039/D0QO00083C	journal	January 2020
Specificity in Two-Component Signal Transduction Pathways Laub, Michael T.; Goulian, Mark Annual Review of Genetics, Vol. 41, Issue 1 https://doi.org/10.1146/annurev.genet.41.042007.170548	journal	December 2007
Carbon dots with hydrogen bond-controlled aggregation behavior Chang, Shuai; Chen, Bin-Bin; Gao, Ya-Ting The Analyst, Vol. 148, Issue 3 https://doi.org/10.1039/D2AN01858F	journal	January 2023
Citric Acid Derived Carbon Dots, the Challenge of Understanding the Synthesis-Structure Relationship Ren, Junkai; Malfatti, Luca; Innocenzi, Plinio C, Vol. 7, Issue 1 https://doi.org/10.3390/c7010002	journal	December 2020
Luminescence phenomena of carbon dots derived from citric acid and urea – a molecular insight Kasprzyk, Wiktor; Świergosz, Tomasz; Bednarz, Szczepan Nanoscale, Vol. 10, Issue 29 https://doi.org/10.1039/C8NR03602K	journal	January 2018
Molecular Origin and Self-Assembly of Fluorescent Carbon Nanodots in Polar Solvents Sharma, Arjun; Gadly, Trilochan; Neogy, Suman The Journal of Physical Chemistry Letters, Vol. 8, Issue 5 https://doi.org/10.1021/acs.jpclett.7b00170	journal	February 2017
Complex shapes self-assembled from single-stranded DNA tiles Wei, Bryan; Dai, Mingjie; Yin, Peng Nature, Vol. 485, Issue 7400 https://doi.org/10.1038/nature11075	journal	May 2012
Self-assembling fluorescent hydrogel for highly efficient water purification and photothermal conversion Li, Meng; Yang, Mengqing; Liu, Bowen Chemical Engineering Journal, Vol. 431 https://doi.org/10.1016/j.cej.2021.134245	journal	March 2022
Self-assembly of surface functionalized amphiphilic carbon dots: tuning in morphological manifestations Sarkar, Saheli; Dinda, Soumik; Choudhury, Pritam Soft Matter, Vol. 15, Issue 13 https://doi.org/10.1039/C9SM00051H	journal	January 2019
Citric acid as complexing agent in synthesis of mesoporous strontium titanate via neutral-templated self-assembly sol–gel combustion method Lertpanyapornchai, Boontawee; Yokoi, Toshiyuki; Ngamcharussrivichai, Chawalit Microporous and Mesoporous Materials, Vol. 226 https://doi.org/10.1016/j.micromeso.2016.02.020	journal	May 2016
The Role of Surface Groups in Dictating the Chiral‐Solvent‐Induced Assembly of Carbon Dots into Structures Exhibiting Circularly Polarized Luminescence Basu, Srestha; Amdursky, Nadav Small, Vol. 19, Issue 8 https://doi.org/10.1002/smll.202205880	journal	December 2022
Induced Supramolecular Chirality in Nanostructured Materials: Ionic Self-Assembly of Perylene-Chiral Surfactant Complexes Franke, Danielle; Vos, Matthijn; Antonietti, Markus Chemistry of Materials, Vol. 18, Issue 7 https://doi.org/10.1021/cm0525499	journal	March 2006
Large and Emissive Crystals from Carbon Quantum Dots onto Interfacial Organized Templates Xiong, Rui; Zhang, Xiaofang; Krecker, Michelle Angewandte Chemie International Edition, Vol. 59, Issue 45 https://doi.org/10.1002/anie.202008748	journal	August 2020
Absorption Spectra and Tautomerism of Cyanuric Acid, Melamine and Some Related Compounds Klotz, Irving M.; Askounis, Themis Journal of the American Chemical Society, Vol. 69, Issue 4 https://doi.org/10.1021/ja01196a017	journal	April 1947
The Spectral Signatures of Frenkel Polarons in H- and J-Aggregates Spano, Frank C. Accounts of Chemical Research, Vol. 43, Issue 3 https://doi.org/10.1021/ar900233v	journal	March 2010
In Situ Visualization of Self-Assembly of Charged Gold Nanoparticles Liu, Yuzi; Lin, Xiao-Min; Sun, Yugang Journal of the American Chemical Society, Vol. 135, Issue 10 https://doi.org/10.1021/ja312620e	journal	February 2013
Poly(ionic liquid)-Assisted Synthesis of Open-Ended Carbon Nitride Tube for Efficient Photocatalytic Hydrogen Evolution under Visible-Light Irradiation Zhao, Shuo; Fang, Jiasheng; Wang, Yanyun ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 11 https://doi.org/10.1021/acssuschemeng.9b01544	journal	May 2019
A new approach to measure melamine, cyanuric acid, and melamine cyanurate using surface enhanced Raman spectroscopy coupled with gold nanosubstrates He, Lili; Liu, Yang; Lin, Mengshi Sensing and Instrumentation for Food Quality and Safety, Vol. 2, Issue 1 https://doi.org/10.1007/s11694-008-9038-0	journal	March 2008
Multiple mode exciton-vibrational coupling in H-aggregates: Synergistic enhancement of the quantum yield Spano, F. C.; Silvestri, Leonardo The Journal of Chemical Physics, Vol. 132, Issue 9 https://doi.org/10.1063/1.3310810	journal	March 2010
Insights into photoluminescence mechanisms of carbon dots: advances and perspectives Ai, Lin; Yang, Yisen; Wang, Boyang Science Bulletin, Vol. 66, Issue 8 https://doi.org/10.1016/j.scib.2020.12.015	journal	April 2021
Tracking the Source of Carbon Dot Photoluminescence: Aromatic Domains versus Molecular Fluorophores Ehrat, Florian; Bhattacharyya, Santanu; Schneider, Julian Nano Letters, Vol. 17, Issue 12 https://doi.org/10.1021/acs.nanolett.7b03863	journal	November 2017
Synthesis and Photoluminescence Mechanism of Multicolored Nitrogen-Doped Carbon Nanodots and Their Application in Polymer Self-Assemblies Xie, Wenyuan; Yu, Xing; Tian, Tian ACS Applied Polymer Materials, Vol. 4, Issue 7 https://doi.org/10.1021/acsapm.2c00385	journal	June 2022
Molecular Fluorophores Self-Organize into C-Dot Seeds and Incorporate into C-Dot Structures Langer, Michal; Paloncýová, Markéta; Medved’, Miroslav The Journal of Physical Chemistry Letters, Vol. 11, Issue 19 https://doi.org/10.1021/acs.jpclett.0c01873	journal	August 2020
Citric Acid-Based Carbon Dots and Their Application in Energy Conversion Vallan, Lorenzo; Imahori, Hiroshi ACS Applied Electronic Materials, Vol. 4, Issue 9 https://doi.org/10.1021/acsaelm.2c01021	journal	September 2022
The Effect of Hydrogen Bonding on Self‐Assembled Polyaniline Nanostructures Zhang, L.; Long, Y.; Chen, Z. Advanced Functional Materials, Vol. 14, Issue 7 https://doi.org/10.1002/adfm.200305020	journal	July 2004
Large-Area Carbon Nanosheets Doped with Phosphorus: A High-Performance Anode Material for Sodium-Ion Batteries Hou, Hongshuai; Shao, Lidong; Zhang, Yan Advanced Science, Vol. 4, Issue 1 https://doi.org/10.1002/advs.201600243	journal	September 2016
Constraints imposed by non‐functional protein–protein interactions on gene expression and proteome size Zhang, Jingshan; Maslov, Sergei; Shakhnovich, Eugene I. Molecular Systems Biology, Vol. 4, Issue 1 https://doi.org/10.1038/msb.2008.48	journal	January 2008
Supra-(carbon dots) with versatile morphologies and promising optical properties Li, Di; Qu, Yanfei; Zhang, Xiaoyu Chemical Engineering Journal, Vol. 454 https://doi.org/10.1016/j.cej.2022.140069	journal	February 2023
Undesired usage and the robust self-assembly of heterogeneous structures Murugan, Arvind; Zou, James; Brenner, Michael P. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7203	journal	February 2015
Theoretical Understanding of Structure–Property Relationships in Luminescence of Carbon Dots Yu, Jingkun; Yong, Xue; Tang, Zhiyong The Journal of Physical Chemistry Letters, Vol. 12, Issue 32 https://doi.org/10.1021/acs.jpclett.1c01856	journal	August 2021
Shedding light on the effective fluorophore structure of high fluorescence quantum yield carbon nanodots Wang, W.; Wang, B.; Embrechts, H. RSC Advances, Vol. 7, Issue 40 https://doi.org/10.1039/C7RA04421F	journal	January 2017
FT-Raman Determination of Melamine and Melamine Cyanurate in Nylon Tseng, Ching-Hui; Mann, Charles K.; Vickers, Thomas J. Applied Spectroscopy, Vol. 48, Issue 4 https://doi.org/10.1366/000370294775268857	journal	April 1994
Molecular Sensitivity of Near-Field Vibrational Infrared Imaging Wang, Chih-Feng; Kafle, Bijesh; Tesema, Tefera E. The Journal of Physical Chemistry C, Vol. 124, Issue 38 https://doi.org/10.1021/acs.jpcc.0c07979	journal	September 2020
Three-Dimensional Structures Self-Assembled from DNA Bricks Ke, Y.; Ong, L. L.; Shih, W. M. Science, Vol. 338, Issue 6111 https://doi.org/10.1126/science.1227268	journal	November 2012
Nanoscale Infrared Absorption Spectroscopy of Individual Nanoparticles Enabled by Scattering-Type Near-Field Microscopy Stiegler, Johannes M.; Abate, Yohannes; Cvitkovic, Antonija ACS Nano, Vol. 5, Issue 8 https://doi.org/10.1021/nn2017638	journal	July 2011

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Title: Hierarchical Self-Assembly of Carbon Dots into High-Aspect-Ratio Nanowires

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