Dual Lithiophilic Structure for Uniform Li Deposition

Yuan, Shouyi; Bao, Junwei Lucas; Li, Chao; Xia, Yongyao; Truhlar, Donald G.; Wang, Yonggang

doi:10.1021/acsami.8b19654

Title: Dual Lithiophilic Structure for Uniform Li Deposition

Journal Article · 25 February 2019 · ACS Applied Materials and Interfaces

DOI: https://doi.org/10.1021/acsami.8b19654 · OSTI ID:2311177

Yuan, Shouyi ^[1]; Bao, Junwei Lucas ^[2]; Li, Chao ^[3];

^[3];

^[2];

^[3]

Fudan University, Shanghai (China); University of Minnesota
University of Minnesota, Minneapolis, MN (United States)
Fudan University, Shanghai (China)

The development of Li metal anode is hindered by the Li dendrites arising from the random deposition of Li metal during cycles. Hence, uniform deposition of Li during repeated cycles is crucial for the development of Li metal batteries. However, it is difficult to regulate Li deposition due to convection in the electrolyte. Here, we employ a dual lithiophilic structure composed of polar metal organic framework (MOF) and highly conductive Ag nanoparticles, and we show that it brings about uniform lithium deposition. Here, the binding energy for Li is increased by the abundant oxygen sites and large surface area of the MOF, and concomitantly the uniform distribution of Li nuclei can be achieved with a low nucleation overpotential. When highly conductive lithiophilic Ag is incorporated into the MOF, the binding energy for Li is further increased and the nucleation overpotential is decreased to nearly zero. As a result, Li platting and stripping on the Ag@MOF (i.e., Ag@HKUST-1) substrate exhibits a Coulombic efficiency (CE) of 97% over 300 cycles and a high areal capacity of 5 mAh cm^-2 without dendrite formation.

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Research Organization:: University of Minnesota, Minneapolis, MN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0008688

OSTI ID:: 2311177

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 11 Vol. 11; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (51)

Synergistic Effect of Graphene Oxide for Impeding the Dendritic Plating of Li Foroozan, Tara; Soto, Fernando A.; Yurkiv, Vitaliy Advanced Functional Materials, Vol. 28, Issue 15 https://doi.org/10.1002/adfm.201705917	journal	February 2018
Dendrite-Free Lithium Deposition Induced by Uniformly Distributed Lithium Ions for Efficient Lithium Metal Batteries Cheng, Xin-Bing; Hou, Ting-Zheng; Zhang, Rui Advanced Materials, Vol. 28, Issue 15 https://doi.org/10.1002/adma.201506124	journal	February 2016
Chemical Dealloying Derived 3D Porous Current Collector for Li Metal Anodes Yun, Qinbai; He, Yan-Bing; Lv, Wei Advanced Materials, Vol. 28, Issue 32 https://doi.org/10.1002/adma.201601409	journal	May 2016
Graphitized Carbon Fibers as Multifunctional 3D Current Collectors for High Areal Capacity Li Anodes Zuo, Tong-Tong; Wu, Xiong-Wei; Yang, Chun-Peng Advanced Materials, Vol. 29, Issue 29 https://doi.org/10.1002/adma.201700389	journal	June 2017
Protected Lithium-Metal Anodes in Batteries: From Liquid to Solid Yang, Chunpeng; Fu, Kun; Zhang, Ying Advanced Materials, Vol. 29, Issue 36 https://doi.org/10.1002/adma.201701169	journal	July 2017
Ultrafine Silver Nanoparticles for Seeded Lithium Deposition toward Stable Lithium Metal Anode Yang, Chunpeng; Yao, Yonggang; He, Shuaiming Advanced Materials, Vol. 29, Issue 38 https://doi.org/10.1002/adma.201702714	journal	August 2017
Mixed Ionic and Electronic Conductor for Li-Metal Anode Protection Yan, Jianhua; Yu, Jianyong; Ding, Bin Advanced Materials, Vol. 30, Issue 7 https://doi.org/10.1002/adma.201705105	journal	January 2018
Developing a “Water-Defendable” and “Dendrite-Free” Lithium-Metal Anode Using a Simple and Promising GeCl ₄ Pretreatment Method Liao, Kaiming; Wu, Shichao; Mu, Xiaowei Advanced Materials, Vol. 30, Issue 36 https://doi.org/10.1002/adma.201705711	journal	July 2018
Lithiophilic Cu-CuO-Ni Hybrid Structure: Advanced Current Collectors Toward Stable Lithium Metal Anodes Wu, Shuilin; Zhang, Zhenyu; Lan, Minhuan Advanced Materials, Vol. 30, Issue 9 https://doi.org/10.1002/adma.201705830	journal	January 2018
Lithium Metal Anodes: Dual‐Layered Film Protected Lithium Metal Anode to Enable Dendrite‐Free Lithium Deposition (Adv. Mater. 25/2018) Yan, Chong; Cheng, Xin‐Bing; Tian, Yang Advanced Materials, Vol. 30, Issue 25 https://doi.org/10.1002/adma.201870181	journal	June 2018
Graphene-Supported Nitrogen and Boron Rich Carbon Layer for Improved Performance of Lithium-Sulfur Batteries Due to Enhanced Chemisorption of Lithium Polysulfides Yuan, Shouyi; Bao, Junwei Lucas; Wang, Lina Advanced Energy Materials, Vol. 6, Issue 5 https://doi.org/10.1002/aenm.201501733	journal	December 2015
Advanced Porous Carbon Materials for High-Efficient Lithium Metal Anodes Ye, Huan; Xin, Sen; Yin, Ya-Xia Advanced Energy Materials, Vol. 7, Issue 23 https://doi.org/10.1002/aenm.201700530	journal	July 2017
Vertically Aligned Lithiophilic CuO Nanosheets on a Cu Collector to Stabilize Lithium Deposition for Lithium Metal Batteries Zhang, Chen; Lv, Wei; Zhou, Guangmin Advanced Energy Materials, Vol. 8, Issue 21 https://doi.org/10.1002/aenm.201703404	journal	April 2018
Compact 3D Copper with Uniform Porous Structure Derived by Electrochemical Dealloying as Dendrite-Free Lithium Metal Anode Current Collector Zhao, Heng; Lei, Danni; He, Yan-Bing Advanced Energy Materials, Vol. 8, Issue 19 https://doi.org/10.1002/aenm.201800266	journal	March 2018
An Efficient Three-Dimensional Oxygen Evolution Electrode Wang, Jun; Zhong, Hai-xia; Qin, Yu-ling Angewandte Chemie International Edition, Vol. 52, Issue 20 https://doi.org/10.1002/anie.201301066	journal	April 2013
Lithiophilic Sites in Doped Graphene Guide Uniform Lithium Nucleation for Dendrite-Free Lithium Metal Anodes Zhang, Rui; Chen, Xiao-Ru; Chen, Xiang Angewandte Chemie International Edition, Vol. 56, Issue 27 https://doi.org/10.1002/anie.201702099	journal	May 2017
Back Cover: Lithium Nitrate Solvation Chemistry in Carbonate Electrolyte Sustains High‐Voltage Lithium Metal Batteries (Angew. Chem. Int. Ed. 43/2018) Yan, Chong; Yao, Yu‐Xing; Chen, Xiang Angewandte Chemie International Edition, Vol. 57, Issue 43 https://doi.org/10.1002/anie.201811031	journal	October 2018
Effect of the damping function in dispersion corrected density functional theory Grimme, Stefan; Ehrlich, Stephan; Goerigk, Lars Journal of Computational Chemistry, Vol. 32, Issue 7 https://doi.org/10.1002/jcc.21759	journal	March 2011
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Metal-organic framework nanosheets-guided uniform lithium deposition for metallic lithium batteries Jiang, Zhanguo; Liu, Tiefeng; Yan, Lijing Energy Storage Materials, Vol. 11 https://doi.org/10.1016/j.ensm.2017.11.003	journal	March 2018
Crumpled Graphene Balls Stabilized Dendrite-free Lithium Metal Anodes Liu, Shan; Wang, Aoxuan; Li, Qianqian Joule, Vol. 2, Issue 1 https://doi.org/10.1016/j.joule.2017.11.004	journal	January 2018
An In Vivo Formed Solid Electrolyte Surface Layer Enables Stable Plating of Li Metal Pang, Quan; Liang, Xiao; Shyamsunder, Abhinandan Joule, Vol. 1, Issue 4 https://doi.org/10.1016/j.joule.2017.11.009	journal	December 2017
Cu 3 (1,3,5-benzenetricarboxylate) 2 metal-organic framework: A promising anode material for lithium-ion battery Maiti, Sandipan; Pramanik, Atin; Manju, Unnikrishnan Microporous and Mesoporous Materials, Vol. 226 https://doi.org/10.1016/j.micromeso.2016.02.011	journal	May 2016
3D lithium metal embedded within lithiophilic porous matrix for stable lithium metal batteries Jin, Chengbin; Sheng, Ouwei; Luo, Jianmin Nano Energy, Vol. 37 https://doi.org/10.1016/j.nanoen.2017.05.015	journal	July 2017
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi Chemical Reviews, Vol. 117, Issue 15 https://doi.org/10.1021/acs.chemrev.7b00115	journal	July 2017
Free-Standing Copper Nanowire Network Current Collector for Improving Lithium Anode Performance Lu, Lei-Lei; Ge, Jin; Yang, Jun-Nan Nano Letters, Vol. 16, Issue 7 https://doi.org/10.1021/acs.nanolett.6b01581	journal	June 2016
Carbon-Free CoO Mesoporous Nanowire Array Cathode for High-Performance Aprotic Li–O₂ Batteries Wu, Baoshan; Zhang, Hongzhang; Zhou, Wei ACS Applied Materials & Interfaces, Vol. 7, Issue 41 https://doi.org/10.1021/acsami.5b07003	journal	October 2015
Dual-Functional Graphene Carbon as Polysulfide Trapper for High-Performance Lithium Sulfur Batteries Zhang, Linlin; Wan, Fang; Wang, Xinyu ACS Applied Materials & Interfaces, Vol. 10, Issue 6 https://doi.org/10.1021/acsami.7b18894	journal	February 2018
In Situ Plating of Porous Mg Network Layer to Reinforce Anode Dendrite Suppression in Li-Metal Batteries Chu, Fulu; Hu, Jiulin; Tian, Jing ACS Applied Materials & Interfaces, Vol. 10, Issue 15 https://doi.org/10.1021/acsami.8b00989	journal	December 2017
Spherical Li Deposited inside 3D Cu Skeleton as Anode with Ultrastable Performance Wang, Yanyan; Wang, Zhijie; Lei, Danni ACS Applied Materials & Interfaces, Vol. 10, Issue 24 https://doi.org/10.1021/acsami.8b04881	journal	May 2018
Hierarchically Porous Carbon Encapsulating Sulfur as a Superior Cathode Material for High Performance Lithium–Sulfur Batteries Xu, Guiyin; Ding, Bing; Nie, Ping ACS Applied Materials & Interfaces, Vol. 6, Issue 1 https://doi.org/10.1021/am4038728	journal	December 2013
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries Suo, Liumin; Hu, Yong-Sheng; Li, Hong Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2513	journal	February 2013
General incorporation of diverse components inside metal-organic framework thin films at room temperature Mao, Yiyin; Li, Junwei; Cao, Wei Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6532	journal	November 2014
Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth Yan, Kai; Lu, Zhenda; Lee, Hyun-Wook Nature Energy, Vol. 1, Issue 3, Article No. 16010 https://doi.org/10.1038/nenergy.2016.10	journal	February 2016
Metal–organic framework-based separator for lithium–sulfur batteries Bai, Songyan; Liu, Xizheng; Zhu, Kai Nature Energy, Vol. 1, Issue 7 https://doi.org/10.1038/nenergy.2016.94	journal	June 2016
Electrolyte additive enabled fast charging and stable cycling lithium metal batteries Zheng, Jianming; Engelhard, Mark H.; Mei, Donghai Nature Energy, Vol. 2, Issue 3 https://doi.org/10.1038/nenergy.2017.12	journal	March 2017
Erratum: Li–O2 and Li–S batteries with high energy storage Bruce, Peter G.; Freunberger, Stefan A.; Hardwick, Laurence J. Nature Materials, Vol. 11, Issue 2 https://doi.org/10.1038/nmat3237	journal	December 2011
Interconnected hollow carbon nanospheres for stable lithium metal anodes Zheng, Guangyuan; Lee, Seok Woo; Liang, Zheng Nature Nanotechnology, Vol. 9, Issue 8 https://doi.org/10.1038/nnano.2014.152	journal	July 2014
Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries Fan, Xiulin; Chen, Long; Borodin, Oleg Nature Nanotechnology, Vol. 13, Issue 8 https://doi.org/10.1038/s41565-018-0183-2	journal	July 2018
Lithium metal anodes for rechargeable batteries Xu, Wu; Wang, Jiulin; Ding, Fei Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/c3ee40795k	journal	January 2014
Functional metal–organic framework boosting lithium metal anode performance via chemical interactions Liu, Wen; Mi, Yingying; Weng, Zhe Chemical Science, Vol. 8, Issue 6 https://doi.org/10.1039/c7sc00668c	journal	January 2017
Three-dimensional stable lithium metal anode with nanoscale lithium islands embedded in ionically conductive solid matrix Lin, Dingchang; Zhao, Jie; Sun, Jie Proceedings of the National Academy of Sciences, Vol. 114, Issue 18 https://doi.org/10.1073/pnas.1619489114	journal	April 2017
Bio-inspired low-tortuosity carbon host for high-performance lithium-metal anode Yin, Yi-Chen; Yu, Zhi-Long; Ma, Zhi-Yuan National Science Review, Vol. 6, Issue 2 https://doi.org/10.1093/nsr/nwy148	journal	November 2018
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/physrevb.13.5188	journal	June 1976
Ab initiomolecular dynamics for liquid metals Kresse, G.; Hafner, J. Physical Review B, Vol. 47, Issue 1, p. 558-561 https://doi.org/10.1103/physrevb.47.558	journal	January 1993
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/physrevb.50.17953	journal	December 1994
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/physrevb.59.1758	journal	January 1999
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/physrevlett.77.3865	journal	October 1996
A “cation-anion regulation” synergistic anode host for dendrite-free lithium metal batteries Zhang, Weidong; Zhuang, Houlong L.; Fan, Lei Science Advances, Vol. 4, Issue 2 https://doi.org/10.1126/sciadv.aar4410	journal	February 2018
A Chemically Functionalizable Nanoporous Material [Cu₃(TMA)₂(H₂O)₃]_n Chui, Stephen S.-Y.; Lo, Samuel M.-F.; Charmant, Jonathan P. H. Science, Vol. 283, Issue 5405, p. 1148-1150 https://doi.org/10.1126/science.283.5405.1148	journal	February 1999
Preparation and Characterization of Ag Nanoparticles Embedded in Hierarchically Porous Monolithic Silica Huan, Yu; Hui, Yang Acta Physico-Chimica Sinica, Vol. 30, Issue 7 https://doi.org/10.3866/PKU.WHXB201405122	journal	January 2014

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Title: Dual Lithiophilic Structure for Uniform Li Deposition

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