Electrical Conductivities and Association Constants in Dilute Aqueous NdCl3Solutions from 298 to 523 K along an Isobar of 25 MPa

Yoon, Tae Jun; Craddock, Erica P.; Maerzke, Katie A.; Currier, Robert P.; Findikoglu, Alp T.

doi:10.1021/acs.jced.1c00844

Title: Electrical Conductivities and Association Constants in Dilute Aqueous NdCl₃Solutions from 298 to 523 K along an Isobar of 25 MPa

Journal Article · 07 February 2022 · Journal of Chemical and Engineering Data

DOI: https://doi.org/10.1021/acs.jced.1c00844 · OSTI ID:2310322

^[1]; Craddock, Erica P. ^[1];

^[1]; Currier, Robert P. ^[1]; Findikoglu, Alp T. ^[1]

Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Here, electrical measurements were performed in dilute aqueous NdCl₃ solutions from 298 to 523 K along the 25 MPa isobar to obtain limiting conductivities and association constants. The specific conductivity data were estimated using a continuous flow cell and a Markov Chain Monte Carlo (MCMC) correction algorithm. The limiting conductivities for the salts in water were derived by regressing the mean spherical approximation model and speciation analyses based on the MCMC algorithm and the deep earth water model. The limiting conductivities derived from the experimental data were correlated using the Zimmerman-Arcis-Tremaine correlation and agreed well with a predictive correlation proposed by Smolyakov, Anderko, and Lencka. Only the first association constant between neodymium and chloride could be derived at low temperatures (<373 K) due to the apparent large statistical uncertainty of the second association constant. Above 373 K, both association constants could be derived and show a reasonable agreement with Migdisov and Williams-Jones and Gammons et al.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: 89233218CNA000001

OSTI ID:: 2310322

Report Number(s):: LA-UR--21-30907

Journal Information:: Journal of Chemical and Engineering Data, Journal Name: Journal of Chemical and Engineering Data Journal Issue: 3 Vol. 67; ISSN 0021-9568

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Electrical Conductivities and Association Constants in Dilute Aqueous NdCl₃Solutions from 298 to 523 K along an Isobar of 25 MPa