Side chain engineering in indacenodithiophene- co -benzothiadiazole and its impact on mixed ionic–electronic transport properties

Holzer, Isabelle; Lemaur, Vincent; Wang, Meng; Wu, Han-Yan; Zhang, Lu; Marcial-Hernandez, Raymundo; Gilhooly-Finn, Peter; Cavassin, Priscila; Hoyas, Sébastien; Meli, Dilara; Wu, Ruiheng; Paulsen, Bryan D.; Strzalka, Joseph; Liscio, Andrea; Rivnay, Jonathan; Sirringhaus, Henning; Banerji, Natalie; Beljonne, David; Fabiano, Simone; Nielsen, Christian B.

doi:10.1039/D3TC04738E

Title: Side chain engineering in indacenodithiophene- co -benzothiadiazole and its impact on mixed ionic–electronic transport properties

Journal Article · 06 March 2024 · Journal of Materials Chemistry C

DOI: https://doi.org/10.1039/D3TC04738E · OSTI ID:2309830

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^[2]; Wang, Meng ^[3]; Wu, Han-Yan ^[4]; Zhang, Lu ^[5];

^[6]; Gilhooly-Finn, Peter ^[6]; Cavassin, Priscila ^[1]; Hoyas, Sébastien ^[7]; Meli, Dilara ^[8]; Wu, Ruiheng ^[9];

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^[13]; Sirringhaus, Henning ^[5];

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Department of Chemistry, Biochemistry and Pharmaceutical Sciences (DCBP), University of Bern, Freiestrasse 3, 3012 Bern, Switzerland
Laboratory for the Chemistry of Novel Materials, Materials Research Institute, University of Mons, Place du Parc 20, Mons, BE-7000, Belgium
Department of Chemistry, Queen Mary University of London, Mile End Road, London E1 4NS, UK, i-Lab & Printable Electronics Research Center, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, 398 Ruoshui Road, SEID, SIP, Suzhou, 215123, P. R. China
Laboratory of Organic Electronics, Department of Science and Technology, Linköping University, SE-601 74 Norrköping, Sweden
Optoelectronics Group, Cavendish Laboratory, JJ Thomson Avenue, Cambridge CB3 0HE, UK
Department of Chemistry, Queen Mary University of London, Mile End Road, London E1 4NS, UK
Laboratory for the Chemistry of Novel Materials, Materials Research Institute, University of Mons, Place du Parc 20, Mons, BE-7000, Belgium, Organic Synthesis & Mass Spectrometry Laboratory, Interdisciplinary Center for Mass Spectrometry (CISMa), Center of Innovation and Research in Materials and Polymers (CIRMAP), University of Mons – UMONS, 23 Place du Parc, 7000 Mons, Belgium
Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois 60208, USA
Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA
Department of Biomedical Engineering, Northwestern University, Evanston, Illinois 60208, USA
X-Ray Science Division, Argonne National Laboratory, Lemont, Illinois 60439, USA
Istituto per la Microelettronica e Microsistemi, CNR, Roma Unit, via del fosso del cavaliere 100, 00133 Roma, Italy
Department of Biomedical Engineering, Northwestern University, Evanston, Illinois 60208, USA, Simpson Querrey Institute, Northwestern University, Chicago, Illinois 60611, USA

This well-studied polymer system does not conform to existing design criteria for imparting mixed conduction. The reasons for this anomalous behaviour are unravelled and used to outline more robust design criteria for new organic semiconductors.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; AC02-06CH11357

OSTI ID:: 2309830

Journal Information:: Journal of Materials Chemistry C, Journal Name: Journal of Materials Chemistry C Journal Issue: 10 Vol. 12; ISSN JMCCCX; ISSN 2050-7526

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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