Alumina Incorporation in Self-Supported Poly(ethylenimine) Sorbents for Direct Air Capture

Narayanan, Pavithra; Guntupalli, Pranav; Lively, Ryan P.; Jones, Christopher W.

doi:10.1021/cbe.3c00079

Title: Alumina Incorporation in Self-Supported Poly(ethylenimine) Sorbents for Direct Air Capture

Journal Article · 20 February 2024 · Chem & Bio Engineering

DOI: https://doi.org/10.1021/cbe.3c00079 · OSTI ID:2309816

^[1]; Guntupalli, Pranav ^[1];

^[1];

^[1]

School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, United States

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0012577

OSTI ID:: 2309816

Journal Information:: Chem & Bio Engineering, Journal Name: Chem & Bio Engineering Journal Issue: 2 Vol. 1; ISSN 2836-967X

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (69)

Ice‐Templated, Large‐Area Silver Nanowire Pattern for Flexible Transparent Electrode Han, Jingkai; Yang, Jiankui; Gao, Weiwei Advanced Functional Materials, Vol. 31, Issue 16 https://doi.org/10.1002/adfm.202010155	journal	February 2021
Ice‐Templating: Integrative Ice Frozen Assembly to Tailor Pore Morphology of Energy Storage and Conversion Devices Zhao, Feng; Lin, Lin; Zhang, Jian Advanced Materials Technologies, Vol. 8, Issue 11 https://doi.org/10.1002/admt.202201968	journal	April 2023
Macroscopic Free-Standing Hierarchical 3D Architectures Assembled from Silver Nanowires by Ice Templating Gao, Huai-Ling; Xu, Liang; Long, Fei Angewandte Chemie International Edition, Vol. 53, Issue 18 https://doi.org/10.1002/anie.201400457	journal	March 2014
Sorbents for the Direct Capture of CO ₂ from Ambient Air Shi, Xiaoyang; Xiao, Hang; Azarabadi, Habib Angewandte Chemie International Edition, Vol. 59, Issue 18 https://doi.org/10.1002/anie.201906756	journal	February 2020
Aminosilanes Grafted to Basic Alumina as CO ₂ Adsorbents-Role of Grafting Conditions on CO ₂ Adsorption Properties Bali, Sumit; Leisen, Johannes; Foo, Guo Shiou ChemSusChem, Vol. 7, Issue 11 https://doi.org/10.1002/cssc.201402373	journal	September 2014
Poly(ethylenimine)-Functionalized Monolithic Alumina Honeycomb Adsorbents for CO ₂ Capture from Air Sakwa-Novak, Miles A.; Yoo, Chun-Jae; Tan, Shuai ChemSusChem, Vol. 9, Issue 14 https://doi.org/10.1002/cssc.201600404	journal	June 2016
Oxide-supported tetraethylenepentamine for CO ₂ capture Fisher, James C.; Tanthana, Jak; Chuang, Steven S. C. Environmental Progress & Sustainable Energy, Vol. 28, Issue 4 https://doi.org/10.1002/ep.10363	journal	December 2009
Synthesis and Structure–Property Relationships of Cryogels Okay, Oguz; Lozinsky, Vladimir I. Polymeric Cryogels https://doi.org/10.1007/978-3-319-05846-7_3	book	January 2014
Aluminum. I. Measurement of the relative enthalpy from 273 to 929 K and derivation of thermodynamic functions for Al(s) from 0 K to Its melting point Ditmars, D. A.; Plint, C. A.; Shukla, R. C. International Journal of Thermophysics, Vol. 6, Issue 5 https://doi.org/10.1007/BF00508893	journal	September 1985
Study of cryostructurization of polymer systems Vainerman, E. S.; Lozinsky, V. I.; Rogozhin, S. V. Colloid and Polymer Science, Vol. 259, Issue 12 https://doi.org/10.1007/BF01525014	journal	December 1981
Recent advances in development of amine functionalized adsorbents for CO2 capture Gelles, Teresa; Lawson, Shane; Rownaghi, Ali A. Adsorption, Vol. 26, Issue 1 https://doi.org/10.1007/s10450-019-00151-0	journal	August 2019
The oxidation of viscose fiber optimized by response surface methodology and its further amination with PEI for CO2 adsorption He, Hui; Hou, Xunan; Ma, Beibei Cellulose, Vol. 23, Issue 4 https://doi.org/10.1007/s10570-016-0955-5	journal	May 2016
A Novel Process for Renewable Methane Production: Combining Direct Air Capture by K2CO3/Alumina Sorbent with CO2 Methanation over Ru/Alumina Catalyst Veselovskaya, Janna V.; Parunin, Pavel D.; Netskina, Olga V. Topics in Catalysis, Vol. 61, Issue 15-17 https://doi.org/10.1007/s11244-018-0997-z	journal	May 2018
Research needs targeting direct air capture of carbon dioxide: Material & process performance characteristics under realistic environmental conditions Kong, Fanhe; Rim, Guanhe; Song, MinGyu Korean Journal of Chemical Engineering, Vol. 39, Issue 1 https://doi.org/10.1007/s11814-021-0976-0	journal	January 2022
The effect of crystallite shape and size distribution on diffusion measurements in molecular sieves Ruthven, D. M.; Loughlin, K. F. Chemical Engineering Science, Vol. 26, Issue 5 https://doi.org/10.1016/0009-2509(71)86002-5	journal	June 1971
An adiabatic calorimeter for heat-capacity measurements between 6 and 300 K. The molar heat capacity of aluminium Downie, D. B.; Martin, J. F. The Journal of Chemical Thermodynamics, Vol. 12, Issue 8 https://doi.org/10.1016/0021-9614(80)90176-7	journal	August 1980
Characterization of commercially available and synthesized polyethylenimines for gene delivery von Harpe, Anke; Petersen, Holger; Li, Youxin Journal of Controlled Release, Vol. 69, Issue 2 https://doi.org/10.1016/S0168-3659(00)00317-5	journal	November 2000
Electrical swing adsorption on functionalized hollow fibers Keller, Laura; Lohaus, Theresa; Abduly, Lorenz Chemical Engineering Journal, Vol. 371 https://doi.org/10.1016/j.cej.2019.04.029	journal	September 2019
Optimum structured adsorbents for gas separation processes Rezaei, Fateme; Webley, Paul Chemical Engineering Science, Vol. 64, Issue 24 https://doi.org/10.1016/j.ces.2009.08.029	journal	December 2009
Stability of amine-based hollow fiber CO2 adsorbents in the presence of NO and SO2 Fan, Yanfang; Rezaei, Fateme; Labreche, Ying Fuel, Vol. 160 https://doi.org/10.1016/j.fuel.2015.07.072	journal	November 2015
Modelling of equilibrium working capacity of PSA, TSA and TVSA processes for CO 2 adsorption under direct air capture conditions Elfving, Jere; Bajamundi, Cyril; Kauppinen, Juho Journal of CO2 Utilization, Vol. 22 https://doi.org/10.1016/j.jcou.2017.10.010	journal	December 2017
Sorbent-coated carbon fibers for direct air capture using electrically driven temperature swing adsorption Lee, Won Hee; Zhang, Xin; Banerjee, Sayan Joule, Vol. 7, Issue 6 https://doi.org/10.1016/j.joule.2023.05.016	journal	June 2023
Preparation of polyvinylidene fluoride hollow fiber membranes for CO2 absorption using phase-inversion promoter additives Mansourizadeh, A.; Ismail, A. F.; Abdullah, M. S. Journal of Membrane Science, Vol. 355, Issue 1-2 https://doi.org/10.1016/j.memsci.2010.03.031	journal	June 2010
CO 2 capture by functionalized alumina sorbents: DiEthanolAmine on γ-alumina Castellazzi, P.; Notaro, M.; Busca, G. Microporous and Mesoporous Materials, Vol. 226 https://doi.org/10.1016/j.micromeso.2016.02.027	journal	May 2016
Functionalization of hierarchically porous silica monoliths with polyethyleneimine (PEI) for CO 2 adsorption Guo, Xingzhong; Ding, Li; Kanamori, Kazuyoshi Microporous and Mesoporous Materials, Vol. 245 https://doi.org/10.1016/j.micromeso.2017.02.076	journal	June 2017
Direct Capture of CO₂ from Ambient Air Sanz-Pérez, Eloy S.; Murdock, Christopher R.; Didas, Stephanie A. Chemical Reviews, Vol. 116, Issue 19, p. 11840-11876 https://doi.org/10.1021/acs.chemrev.6b00173	journal	August 2016
Effect of SO₂ on the CO₂ Capture Performance of Self-Supported Branched Poly(ethyleneimine) Scaffolds Narayanan, Pavithra; Lively, Ryan P.; Jones, Christopher W. Energy & Fuels, Vol. 37, Issue 7 https://doi.org/10.1021/acs.energyfuels.2c03846	journal	March 2023
A Review on the Recent Scientific and Commercial Progress on the Direct Air Capture Technology to Manage Atmospheric CO₂ Concentrations and Future Perspectives Chowdhury, Satyajit; Kumar, Yogendra; Shrivastava, Saket Energy & Fuels, Vol. 37, Issue 15 https://doi.org/10.1021/acs.energyfuels.2c03971	journal	June 2023
The Structure of Adsorbed Species on Immobilized Amines in CO ₂ Capture: An in Situ IR Study Yu, Jie; Chuang, Steven S. C. Energy & Fuels, Vol. 30, Issue 9 https://doi.org/10.1021/acs.energyfuels.6b01423	journal	August 2016
Amine-Functionalized MIL-101 Monoliths for CO₂ Removal from Enclosed Environments Lawson, Shane; Griffin, Connor; Rapp, Kambria Energy & Fuels, Vol. 33, Issue 3 https://doi.org/10.1021/acs.energyfuels.8b04508	journal	February 2019
Steam Regeneration of Polyethylenimine-Impregnated Silica Sorbent for Postcombustion CO ₂ Capture: A Multicyclic Study Sandhu, Navjot Kaur; Pudasainee, Deepak; Sarkar, Partha Industrial & Engineering Chemistry Research, Vol. 55, Issue 7 https://doi.org/10.1021/acs.iecr.5b04741	journal	February 2016
Indoor CO₂ Control through Mesoporous Amine-Functionalized Silica Monoliths Zhao, Yiying; Zhou, Jizhi; Fan, Lili Industrial & Engineering Chemistry Research, Vol. 58, Issue 42 https://doi.org/10.1021/acs.iecr.9b03338	journal	September 2019
Direct Dry Air Capture of CO₂ Using VTSA with Faujasite Zeolites Wilson, Sean M. W.; Tezel, F. Handan Industrial & Engineering Chemistry Research, Vol. 59, Issue 18 https://doi.org/10.1021/acs.iecr.9b04803	journal	February 2020
The Mechanism of CO ₂ Adsorption under Dry and Humid Conditions in Mesoporous Silica-Supported Amine Sorbents Li, Kuijun; Kress, Joel D.; Mebane, David S. The Journal of Physical Chemistry C, Vol. 120, Issue 41 https://doi.org/10.1021/acs.jpcc.6b08808	journal	October 2016
Effect of Humidity on the CO ₂ Adsorption of Tertiary Amine Grafted SBA-15 Lee, Jason J.; Chen, Chia-Hsin; Shimon, Daphna The Journal of Physical Chemistry C, Vol. 121, Issue 42 https://doi.org/10.1021/acs.jpcc.7b07930	journal	October 2017
Probing Intramolecular versus Intermolecular CO ₂ Adsorption on Amine-Grafted SBA-15 Yoo, Chun-Jae; Lee, Li-Chen; Jones, Christopher W. Langmuir, Vol. 31, Issue 49 https://doi.org/10.1021/acs.langmuir.5b03657	journal	November 2015
Direct Air Capture of CO₂ Using Poly(ethyleneimine)-Functionalized Expanded Poly(tetrafluoroethylene)/Silica Composite Structured Sorbents Min, Youn Ji; Ganesan, Arvind; Realff, Matthew J. ACS Applied Materials & Interfaces, Vol. 14, Issue 36 https://doi.org/10.1021/acsami.2c11143	journal	September 2022
3D-Printed Zeolite Monoliths for CO ₂ Removal from Enclosed Environments Thakkar, Harshul; Eastman, Stephen; Hajari, Amit ACS Applied Materials & Interfaces, Vol. 8, Issue 41 https://doi.org/10.1021/acsami.6b09647	journal	October 2016
Monolith-Supported Amine-Functionalized Mg ₂ (dobpdc) Adsorbents for CO ₂ Capture Darunte, Lalit A.; Terada, Yuri; Murdock, Christopher R. ACS Applied Materials & Interfaces, Vol. 9, Issue 20 https://doi.org/10.1021/acsami.7b02035	journal	April 2017
3D-Printed Metal–Organic Framework Monoliths for Gas Adsorption Processes Thakkar, Harshul; Eastman, Stephen; Al-Naddaf, Qasim ACS Applied Materials & Interfaces, Vol. 9, Issue 41 https://doi.org/10.1021/acsami.7b11626	journal	October 2017
Poly(glycidyl amine)-Loaded SBA-15 Sorbents for CO ₂ Capture from Dilute and Ultradilute Gas Mixtures Sujan, Achintya R.; Kumar, Dharam Raj; Sakwa-Novak, Miles ACS Applied Polymer Materials, Vol. 1, Issue 11 https://doi.org/10.1021/acsapm.9b00788	journal	October 2019
Direct CO ₂ Capture from Air using Poly(ethylenimine)-Loaded Polymer/Silica Fiber Sorbents Sujan, Achintya R.; Pang, Simon H.; Zhu, Guanghui ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 5 https://doi.org/10.1021/acssuschemeng.8b06203	journal	February 2019
Polyethylenimine-Impregnated Resin for High CO ₂ Adsorption: An Efficient Adsorbent for CO ₂ Capture from Simulated Flue Gas and Ambient Air Chen, Zhenhe; Deng, Shubo; Wei, Haoran ACS Applied Materials & Interfaces, Vol. 5, Issue 15 https://doi.org/10.1021/am400661b	journal	July 2013
Steam Induced Structural Changes of a Poly(ethylenimine) Impregnated γ-Alumina Sorbent for CO ₂ Extraction from Ambient Air Sakwa-Novak, Miles A.; Jones, Christopher W. ACS Applied Materials & Interfaces, Vol. 6, Issue 12 https://doi.org/10.1021/am501500q	journal	June 2014
Mesoporous Alumina-Supported Amines as Potential Steam-Stable Adsorbents for Capturing CO ₂ from Simulated Flue Gas and Ambient Air Chaikittisilp, Watcharop; Kim, Hyung-Ju; Jones, Christopher W. Energy & Fuels, Vol. 25, Issue 11 https://doi.org/10.1021/ef201224v	journal	November 2011
Amine-Based Nanofibrillated Cellulose As Adsorbent for CO ₂ Capture from Air Gebald, Christoph; Wurzbacher, Jan Andre; Tingaut, Philippe Environmental Science & Technology, Vol. 45, Issue 20 https://doi.org/10.1021/es202223p	journal	October 2011
Analysis of Equilibrium-Based TSA Processes for Direct Capture of CO ₂ from Air Kulkarni, Ambarish R.; Sholl, David S. Industrial & Engineering Chemistry Research, Vol. 51, Issue 25 https://doi.org/10.1021/ie300691c	journal	June 2012
Hollow Fiber Adsorbents for CO ₂ Removal from Flue Gas Lively, Ryan P.; Chance, Ronald R.; Kelley, B. T. Industrial & Engineering Chemistry Research, Vol. 48, Issue 15 https://doi.org/10.1021/ie9005244	journal	August 2009
Understanding the Impacts of Support–Polymer Interactions on the Dynamics of Poly(ethyleneimine) Confined in Mesoporous SBA-15 Moon, Hyun June; Carrillo, Jan-Michael; Leisen, Johannes Journal of the American Chemical Society, Vol. 144, Issue 26 https://doi.org/10.1021/jacs.2c03028	journal	June 2022
Support Pore Structure and Composition Strongly Influence the Direct Air Capture of CO₂ on Supported Amines Rim, Guanhe; Priyadarshini, Pranjali; Song, MinGyu Journal of the American Chemical Society, Vol. 145, Issue 13 https://doi.org/10.1021/jacs.2c12707	journal	March 2023
Thermal, Oxidative and CO ₂ Induced Degradation of Primary Amines Used for CO ₂ Capture: Effect of Alkyl Linker on Stability Didas, Stephanie A.; Zhu, Rongshun; Brunelli, Nicholas A. The Journal of Physical Chemistry C, Vol. 118, Issue 23 https://doi.org/10.1021/jp5025137	journal	May 2014
Mechanism and Kinetics of CO ₂ Adsorption on Surface Bonded Amines Hahn, Maximilian W.; Steib, Matthias; Jentys, Andreas The Journal of Physical Chemistry C, Vol. 119, Issue 8 https://doi.org/10.1021/jp512001t	journal	February 2015
Effect of Amine Surface Coverage on the Co-Adsorption of CO ₂ and Water: Spectral Deconvolution of Adsorbed Species Didas, Stephanie A.; Sakwa-Novak, Miles A.; Foo, Guo Shiou The Journal of Physical Chemistry Letters, Vol. 5, Issue 23 https://doi.org/10.1021/jz502032c	journal	November 2014
Modulating the Porosity of Cryogels by Influencing the Nonfrozen Liquid Phase through the Addition of Inert Solutes Kirsebom, Harald; Topgaard, Daniel; Galaev, Igor Yu. Langmuir, Vol. 26, Issue 20 https://doi.org/10.1021/la102917c	journal	September 2010
Mechanisms and Kinetics for Sorption of CO ₂ on Bicontinuous Mesoporous Silica Modified with n -Propylamine Bacsik, Zoltán; Ahlsten, Nanna; Ziadi, Asraa Langmuir, Vol. 27, Issue 17 https://doi.org/10.1021/la202033p	journal	September 2011
Feret‘s Statistical Diameter as a Measure of Particle Size Walton, W. H. Nature, Vol. 162, Issue 4113 https://doi.org/10.1038/162329b0	journal	August 1948
Super-elastic and fatigue resistant carbon material with lamellar multi-arch microstructure Gao, Huai-Ling; Zhu, Yin-Bo; Mao, Li-Bo Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12920	journal	September 2016
Aligned two- and three-dimensional structures by directional freezing of polymers and nanoparticles Zhang, Haifei; Hussain, Irshad; Brust, Mathias Nature Materials, Vol. 4, Issue 10 https://doi.org/10.1038/nmat1487	journal	September 2005
Thin zeolite laminates for rapid and energy-efficient carbon capture Akhtar, Farid; Ogunwumi, Steven; Bergström, Lennart Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-10518-4	journal	September 2017
Preparation of macroporous scaffolds with holes in pore walls and pressure driven flows through them Chatterjee, Soumyajyoti; Potdar, Aditi; Kuhn, Simon RSC Advances, Vol. 8, Issue 44 https://doi.org/10.1039/C8RA03867H	journal	January 2018
Self-supported branched poly(ethyleneimine) materials for CO ₂ adsorption from simulated flue gas Yoo, Chun-Jae; Narayanan, Pavithra; Jones, Christopher W. Journal of Materials Chemistry A, Vol. 7, Issue 33 https://doi.org/10.1039/C9TA04662C	journal	January 2019
Direct air capture: process technology, techno-economic and socio-political challenges Erans, María; Sanz-Pérez, Eloy S.; Hanak, Dawid P. Energy & Environmental Science, Vol. 15, Issue 4 https://doi.org/10.1039/D1EE03523A	journal	January 2022
Amine-oxide hybrid materials for acid gas separations Bollini, Praveen; Didas, Stephanie A.; Jones, Christopher W. Journal of Materials Chemistry, Vol. 21, Issue 39 https://doi.org/10.1039/c1jm12522b	journal	January 2011
A review of direct air capture (DAC): scaling up commercial technologies and innovating for the future McQueen, Noah; Gomes, Katherine Vaz; McCormick, Colin Progress in Energy, Vol. 3, Issue 3 https://doi.org/10.1088/2516-1083/abf1ce	journal	April 2021
Architectural Control of Freeze-Cast Ceramics Through Additives and Templating Munch, Etienne; Saiz, Eduardo; Tomsia, Antoni P. Journal of the American Ceramic Society, Vol. 92, Issue 7 https://doi.org/10.1111/j.1551-2916.2009.03087.x	journal	July 2009
Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report) Thommes, Matthias; Kaneko, Katsumi; Neimark, Alexander V. Pure and Applied Chemistry, Vol. 87, Issue 9-10 https://doi.org/10.1515/pac-2014-1117	journal	October 2015
A Comparative Study of Different Sorbents in the Context of Direct Air Capture (DAC): Evaluation of Key Performance Indicators and Comparisons Leonzio, Grazia; Fennell, Paul S.; Shah, Nilay Applied Sciences, Vol. 12, Issue 5 https://doi.org/10.3390/app12052618	journal	March 2022
A Review of CO2 Capture by Absorption and Adsorption Yu, Cheng-Hsiu; Huang, Chih-Hung; Tan, Chung-Sung Aerosol and Air Quality Research, Vol. 12, Issue 5 https://doi.org/10.4209/aaqr.2012.05.0132	journal	January 2012
ImageJ Plugin for Analysis of Porous Scaffolds used in Tissue Engineering Haeri, Morteza; Haeri, Mohammad Journal of Open Research Software, Vol. 3 https://doi.org/10.5334/jors.bn	journal	January 2015

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