A robust protonic ceramic fuel cell with a triple conducting oxygen electrode under accelerated stress tests

Zheng, Shuanglin; Bian, Wenjuan; Ding, Hanping

doi:10.1039/D3MA01167D

Title: A robust protonic ceramic fuel cell with a triple conducting oxygen electrode under accelerated stress tests

Journal Article · 17 March 2024 · Materials Advances

DOI: https://doi.org/10.1039/D3MA01167D · OSTI ID:2305445

Zheng, Shuanglin ^[1];

^[2];

^[1]

School of Aerospace and Mechanical Engineering, University of Oklahoma, Norman, OK 73019, USA
Department of Hydrogen and Electrochemistry, Idaho National Laboratory, Idaho Falls, ID 83415, USA

Accelerated stress test of protonic ceramic fuel cells for evaluating the durability of materials and interfaces.

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC07-05ID14517; FE0032235

OSTI ID:: 2305445

Journal Information:: Materials Advances, Journal Name: Materials Advances Journal Issue: 6 Vol. 5; ISSN MAADC9; ISSN 2633-5409

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (55)

Regulation of Cathode Mass and Charge Transfer by Structural 3D Engineering for Protonic Ceramic Fuel Cell at 400 °C Bian, Wenjuan; Wu, Wei; Gao, Yipeng Advanced Functional Materials, Vol. 31, Issue 33 https://doi.org/10.1002/adfm.202102907	journal	June 2021
Protonic Ceramic Electrochemical Cells for Synthesizing Sustainable Chemicals and Fuels Liu, Fan; Ding, Dong; Duan, Chuancheng Advanced Science, Vol. 10, Issue 8 https://doi.org/10.1002/advs.202206478	journal	January 2023
Advances in Cathode Materials for Solid Oxide Fuel Cells: Complex Oxides without Alkaline Earth Metal Elements Chen, Yubo; Zhou, Wei; Ding, Dong Advanced Energy Materials, Vol. 5, Issue 18 https://doi.org/10.1002/aenm.201500537	journal	June 2015
Advanced Cathode Materials for Protonic Ceramic Fuel Cells: Recent Progress and Future Perspectives Wang, Ning; Tang, Chunmei; Du, Lei Advanced Energy Materials, Vol. 12, Issue 34 https://doi.org/10.1002/aenm.202201882	journal	July 2022
Progress in proton‐conducting oxides as electrolytes for low‐temperature solid oxide fuel cells: From materials to devices Zhang, Wei; Hu, Yun Hang Energy Science & Engineering, Vol. 9, Issue 7 https://doi.org/10.1002/ese3.886	journal	March 2021
Experimental and Theoretical Investigation of Degradation Mechanisms by Particle Coarsening in SOFC Electrodes Tanasini, P.; Cannarozzo, M.; Costamagna, P. Fuel Cells, Vol. 9, Issue 5 https://doi.org/10.1002/fuce.200800192	journal	October 2009
An Unbalanced Battle in Excellence: Revealing Effect of Ni/Co Occupancy on Water Splitting and Oxygen Reduction Reactions in Triple‐Conducting Oxides for Protonic Ceramic Electrochemical Cells Tang, Wei; Ding, Hanping; Bian, Wenjuan Small, Vol. 18, Issue 30 https://doi.org/10.1002/smll.202201953	journal	June 2022
Hydrogen as a carrier of renewable energies toward carbon neutrality: State-of-the-art and challenging issues Liu, Xuan; Liu, Gaoyang; Xue, Jilai International Journal of Minerals, Metallurgy and Materials, Vol. 29, Issue 5 https://doi.org/10.1007/s12613-022-2449-9	journal	April 2022
The degradation of SOFC electrodes Hsiao, Y. Solid State Ionics, Vol. 98, Issue 1-2 https://doi.org/10.1016/S0167-2738(97)00106-9	journal	June 1997
Modelling static and dynamic behaviour of proton exchange membrane fuel cells on the basis of electro-chemical description Ceraolo, M.; Miulli, C.; Pozio, A. Journal of Power Sources, Vol. 113, Issue 1 https://doi.org/10.1016/S0378-7753(02)00565-7	journal	January 2003
Investigation of a Ba0.5Sr0.5Co0.8Fe0.2O3−δ based cathode IT-SOFC Yan, Aiyu; Cheng, Mojie; Dong, Yonglai Applied Catalysis B: Environmental, Vol. 66, Issue 1-2 https://doi.org/10.1016/j.apcatb.2006.02.021	journal	June 2006
Progress in solid oxide fuel cell-gas turbine hybrid power systems: System design and analysis, transient operation, controls and optimization Azizi, Mohammad Ali; Brouwer, Jacob Applied Energy, Vol. 215 https://doi.org/10.1016/j.apenergy.2018.01.098	journal	April 2018
Electrochemical conversion of carbon dioxide in a solid oxide electrolysis cell Uhm, Sunghyun; Kim, Young Dok Current Applied Physics, Vol. 14, Issue 5 https://doi.org/10.1016/j.cap.2014.02.013	journal	May 2014
High performance low-temperature tubular protonic ceramic fuel cells based on barium cerate-zirconate electrolyte Cao, Dan; Zhou, Mingyang; Yan, Xiaomin Electrochemistry Communications, Vol. 125 https://doi.org/10.1016/j.elecom.2021.106986	journal	April 2021
PrBa0.5Sr0.5Co2O5+δ layered perovskite cathode for intermediate temperature solid oxide fuel cells Ding, Hanping; Xue, Xingjian Electrochimica Acta, Vol. 55, Issue 11 https://doi.org/10.1016/j.electacta.2010.01.104	journal	April 2010
SOFC operation with carbon oxides: Experimental analysis of performance and degradation Stoeckl, Bernhard; Subotić, Vanja; Preininger, Michael Electrochimica Acta, Vol. 275 https://doi.org/10.1016/j.electacta.2018.04.036	journal	June 2018
Comparison study on different SOFC hybrid systems with zero-CO2 emission Duan, Liqiang; Huang, Kexin; Zhang, Xiaoyuan Energy, Vol. 58 https://doi.org/10.1016/j.energy.2013.04.063	journal	September 2013
Fast performance degradation of SOFC caused by cathode delamination in long-term testing Park, Kwangjin; Yu, Sungoh; Bae, Joongmyeon International Journal of Hydrogen Energy, Vol. 35, Issue 16 https://doi.org/10.1016/j.ijhydene.2010.05.005	journal	August 2010
Research and development of on-board hydrogen-producing fuel cell vehicles Shusheng, Xiong; Qiujie, Song; Baosheng, Guo International Journal of Hydrogen Energy, Vol. 45, Issue 35 https://doi.org/10.1016/j.ijhydene.2020.04.236	journal	July 2020
Effects of cathode thickness and microstructural properties on the performance of protonic ceramic fuel cell (PCFC): A 3D modelling study Li, Zheng; He, Qijiao; Xia, Lingchao International Journal of Hydrogen Energy, Vol. 47, Issue 6 https://doi.org/10.1016/j.ijhydene.2021.11.022	journal	January 2022
BaCo0·4Fe0·4Zr0·1Y0·1O3 –δ triple conductor for boosting electrode efficiency for proton conducting fuel cells Kim, Chanho; Lee, Hyungjun; Jang, Inyoung International Journal of Hydrogen Energy, Vol. 47, Issue 8 https://doi.org/10.1016/j.ijhydene.2021.11.140	journal	January 2022
A Highly Efficient Multi-phase Catalyst Dramatically Enhances the Rate of Oxygen Reduction Chen, Yu; Choi, YongMan; Yoo, Seonyoung Joule, Vol. 2, Issue 5 https://doi.org/10.1016/j.joule.2018.02.008	journal	May 2018
A high dynamic PEM fuel cell model with temperature effects Shan, Yuyao; Choe, Song-Yul Journal of Power Sources, Vol. 145, Issue 1 https://doi.org/10.1016/j.jpowsour.2004.12.033	journal	July 2005
Benchmarking the expected stack manufacturing cost of next generation, intermediate-temperature protonic ceramic fuel cells with solid oxide fuel cell technology Dubois, Alexis; Ricote, Sandrine; Braun, Robert J. Journal of Power Sources, Vol. 369 https://doi.org/10.1016/j.jpowsour.2017.09.024	journal	November 2017
Ca-containing Ba0·95Ca0·05Co0·4Fe0·4Zr0·1Y0·1O3-δ cathode with high CO2-poisoning tolerance for proton-conducting solid oxide fuel cells Li, Jun; Hou, Jie; Lu, Ying Journal of Power Sources, Vol. 453 https://doi.org/10.1016/j.jpowsour.2020.227909	journal	March 2020
Reaction tuned formation of hierarchical BaCo0.4Fe0.4Zr0.1Y0.1O3-δ cathode Qi, Huiying; Zhao, Zhe; Tu, Baofeng Journal of Power Sources, Vol. 455 https://doi.org/10.1016/j.jpowsour.2020.227971	journal	April 2020
A comprehensive review of direct carbon fuel cell technology Giddey, S.; Badwal, S. P. S.; Kulkarni, A. Progress in Energy and Combustion Science, Vol. 38, Issue 3 https://doi.org/10.1016/j.pecs.2012.01.003	journal	June 2012
Long term testing of BCZY-based protonic ceramic fuel cell PCFC: Micro-generation profile and reversible production of hydrogen and electricity Dailly, Julian; Ancelin, Marie; Marrony, Mathieu Solid State Ionics, Vol. 306 https://doi.org/10.1016/j.ssi.2017.03.002	journal	August 2017
Electrochemical Performance and Enhancement of Hydration Kinetics on BaCo_0.7Fe_0.2Zr_0.1O_3−δ Cathode for Protonic Ceramic Fuel Cells Li, Haowei; Li, Jun; Wang, Xiaoyu ACS Applied Energy Materials, Vol. 6, Issue 17 https://doi.org/10.1021/acsaem.3c01698	journal	August 2023
Strain Effects on Oxygen Reduction Activity of Pr ₂ NiO ₄ Caused by Gold Bulk Dispersion for Low Temperature Solid Oxide Fuel Cells Kim, Sun Jae; Akbay, Taner; Matsuda, Junko ACS Applied Energy Materials, Vol. 2, Issue 2 https://doi.org/10.1021/acsaem.8b01776	journal	January 2019
Degradation of (La _0.6 Sr _0.4 ) _0.95 (Co _0.2 Fe _0.8 )O _3−δ Solid Oxide Fuel Cell Cathodes at the Nanometer Scale and below Ni, Na; Cooper, Samuel J.; Williams, Robert ACS Applied Materials & Interfaces, Vol. 8, Issue 27 https://doi.org/10.1021/acsami.6b05290	journal	June 2016
A Review of Solid Oxide Fuel Cell (SOFC) Dynamic Models Bhattacharyya, Debangsu; Rengaswamy, Raghunathan Industrial & Engineering Chemistry Research, Vol. 48, Issue 13 https://doi.org/10.1021/ie801664j	journal	July 2009
Self-sustainable protonic ceramic electrochemical cells using a triple conducting electrode for hydrogen and power production Ding, Hanping; Wu, Wei; Jiang, Chao Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-15677-z	journal	April 2020
Exceptional power density and stability at intermediate temperatures in protonic ceramic fuel cells Choi, Sihyuk; Kucharczyk, Chris J.; Liang, Yangang Nature Energy, Vol. 3, Issue 3 https://doi.org/10.1038/s41560-017-0085-9	journal	February 2018
Highly durable, coking and sulfur tolerant, fuel-flexible protonic ceramic fuel cells Duan, Chuancheng; Kee, Robert J.; Zhu, Huayang Nature, Vol. 557, Issue 7704 https://doi.org/10.1038/s41586-018-0082-6	journal	May 2018
Revitalizing interface in protonic ceramic cells by acid etch Bian, Wenjuan; Wu, Wei; Wang, Baoming Nature, Vol. 604, Issue 7906 https://doi.org/10.1038/s41586-022-04457-y	journal	April 2022
Ruddlesden Popper oxides of LnSr₃Fe₃O_10−δ (Ln = La, Pr, Nd, Sm, Eu, and Gd) as active cathodes for low temperature solid oxide fuel cells Chaianansutcharit, S.; Hosoi, K.; Hyodo, J. Journal of Materials Chemistry A, Vol. 3, Issue 23 https://doi.org/10.1039/C5TA01273B	journal	January 2015
Smart utilization of cobaltite-based double perovskite cathodes on barrier-layer-free zirconia electrolyte of solid oxide fuel cells Li, Meng; Chen, Kongfa; Hua, Bin Journal of Materials Chemistry A, Vol. 4, Issue 48 https://doi.org/10.1039/C6TA08396J	journal	January 2016
Controlling cation segregation in perovskite-based electrodes for high electro-catalytic activity and durability Li, Yifeng; Zhang, Wenqiang; Zheng, Yun Chemical Society Reviews, Vol. 46, Issue 20 https://doi.org/10.1039/C7CS00120G	journal	January 2017
Pr ₂ BaNiMnO _7−δ double-layered Ruddlesden–Popper perovskite oxides as efficient cathode electrocatalysts for low temperature proton conducting solid oxide fuel cells Wang, Qi; Hou, Jie; Fan, Yun Journal of Materials Chemistry A, Vol. 8, Issue 16 https://doi.org/10.1039/C9TA11212J	journal	January 2020
A mini review of the recent progress of electrode materials for low-temperature solid oxide fuel cells Hu, Shiming; Li, Jin; Zeng, Yu Physical Chemistry Chemical Physics, Vol. 25, Issue 8 https://doi.org/10.1039/D2CP05133H	journal	January 2023
Perovskites for protonic ceramic fuel cells: a review Cao, Jiafeng; Ji, Yuexia; Shao, Zongping Energy & Environmental Science, Vol. 15, Issue 6 https://doi.org/10.1039/D2EE00132B	journal	January 2022
Construction of high-temperature electronic conduction paths for the scale-up of solid oxide fuel cell technology Park, Mi Young; Park, Sun-Young; Seo, Haewon Journal of Materials Chemistry A, Vol. 10, Issue 22 https://doi.org/10.1039/D2TA02468C	journal	January 2022
A review of progress in proton ceramic electrochemical cells: material and structural design, coupled with value-added chemical production Wang, Yakun; Ling, Yeqing; Wang, Bin Energy & Environmental Science, Vol. 16, Issue 12 https://doi.org/10.1039/D3EE03121G	journal	January 2023
Lightly doping Ca2+ in perovskite PrCoO3 for tailored spin states and electrical properties Wang, Heng; Li, Guangshe; Guan, Xiangfeng Physical Chemistry Chemical Physics, Vol. 13, Issue 39 https://doi.org/10.1039/c1cp21562k	journal	January 2011
Proton-conducting oxides for energy conversion and storage Duan, Chuancheng; Huang, Jake; Sullivan, Neal Applied Physics Reviews, Vol. 7, Issue 1 https://doi.org/10.1063/1.5135319	journal	March 2020
PEM Fuel Cells Modeling and Analysis Through Current and Voltage Transient Behaviors Adzakpa, K. P.; Agbossou, K.; Dube, Y. IEEE Transactions on Energy Conversion, Vol. 23, Issue 2 https://doi.org/10.1109/TEC.2007.914170	journal	June 2008
Experimental Modeling of Transients in Large SOFC Systems Leone, P.; Lanzini, A. Journal of Fuel Cell Science and Technology, Vol. 10, Issue 1 https://doi.org/10.1115/1.4023217	journal	January 2013
Readily processed protonic ceramic fuel cells with high performance at low temperatures Duan, C.; Tong, J.; Shang, M. Science, Vol. 349, Issue 6254 https://doi.org/10.1126/science.aab3987	journal	July 2015
Current Status of National SOFC Projects in Japan Nirasawa, Hitoshi ECS Transactions, Vol. 78, Issue 1 https://doi.org/10.1149/07801.0033ecst	journal	May 2017
Degradation Analysis of an SOFC Short Stack Subject to 10,000 h of Operation Fang, Qingping; de Haart, Ute; Schäfer, Dominik Journal of The Electrochemical Society, Vol. 167, Issue 14 https://doi.org/10.1149/1945-7111/abc843	journal	November 2020
Scale-Up of Thin-Film Deposition-Based Solid Oxide Fuel Cell by Sputtering, a Commercially Viable Thin-Film Technology Noh, Ho-Sung; Hong, Jongsup; Kim, Hyoungchul Journal of The Electrochemical Society, Vol. 163, Issue 7 https://doi.org/10.1149/2.0331607jes	journal	January 2016
Electrochemical Performance and Degradation Analysis of an SOFC Short Stack Following Operation of More than 100,000 Hours Fang, Qingping; Blum, Ludger; Stolten, Detlef Journal of The Electrochemical Society, Vol. 166, Issue 16 https://doi.org/10.1149/2.0751916jes	journal	January 2019
Low-Cost Intermediate-Temperature Fuel-Flexible Protonic-Ceramic Fuel Cell and Stack O'Hayre, Ryan; Sullivan, Neal; Kee, Robert https://doi.org/10.2172/1861417	report	September 2021
Towards the Commercialization of Solid Oxide Fuel Cells: Recent Advances in Materials and Integration Strategies Mendonça, Catarina; Ferreira, António; Santos, Diogo M. F. Fuels, Vol. 2, Issue 4 https://doi.org/10.3390/fuels2040023	journal	October 2021

Similar Records

Enhancing surface activity and durability in triple conducting electrode for protonic ceramic electrochemical cells

Journal Article · 2025 · Nature Communications · OSTI ID:2584002

Zheng, Shuanglin; Wu, Wei; Zhang, Yuchen; +4 more

Tuning electrochemical performance and interfacial compatibility of oxygen electrodes in proton-conducting solid oxide electrolysis cells

Journal Article · 2025 · Journal of Materials Chemistry. A · OSTI ID:2549430

Karki, Saroj; Zheng, Shuanglin; Bello, Idris Temitope; +2 more

Performance degradation in proton-conducting ceramic fuel cell and electrolyzer stacks

Journal Article · 2022 · Journal of Power Sources · OSTI ID:1977398

Le, Long Q.; Meisel, Charlie; Hernandez, Carolina H.; +4 more

Title: A robust protonic ceramic fuel cell with a triple conducting oxygen electrode under accelerated stress tests

Citation Formats

References (55)

Similar Records

Related Subjects