Red-Colored Circularly Polarized Luminescence from a Benzo-Fused BODIPY-BINOL Complex

Tsuji, Miu; Abuhadba, Sara; Chen, Angela; Ito, Mio; Makhijani, Amrita; Kuwahara, Yutaka; Esipova, Tatiana; Mani, Tomoyasu

doi:10.1021/acs.jpcb.3c05496

Title: Red-Colored Circularly Polarized Luminescence from a Benzo-Fused BODIPY-BINOL Complex

Journal Article · 01 November 2023 · Journal of Physical Chemistry. B

DOI: https://doi.org/10.1021/acs.jpcb.3c05496 · OSTI ID:2284070

Tsuji, Miu ^[1]; Abuhadba, Sara ^[2]; Chen, Angela ^[1]; Ito, Mio ^[3]; Makhijani, Amrita ^[1];

^[3]; Esipova, Tatiana ^[2];

^[4]

Univ. of Connecticut, Storrs, CT (United States)
Loyola University, Chicago, IL (United States)
Kumamoto University (Japan)
Univ. of Connecticut, Storrs, CT (United States); Brookhaven National Laboratory (BNL), Upton, NY (United States)

Red emission with sharp bandwidth and high quantum yield are desired characteristics for organic chromophores in optoelectronic, spintronic, and biomedical applications. Here, we observe circularly polarized luminescence (CPL) with these characteristics from a benzo-fused BODIPY-BINOL complex (1). Using time-resolved optical spectroscopy, electrochemistry, and density functional theory calculations, we showed that the emissive excited state of 1 does not have a charge-transfer character, unlike the regular BODIPY counterpart (2). In conclusion, the rigidity and the lack of charge-transfer character make this class of molecules an appealing platform for CPL-active molecules in the red spectral region with ample room for improvement in the dissymmetry factor and brightness.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: SC0012704

OSTI ID:: 2284070

Report Number(s):: BNL--225280-2024-JAAM

Journal Information:: Journal of Physical Chemistry. B, Journal Name: Journal of Physical Chemistry. B Journal Issue: 45 Vol. 127; ISSN 1520-6106

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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