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Title: Penetrant-induced plasticization in microporous polymer membranes

Journal Article · · Chemical Society Reviews
DOI: https://doi.org/10.1039/D3CS00235G · OSTI ID:2283486

This review provides a comprehensive overview on the effects of plasticization on microporous polymer membranes, as well as strategies to mitigate this phenomenon for gas separation applications.

Sponsoring Organization:
USDOE
Grant/Contract Number:
SC0019087
OSTI ID:
2283486
Journal Information:
Chemical Society Reviews, Journal Name: Chemical Society Reviews Vol. 53 Journal Issue: 5; ISSN 0306-0012
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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Role of Intrachain Rigidity in the Plasticization of Intrinsically Microporous Triptycene-Based Polyimide Membranes in Mixed-Gas CO 2 /CH 4 Separations journal October 2014
Quantification of sorption, diffusion, and plasticization properties of cellulose triacetate films under mixed-gas CO2/CH4 environment journal September 2020
Gas separation properties in cyclic olefin copolymer membrane studied by positron annihilation, sorption, and gas permeation journal April 2006
Enhancement of biogas production from solid substrates using different techniques––a review journal October 2004
Energy-Efficient Hydrogen Separation by AB-Type Ladder-Polymer Molecular Sieves journal July 2014
High performance ZIF-8/6FDA-DAM mixed matrix membrane for propylene/propane separations journal February 2012
Effect of various exposure histories on sorption and dilation in a family of polycarbonates journal May 1990
Pure and mixed gas CH4 and n-C4H10 permeability and diffusivity in poly(dimethylsiloxane) journal December 2007
Aspects of simple, non-cooperative relaxations journal January 1991
Reverse selective glassy polymers for C3+ hydrocarbon recovery from natural gas journal January 2017
Molecular engineering of PIM-1/Matrimid blend membranes for gas separation journal July 2012
Task-Specific Ionic Liquids Tuning ZIF-67/PIM-1 Mixed Matrix Membranes for Efficient CO 2 Separation journal December 2020
Decarboxylation Cross-Linking of Triptycene-Based Tröger’s Base Polymers for Gas Separation journal September 2020
Physical aging of ultrathin glassy polymer films tracked by gas permeability journal November 2009
Synthesis and Characterization of a Novel Microporous Dihydroxyl-Functionalized Triptycene-Diamine-Based Polyimide for Natural Gas Membrane Separation journal July 2017
2D boron nitride nanosheets in PIM-1 membranes for CO2/CH4 separation journal October 2021
Revisiting group contribution theory for estimating fractional free volume of microporous polymer membranes journal October 2021
Single- and mixed-gas sorption in large-scale molecular models of glassy bulk polymers. Competitive sorption of a binary CH4/N2 and a ternary CH4/N2/CO2 mixture in a polyimide membrane journal November 2020
Basis of Permeability/Selectivity Tradeoff Relations in Polymeric Gas Separation Membranes journal January 1999
Nanoporous Organic Polymer/Cage Composite Membranes journal December 2012
Correlation between fractional free volume and diffusivity of gas molecules in glassy polymers journal December 1999
Highly CO 2 -Selective Gas Separation Membranes Based on Segmented Copolymers of Poly(Ethylene oxide) Reinforced with Pentiptycene-Containing Polyimide Hard Segments journal January 2016
High performance PIM-1/Matrimid hollow fiber membranes for CO2/CH4, O2/N2 and CO2/N2 separation journal September 2013
Direct observation of molecular cooperativity near the glass transition journal December 2000
Effects of Supercritical CO2 Conditioning on Cross-Linked Polyimide Membranes journal April 2010
Anomalous collapses of Nares Strait ice arches leads to enhanced export of Arctic sea ice journal January 2021
High-performance intrinsically microporous dihydroxyl-functionalized triptycene-based polyimide for natural gas separation journal May 2016
The Impact of Various Natural Gas Contaminant Exposures on CO2/CH4 Separation by a Polyimide Membrane journal October 2020
Carbon molecular sieve membrane from a microporous spirobisindane-based polyimide precursor with enhanced ethylene/ethane mixed-gas selectivity journal January 2017
Tailoring Physical Aging in Super Glassy Polymers with Functionalized Porous Aromatic Frameworks for CO 2 Capture journal June 2015
Dehydration of ethanol–water mixtures using asymmetric hollow fiber membranes from commercial polyimides journal February 2009
Improvement of CO2/CH4 separation characteristics of polyimides by chemical crosslinking journal March 1999
“Second component” effects in sorption and permeation of gases in glassy polymers journal September 1983
Effect of antiplasticization on gas sorption and transport. I. Polysulfone journal May 1987
Decarboxylation-Induced Cross-Linking of Polymers of Intrinsic Microporosity (PIMs) for Membrane Gas Separation journal June 2012
Future Directions of Membrane Gas Separation Technology journal March 2002
Highly Permeable Benzotriptycene-Based Polymer of Intrinsic Microporosity journal August 2015
MOF-Based Membranes for Gas Separations journal July 2020
Shear Viscosity Measurements of Liquid Carbon Dioxide journal July 1970
High Performance Polyimide with High Internal Free Volume Elements journal January 2011
Highly permeable and aging resistant 3D architecture from polymers of intrinsic microporosity incorporated with beta-cyclodextrin journal February 2017
Mixed-gas sorption in polymers via a new barometric test system: sorption and diffusion of CO2-CH4 mixtures in polydimethylsiloxane (PDMS) journal May 2019
Some observations about the application of Fick's first law for membrane separation of multicomponent mixtures journal November 1997
Preparation and gas transport properties of triptycene-containing polybenzoxazole (PBO)-based polymers derived from thermal rearrangement (TR) and thermal cyclodehydration (TC) processes journal January 2016
High-Performance Thermally Self-Cross-Linked Polymer of Intrinsic Microporosity (PIM-1) Membranes for Energy Development journal January 2012
Gas Permeation Properties, Physical Aging, and Its Mitigation in High Free Volume Glassy Polymers journal May 2018
Spectroscopic Ellipsometry Analysis of a Thin Film Composite Membrane Consisting of Polysulfone on a Porous α-Alumina Support journal February 2012
High-Pressure CO 2 Sorption in Polymers of Intrinsic Microporosity under Ultrathin Film Confinement journal March 2018
Mixed gas sorption in glassy polymers: Equipment design considerations and preliminary results journal April 1983
Carbon dioxide plasticization and conditioning effects in thick vs. thin glassy polymer films journal March 2011
Hydrocarbon separations by glassy polymer membranes journal July 2020
Seven chemical separations to change the world journal April 2016
Physical aging, CO 2 sorption and plasticization in thin films of polymer with intrinsic microporosity (PIM-1) journal September 2017
Synthesis and gas permeation properties of novel spirobisindane-based polyimides of intrinsic microporosity journal January 2013
Deuterium NMR investigation of the plasticization effects induced by high-pressure carbon dioxide gas on the molecular dynamics of polymers journal June 1990
Polymers of intrinsic microporosity (PIMs): robust, solution-processable, organic nanoporous materials journal January 2004
Gas separation performance and mechanical properties of thermally-rearranged polybenzoxazoles derived from an intrinsically microporous dihydroxyl-functionalized triptycene diamine-based polyimide journal February 2020
Carbon Dioxide-Induced Plasticization of Polyimide Membranes:  Pseudo-Equilibrium Relationships of Diffusion, Sorption, and Swelling journal August 2003
Ultrapermeable Polymers of Intrinsic Microporosity Containing Spirocyclic Units with Fused Triptycenes journal June 2021
Temperature and Pressure Dependence of Gas Permeation in a Microporous Tröger’s Base Polymer journal December 2018
Molecular Design of Free Volume as a Route to Low-κ Dielectric Materials journal November 2003
Gas-Separation Membranes Loaded with Porous Aromatic Frameworks that Improve with Age journal January 2015
Polymeric membranes based on bisphenol-A for gas separations journal March 1989
Influence of molecular weight and degree of crosslinking on the specific volume and glass temperature of polymers journal February 1955
Preparation and gas separation properties of spirobisbenzoxazole-based polyimides journal June 2022
When Do Sorption-Induced Relaxations in Glassy Polymers Set In? journal June 2007
Polymers with Cavities Tuned for Fast Selective Transport of Small Molecules and Ions journal October 2007
NELF predictions of a solubility–solubility selectivity upper bound journal April 2014
Natural Gas Processing with Membranes:  An Overview journal April 2008
Current challenges in membrane separation of CO2 from natural gas: A review journal September 2013
Gas separation performance and physical aging of tubular thin-film composite carbon molecular sieve membranes based on a polyimide of intrinsic microporosity precursor journal June 2022
Recent Applications of Polymer Blends in Gas Separation Membranes journal October 2013
Gas separation performance of 6FDA-based polyimides with different chemical structures journal October 2013
Olefin/paraffin separation through membranes: from mechanisms to critical materials journal January 2019
Morphology and mechanical properties of polymer-inorganic nanocomposite containing triple chain fibrous Na-Mg hydrosilicate journal June 2015
Synergistically improved PIM-1 membrane gas separation performance by PAF-1 incorporation and UV irradiation journal January 2022
Highly permeable thermally rearranged polymer composite membranes with a graphene oxide scaffold for gas separation journal January 2018
Gas separation membranes from polymers of intrinsic microporosity journal April 2005
Relaxation processes in the glassy state: Molecular aspects journal January 1980
Nanoporous ZIF-67 embedded polymers of intrinsic microporosity membranes with enhanced gas separation performance journal February 2018
Effect of Unexpected CO2’s Phase Transition on the High-Pressure Differential Scanning Calorimetry Performance of Various Polymers journal February 2016
A high-performance hydroxyl-functionalized polymer of intrinsic microporosity for an environmentally attractive membrane-based approach to decontamination of sour natural gas journal January 2015
Carbon dioxide foaming of glassy polymers journal September 1994
Simultaneously enhanced CO2 permeability and CO2/N2 selectivity at sub-ambient temperature from two novel functionalized intrinsic microporous polymers journal February 2022
Outstanding performance of PIM-1 membranes towards the separation of fluorinated refrigerant gases journal June 2023
Carbon molecular sieve gas separation membranes-I. Preparation and characterization based on polyimide precursors journal January 1994
Dielectric Relaxation of Polymer/Carbon Dioxide Systems journal June 2009
Mechanical motions in amorphous and semi-crystalline polymers☆ journal November 1976
Tröger 's base mixed matrix membranes for gas separation incorporating NH2-MIL-53(Al) nanocrystals journal March 2019
Plasticization of gas separation membranes journal December 1991
Cost competitive membrane—cryogenic post-combustion carbon capture journal September 2013
CO2 plasticization and physical aging of perfluorocyclobutyl polymer selective layers journal March 2014
Carbon dioxide/ethane mixed-gas sorption and dilation in a cross-linked poly(ethylene oxide) copolymer journal March 2010
Metal-organic framework MOF-801/PIM-1 mixed-matrix membranes for enhanced CO2/N2 separation performance journal November 2020
Triptycene-Based Polymers of Intrinsic Microporosity: Organic Materials That Can Be Tailored for Gas Adsorption journal June 2010
Molecular mobility and gas transport properties of nanocomposites based on PIM-1 and polyhedral oligomeric phenethyl-silsesquioxanes (POSS) journal May 2017
Leveraging Free Volume Manipulation to Improve the Membrane Separation Performance of Amine‐Functionalized PIM‐1 journal February 2021
Measuring and correlating diffusivity in polymer–solvent systems using free-volume theory journal January 2014
Post-crosslinking of triptycene-based Tröger's base polymers with enhanced natural gas separation performance journal June 2018
Analysis of the transport properties of thermally rearranged (TR) polymers and polymers of intrinsic microporosity (PIM) relative to upper bound performance journal March 2017
Studies in Newtonian Flow. II. The Dependence of the Viscosity of Liquids on Free‐Space journal December 1951
Plasticization mitigation strategies for gas and liquid filtration membranes - A review journal January 2023
Investigation of CO2-induced plasticization in fluorinated polyimide membranes via molecular simulation journal November 2012
Fine-Tuned Intrinsically Ultramicroporous Polymers Redefine the Permeability/Selectivity Upper Bounds of Membrane-Based Air and Hydrogen Separations journal August 2015
Interaction between p-Aminophenol and p-Chloranil in Solid State journal February 1997
Penetrant-induced plasticization and gas permeation in glassy polymers journal April 1988
Effects of Minor Components in Carbon Dioxide Capture Using Polymeric Gas Separation Membranes journal January 2009
The time temperature position of the glass-rubber transition of amorphous polymers and the free volume journal March 1980
Gas Separation Membrane Materials: A Perspective journal September 2014
Solubility in Glassy Polymers:  Correlations through the Nonequilibrium Lattice Fluid Model journal July 2001
Approaches to Suppress CO2-Induced Plasticization of Polyimide Membranes in Gas Separation Applications journal January 2019
Plasticization-resistant glassy polyimide membranes for CO2/CO4 separations journal August 1998
Surprising plasticization benefits in natural gas upgrading using polyimide membranes journal January 2020
In-situ cross interface linking of PIM-1 polymer and UiO-66-NH2 for outstanding gas separation and physical aging control journal February 2018
Effect of Film Thickness on the Gas-Permeation Characteristics of Glassy Polymer Membranes journal April 2007
Polymer Plasticization Using Supercritical Carbon Dioxide:  Experiment and Modeling journal May 2003
Enhanced PIM-1 membrane gas separation selectivity through efficient dispersion of functionalized POSS fillers journal October 2017
Thermally Rearranged Poly(benzoxazole- co -imide) Membranes with Superior Mechanical Strength for Gas Separation Obtained by Tuning Chain Rigidity journal March 2015
Synthesis of cardo-polymers using Tröger's base formation journal January 2014
Celebrating 50 Years of Macromolecules journal December 2017
Application of free-volume theory to self diffusion of solvents in polymers below the glass transition temperature: A review journal September 2011
Transport of gases through polymeric membranes journal May 1993
Amino-functionalized NUS-8 nanosheets as fillers in PIM-1 mixed matrix membranes for CO2 separations journal January 2022
Ultraselective glassy polymer membranes with unprecedented performance for energy-efficient sour gas separation journal May 2019
NELF model prediction of the infinite dilution gas solubility in glassy polymers journal February 2007
Polymeric Gas Separation Membranes journal March 2012
Correlation of separation factor versus permeability for polymeric membranes journal October 1991
Polymer ultrapermeability from the inefficient packing of 2D chains journal July 2017
Natural Gas Sweetening book June 2012
Dense film polyimide membranes for aggressive sour gas feed separations journal February 2013
Facile synthesis of Bi-functionalized intrinsic microporous polymer with fully carbon backbone for gas separation application journal December 2021
Facile and Time-Efficient Carboxylic Acid Functionalization of PIM-1: Effect on Molecular Packing and Gas Separation Performance journal July 2020
Nature of the Glass Transition and the Glassy State journal March 1958
Superhigh CO2-Permeable Mixed Matrix Membranes Composed of a Polymer of Intrinsic Microporosity (PIM-1) and Surface-Modified Silica Nanoparticles journal August 2019
Polymer nanosieve membranes for CO2-capture applications journal April 2011
The effect of plasticization on the transport of gases in and through glassy polymers journal January 1989
Materials for next-generation molecularly selective synthetic membranes journal January 2017
A highly rigid and gas selective methanopentacene-based polymer of intrinsic microporosity derived from Tröger's base polymerization journal January 2018
Gas-induced plasticization and the permselectivity of poly(tetrabromophenolphthalein terephthalate) to a mixture of carbon dioxide and methane journal April 1991
Triptycene Induced Enhancement of Membrane Gas Selectivity for Microporous Tröger's Base Polymers journal March 2014
Physical aging in plastics and other glassy materials journal March 1977
Bis(phenyl)fluorene-based polymer of intrinsic microporosity/functionalized multi-walled carbon nanotubes mixed matrix membranes for enhanced CO2 separation performance journal February 2020
Dynamic relaxation characteristics of thermally rearranged aromatic polyimides journal January 2013
Gas sorption and characterization of thermally rearranged polyimides based on 3,3′-dihydroxy-4,4′-diamino-biphenyl (HAB) and 2,2′-bis-(3,4-dicarboxyphenyl) hexafluoropropane dianhydride (6FDA) journal October 2012
A facile synthesis of a novel triptycene-containing A–B monomer: precursor to polymers of intrinsic microporosity journal January 2012
Molecular Weight Dependence of Surface Dynamic Viscoelastic Properties for the Monodisperse Polystyrene Film journal January 1996
A Combined Experimental and First-Principle Calculation (DFT Study) for In Situ Polymer Inclusion Membrane-Assisted Growth of Metal-Organic Frameworks (MOFs) journal June 2020
Plasticization of ultra-thin polysulfone membranes by carbon dioxide journal January 2010
Hypercrosslinked Additives for Ageless Gas-Separation Membranes journal January 2016
Dehydration of natural gas using membranes. Part I: Composite membranes journal September 2012
Comparison of pure and mixed gas permeation of the highly fluorinated polymer of intrinsic microporosity PIM-2 under dry and humid conditions: Experiment and modelling journal January 2020
Plasticization effects on the gas permeability and permselectivity of polymer membranes journal December 1992
Mixed matrix formulations with MOF molecular sieving for key energy-intensive separations journal February 2018
Mixed matrix membranes derived from nanoscale porous organic frameworks for permeable and selective CO2 separation journal December 2019
Modulus and damping of polymers in relation to their structure journal January 1969
Effect of the Amide Bond Diamine Structure on the CO 2 , H 2 S, and CH 4 Transport Properties of a Series of Novel 6FDA-Based Polyamide–Imides for Natural Gas Purification journal August 2012
Carbon dioxide plasticization of thin glassy polymer films journal November 2011
Nonequilibrium Lattice Fluids:  A Predictive Model for the Solubility in Glassy Polymers journal January 1996
High pressure pure- and mixed-gas separation of CO2/CH4 by thermally-rearranged and carbon molecular sieve membranes derived from a polyimide of intrinsic microporosity journal November 2013
Predicting polymer/solvent diffusion coefficients using free-volume theory journal March 1992
A multiscale approach to predict the mixed gas separation performance of glassy polymeric membranes for CO 2 capture: the case of CO 2 /CH 4 mixture in Matrimid ® journal October 2017