Role of Curvature in Stabilizing Boron-Doped Nanocorrugated Graphene

Tian, Mengkun; Tennyson, Wesley D.; Yoon, Mina; Puretzky, Alexander A.; Geohegan, David B.; Duscher, Gerd; Eres, Gyula

doi:10.1021/acsami.3c10664

Title: Role of Curvature in Stabilizing Boron-Doped Nanocorrugated Graphene

Journal Article · 18 December 2023 · ACS Applied Materials and Interfaces

DOI: https://doi.org/10.1021/acsami.3c10664 · OSTI ID:2281968

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^[1]; Geohegan, David B. ^[1]; Duscher, Gerd ^[3];

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Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States)

Boron-doped carbon nanostructures have attracted great interest recently because of their remarkable electrocatalytic performance comparable to or better than that of conventional metal catalysts. In a previous work (Carbon 123, 605 (2017)), we reported that along with significant performance improvement, B doping enhances the oxidation resistance of few-layer graphene (FLG) that provides increased structural stability for intermediate-temperature fuel-cell electrodes. In general, detailed characterization of the atomic and electronic structure transformations that occur in B-doped carbon nanostructures during fuel-cell operation is lacking. In this work, we use aberration-corrected scanning transmission electron microscopy, nanobeam electron diffraction, and electron energy-loss spectroscopy (EELS) to characterize the atomic and electronic structures of B-doped FLG before and after fuel-cell operation. These data point to the nanoscale corrugation of B-doped FLGs as the key factor responsible for increased stability and high corrosion resistance. In conclusion, the similarity of the 1s to π* and σ* transition features in the B K-edge EELS to those in B-doped carbon nanotubes provides an estimate for the curvature of nanocorrugation in B-FLG.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Oak Ridge Leadership Computing Facility (OLCF); Argonne National Laboratory (ANL), Argonne, IL (United States). Center for Nanoscale Materials (CNM); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: AC05-00OR22725; AC02-06CH11357; AC02-05CH11231; ERKCS81; BES-ERCAP0024568

OSTI ID:: 2281968

Journal Information:: ACS Applied Materials and Interfaces, Vol. 16, Issue 1; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (31)

Instability of Supported Platinum Nanoparticles in Low-Temperature Fuel Cells Shao-Horn, Y.; Sheng, W. C.; Chen, S. Topics in Catalysis, Vol. 46, Issue 3-4 https://doi.org/10.1007/s11244-007-9000-0	journal	November 2007
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Nanostructured carbon electrocatalyst supports for intermediate-temperature fuel cells: Single-walled versus multi-walled structures Papandrew, Alexander B.; Elgammal, Ramez A.; Tian, Mengkun Journal of Power Sources, Vol. 337 https://doi.org/10.1016/j.jpowsour.2016.10.093	journal	January 2017
Evidence for the solubility of boron in graphite by electron energy loss spectroscopy Serin, Virginie; Brydson, Rik; Scott, Andrew Carbon, Vol. 38, Issue 4 https://doi.org/10.1016/S0008-6223(99)00128-1	journal	January 2000
Bottom up synthesis of boron-doped graphene for stable intermediate temperature fuel cell electrodes Tennyson, Wesley D.; Tian, Mengkun; Papandrew, Alexander B. Carbon, Vol. 123 https://doi.org/10.1016/j.carbon.2017.08.002	journal	October 2017
Moiré pattern as a magnifying glass for strain and dislocations in van der Waals heterostructures Cosma, Diana A.; Wallbank, John R.; Cheianov, Vadim Faraday Discuss. https://doi.org/10.1039/C4FD00146J	journal	January 2014
Model for Self-Assembly of Carbon Nanotubes from Acetylene Based on Real-Time Studies of Vertically Aligned Growth Kinetics Eres, Gyula; Rouleau, C. M.; Yoon, Mina The Journal of Physical Chemistry C, Vol. 113, Issue 35 https://doi.org/10.1021/jp9001127	journal	August 2009
Graphene Edge Structures: Folding, Scrolling, Tubing, Rippling and Twisting Ivanovskaya, V. V.; Wagner, P.; Zobelli, A. Carbon Nanostructures https://doi.org/10.1007/978-3-642-20644-3_10	book	January 2012
Adjusting the Structure and Electronic Properties of Carbons for Metal‐Free Carbocatalysis of Organic Transformations Antonietti, Markus; Lopez‐Salas, Nieves; Primo, Ana Advanced Materials, Vol. 31, Issue 13 https://doi.org/10.1002/adma.201805719	journal	December 2018
Feature-rich electronic properties in graphene ripples Lin, Shih-Yang; Chang, Shen-Lin; Shyu, Feng-Lin Carbon, Vol. 86 https://doi.org/10.1016/j.carbon.2014.12.068	journal	May 2015
Curvature-induced bonding changes in carbon nanotubes investigated by electron energy-loss spectrometry Stéphan, O.; Ajayan, P. M.; Colliex, C. Physical Review B, Vol. 53, Issue 20 https://doi.org/10.1103/physrevb.53.13824	journal	May 1996
Defect-Dependent Corrugation in Graphene Thiemann, Fabian L.; Rowe, Patrick; Zen, Andrea Nano Letters, Vol. 21, Issue 19 https://doi.org/10.1021/acs.nanolett.1c02585	journal	September 2021
Direct Imaging of Rotational Stacking Faults in Few Layer Graphene Warner, Jamie H.; Rümmeli, Mark H.; Gemming, Thomas Nano Letters, Vol. 9, Issue 1 https://doi.org/10.1021/nl8025949	journal	January 2009
Low-dimensional non-metal catalysts: principles for regulating p-orbital-dominated reactivity Zhou, Si; Pei, Wei; Zhao, Yanyan npj Computational Materials, Vol. 7, Issue 1 https://doi.org/10.1038/s41524-021-00654-x	journal	November 2021
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Carbon as catalyst and support for electrochemical energy conversion Trogadas, Panagiotis; Fuller, Thomas F.; Strasser, Peter Carbon, Vol. 75 https://doi.org/10.1016/j.carbon.2014.04.005	journal	August 2014
Carbocatalysis by Graphene-Based Materials Navalon, Sergio; Dhakshinamoorthy, Amarajothi; Alvaro, Mercedes Chemical Reviews, Vol. 114, Issue 12 https://doi.org/10.1021/cr4007347	journal	April 2014
Quo vadis carbocatalysis? Schlögl, Robert Journal of Energy Chemistry, Vol. 61 https://doi.org/10.1016/j.jechem.2021.02.024	journal	October 2021
Unexpected catalytic activity of nanorippled graphene Sun, P. Z.; Xiong, W. Q.; Bera, A. Proceedings of the National Academy of Sciences, Vol. 120, Issue 12 https://doi.org/10.1073/pnas.2300481120	journal	March 2023
Will Any Crap We Put into Graphene Increase Its Electrocatalytic Effect? Wang, Lu; Sofer, Zdenek; Pumera, Martin ACS Nano, Vol. 14, Issue 1 https://doi.org/10.1021/acsnano.9b00184	journal	January 2020
Carbon-based metal-free catalysts Liu, Xien; Dai, Liming Nature Reviews Materials, Vol. 1, Issue 11 https://doi.org/10.1038/natrevmats.2016.64	journal	September 2016
Atomistic Interrogation of B–N Co-dopant Structures and Their Electronic Effects in Graphene Schiros, Theanne; Nordlund, Dennis; Palova, Lucia ACS Nano, Vol. 10, Issue 7 https://doi.org/10.1021/acsnano.6b01318	journal	June 2016
Ultrahigh Performance Supercapacitor from Lacey Reduced Graphene Oxide Nanoribbons Sahu, Vikrant; Shekhar, Shashank; Sharma, Raj Kishore ACS Applied Materials & Interfaces, Vol. 7, Issue 5 https://doi.org/10.1021/am5071706	journal	January 2015
Boron doping of graphene–pushing the limit Chaban, Vitaly V.; Prezhdo, Oleg V. Nanoscale, Vol. 8, Issue 34 https://doi.org/10.1039/C6NR05309B	journal	January 2016
Synthesis and Characterization of Boron-Doped Single-Wall Carbon Nanotubes Produced by the Laser Vaporization Technique Blackburn, Jeff L.; Yan, Yanfa; Engtrakul, Chaiwat Chemistry of Materials, Vol. 18, Issue 10 https://doi.org/10.1021/cm060192i	journal	May 2006
An EELS study on an individual boron-doped multi-walled carbon nanotube Shindou, Emi; Hamamura, Naoki; Yoshida, Akira TANSO, Vol. 2009, Issue 239 https://doi.org/10.7209/tanso.2009.162	journal	January 2009
p-Block elements for catalysis Zhou, Zhen npj Computational Materials, Vol. 7, Issue 1 https://doi.org/10.1038/s41524-021-00680-9	journal	December 2021
Electronic Structure Modification of Ion Implanted Graphene: The Spectroscopic Signatures of p- and n-Type Doping Kepaptsoglou, Demie; Hardcastle, Trevor P.; Seabourne, Che R. ACS Nano, Vol. 9, Issue 11 https://doi.org/10.1021/acsnano.5b05305	journal	October 2015
Preparation and characterization of B x C 1 − x thin films with the graphite structure Way, B. M.; Dahn, J. R.; Tiedje, T. Physical Review B, Vol. 46, Issue 3 https://doi.org/10.1103/PhysRevB.46.1697	journal	July 1992
Local Atomic and Electronic Structure of Boron Chemical Doping in Monolayer Graphene Zhao, Liuyan; Levendorf, Mark; Goncher, Scott Nano Letters, Vol. 13, Issue 10 https://doi.org/10.1021/nl401781d	journal	September 2013

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Title: Role of Curvature in Stabilizing Boron-Doped Nanocorrugated Graphene

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