Nanoscale water–polymer interactions tune macroscopic diffusivity of water in aqueous poly(ethylene oxide) solutions

Moon, Joshua D.; Webber, Thomas R.; Brown, Dennis Robinson; Richardson, Peter M.; Casey, Thomas M.; Segalman, Rachel A.; Shell, M. Scott; Han, Songi

doi:10.1039/D3SC05377F

Title: Nanoscale water–polymer interactions tune macroscopic diffusivity of water in aqueous poly(ethylene oxide) solutions

Journal Article · 13 February 2024 · Chemical Science

DOI: https://doi.org/10.1039/D3SC05377F · OSTI ID:2281280

Moon, Joshua D. ^[1];

^[2];

^[3]; Casey, Thomas M. ^[4]; Segalman, Rachel A. ^[1]; Shell, M. Scott ^[2]; Han, Songi ^[5]

Materials Department, University of California, Santa Barbara, California 93106, USA, Department of Chemical Engineering, University of California, Santa Barbara, California 93106, USA
Department of Chemical Engineering, University of California, Santa Barbara, California 93106, USA
Materials Department, University of California, Santa Barbara, California 93106, USA
Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, USA
Department of Chemical Engineering, University of California, Santa Barbara, California 93106, USA, Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, USA

PEO restructures water near the polymer, reducing free volume and slowing local water.

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Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019272

OSTI ID:: 2281280

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 7 Vol. 15; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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