Biopolymer‐assisted Synthesis of P‐doped TiO 2 Nanoparticles for High‐performance Lithium‐ion Batteries: A Comprehensive Study

El Halya, Nabil; Aqil, Mohamed; El Ouardi, Karim; Bano, Amreen; El Bendali, Ayoub; Hdidou, Loubna; Amine, Rachid; Son, Seoung‐Bum; Ghamouss, Fouad; Major, Dan Thomas; Amine, Khalil; Alami, Jones; Dahbi, Mouad

doi:10.1002/batt.202300424

Title: Biopolymer‐assisted Synthesis of P‐doped TiO ₂ Nanoparticles for High‐performance Lithium‐ion Batteries: A Comprehensive Study

Journal Article · 15 November 2023 · Batteries & Supercaps

DOI: https://doi.org/10.1002/batt.202300424 · OSTI ID:2281273

El Halya, Nabil ^[1]; Aqil, Mohamed ^[1]; El Ouardi, Karim ^[2]; Bano, Amreen ^[3]; El Bendali, Ayoub ^[1]; Hdidou, Loubna ^[1]; Amine, Rachid ^[4]; Son, Seoung‐Bum ^[4]; Ghamouss, Fouad ^[1]; Major, Dan Thomas ^[3]; Amine, Khalil ^[4]; Alami, Jones ^[1];

^[1]

Materials Science, Energy, and Nano-engineering Department Mohammed VI Polytechnic University Ben Guerir Morocco
Materials Science, Energy, and Nano-engineering Department Mohammed VI Polytechnic University Ben Guerir Morocco, Laboratory of Physic-Chemistry, Materials and Catalysis department of chemistry Faculty of Sciences Ben M'sik University Hassan II of Casablanca Casablanca Morocco
Department of Chemistry and Institute of Nanotechnology and Advanced Materials Bar-Ilan University Ramat-Gan 52900 Israel
Chemical Sciences and engineering Division Argonne National Laboratory 9700 S. Cass Avenue Lemont IL 60439 USA

Abstract TiO ₂ material has gained significant attention for large‐scale energy storage due to its abundant, low‐cost, and environmentally friendly properties, as well as the availability of various nanostructures. Phosphorus doping has been established as an effective technique for improving electronic conductivity and managing the slow ionic diffusion kinetics of TiO ₂ . In this study, non‐doped and phosphorus doped TiO ₂ materials were synthesized using sodium alginate biopolymer as chelating agent. The prepared materials were evaluated as anode materials for lithium‐ion batteries (LIBs). The electrodes exhibit remarkable electrochemical performance, including a high reversible capacity of 235 mAh g ⁻¹ at 0.1 C and excellent first coulombic efficiency of 99 %. An integrated approach, combining operando XRD and ex‐situ XAS, comprehensively investigates the relationship between phosphorus doping, material structure, and electrochemical performance, reinforced by analytical tools and first principles calculations. Furthermore, a full cell was designed using 2 %P‐doped TiO ₂ anode and LiFePO ₄ cathode. The output voltage was about 1.6 V with high initial specific capacity of 148 mAh g ⁻¹ , high rate‐capability of 120 mAh g ⁻¹ at 1 C, and high‐capacity retention of 96 % after 1000 cycles at 1 C.

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Sponsoring Organization:: USDOE

OSTI ID:: 2281273

Alternate ID(s):: OSTI ID: 2350619

Journal Information:: Batteries & Supercaps, Journal Name: Batteries & Supercaps Journal Issue: 1 Vol. 7; ISSN 2566-6223

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Title: Biopolymer‐assisted Synthesis of P‐doped TiO ₂ Nanoparticles for High‐performance Lithium‐ion Batteries: A Comprehensive Study