Chalcocarbogels as High-Capacity and Cycle-Stable Electrode Materials for Lithium and Sodium Ion Batteries

Islam, Taohedul; Li, Mengya; Blanton, Alicia; Pitton, Kathryn A.; Rao, Keerthan R.; Bayat, Sahar; Wiaderek, Kamila M.; Weret, Misganaw Adigo; Roy, Subrata C.; Feng, Renfei; Li, Dien; Alam, Robiul; Nie, Jing; Oketola, Oluwaseun; Pramanik, Avijit; Guiton, Beth S.; Risko, Chad; Belharouak, Ilias; Amin, Ruhul; Islam, Saiful Muhammad

doi:10.1021/acsenergylett.3c02112

Title: Chalcocarbogels as High-Capacity and Cycle-Stable Electrode Materials for Lithium and Sodium Ion Batteries

Journal Article · 29 November 2023 · ACS Energy Letters

DOI: https://doi.org/10.1021/acsenergylett.3c02112 · OSTI ID:2281095

Islam, Taohedul ^[1];

^[2]; Blanton, Alicia ^[1]; Pitton, Kathryn A. ^[3]; Rao, Keerthan R. ^[3]; Bayat, Sahar ^[3];

^[4];

^[1]; Roy, Subrata C. ^[1];

^[5]; Li, Dien ^[6]; Alam, Robiul ^[1]; Nie, Jing ^[1]; Oketola, Oluwaseun ^[1];

^[1];

^[3];

^[2];

^[1]

Jackson State Univ., Jackson, MS (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Univ. of Kentucky, Lexington, KY (United States)
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Univ. of Saskatchewan, Saskatoon, SK (Canada). Canadian Light Source, Inc.
Savannah River National Laboratory (SRNL), Aiken, SC (United States)

The low capacities of commercial Li ion batteries and cycle instabilities of amorphous metal sulfide based batteries impose constraints on their utilization for large-scale energy storage. We report here the acid-free, room-temperature (RT), and solution-based synthesis of a chalcogenide–carbonaceous hybrid aerogel, termed as “chalcocarbogel”, comprising molybdenum sulfide (MoS_x) and graphene oxide (GO). The chalcocarbogel is a nanoparticle-aggregated, porous, amorphous gel consisting of Mo₃S₁₃ and Mo₂S₁₂-like structures as determined by synchrotron X-ray PDF, XANES, and EXAFS. The MoS_x-GO chalcocarbogel demonstrates high specific capacities of ~1215 and ~807 mAh g^–1 for Li/MoS_x-GO and Na/MoS_x-GO cells, respectively, for a 50 mAg^–1 discharge rate during the first cycle. After the activation cycles, the MoS_x-GO chalcocarbogel stabilizes, maintaining high specific capacities of approximately ~700 mAh g^–1 for Li/MoS_x-GO and ~473 mAh g^–1 for Na/MoS_x-GO cells, while continuously cycling. Importantly, the MoS_x-GO aerogel reported here serves as a promising platform to develop chalcocarbogels for applications spanning both Li and Na ion batteries.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Savannah River National Laboratory (SRNL), Aiken, SC (United States); Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF); National Science Foundation (NSF)

Grant/Contract Number:: AC05-00OR22725; AC02-06CH11357; SC0022315

OSTI ID:: 2281095

Alternate ID(s):: OSTI ID: 2441496

Journal Information:: ACS Energy Letters, Journal Name: ACS Energy Letters Journal Issue: 1 Vol. 9; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Chalcocarbogels as High-Capacity and Cycle-Stable Electrode Materials for Lithium and Sodium Ion Batteries

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