Ceria Incorporation in Sinter-Resistant Platinum-Based Catalysts

Stone, Michael L.; Cendejas, Melissa C.; Persson, Alex; Liccardo, Gennaro; Smith, Jacob; Kumar, Abinash; Zhou, Chengshuang; Gardner, Evan; Aitbekova, Aisulu; Bustillo, Karen C.; Chi, Miaofang; Bare, Simon R.; Cargnello, Matteo

doi:10.1021/acscatal.3c02766

Title: Ceria Incorporation in Sinter-Resistant Platinum-Based Catalysts

Journal Article · 01 November 2023 · ACS Catalysis

DOI: https://doi.org/10.1021/acscatal.3c02766 · OSTI ID:2280914

Stone, Michael L. ^[1]; Cendejas, Melissa C. ^[2]; Persson, Alex ^[3]; Liccardo, Gennaro ^[4]; Smith, Jacob ^[5]; Kumar, Abinash ^[5];

^[3]; Gardner, Evan ^[3]; Aitbekova, Aisulu ^[3];

^[6];

^[5];

^[2];

^[3]

Stanford University, CA (United States); Stanford University
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Stanford University, CA (United States)
Stanford University, CA (United States); SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Platinum group metals (PGM) are widely used for exhaust emission abatement. Sintering during the high-temperature emission control conditions decreases noble metal utilization efficiency. Efficient use of scarce noble metals requires sinter-resistant catalysts. Here we extend an approach to synthesize catalysts consisting of platinum nanoparticles encapsulated in a mixture of cerium and aluminum oxides (Pt@Al₂O₃-CeO₂). We tested the activity of this catalyst toward carbon monoxide, propene, and propane oxidation chosen as model oxidation reactions for emission control catalysts. Pt@Al₂O₃-CeO₂ catalysts demonstrated similar activity and stability upon aging as the comparison system without ceria, Pt@Al₂O₃, while maintaining small Pt nanoparticles and ceria crystallites. Additionally, we studied the influence of various thermal treatments on CO oxidation activity and determined that a steam treatment can activate low temperature CO oxidation activity of Pt@Al₂O₃-CeO₂. STEM-EDS analysis revealed that thermal treatments led to the co-location of Pt and CeO₂ and temperature programmed-reduction analysis revealed that the steam treatment specifically enhanced CO oxidation activity through surface reduction of the CeO₂. As a result, we demonstrate the versatility of this encapsulation approach to generate mixed metal-oxide supports with improved metal-support interactions without hindering nanoparticle stability.

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Research Organization:: Stanford University, CA (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: SC0022197; AC02-05CH11231; AC02-76SF00515; AC05-00OR22725

OSTI ID:: 2280914

Alternate ID(s):: OSTI ID: 2438690; OSTI ID: 2440471

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 22 Vol. 13; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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