Perovskite evolution on La modified Mn1.5Co1.5O4 spinel through thermal ageing with enhanced oxidation activity: Is sintering always an issue?

Tang, Wenxiang; Zhang, Chi; Cao, Yijia; Liu, Fangyuan; Weng, Junfei; Lu, Xingxu; Dang, Yanliu; Nam, Chang-Yong; Suib, Steven L.; Gao, Pu-Xian

doi:10.1016/j.cej.2023.147073

Title: Perovskite evolution on La modified Mn_1.5Co_1.5O₄ spinel through thermal ageing with enhanced oxidation activity: Is sintering always an issue?

Journal Article · 31 October 2023 · Chemical Engineering Journal

DOI: https://doi.org/10.1016/j.cej.2023.147073 · OSTI ID:2280505

^[1]; Zhang, Chi ^[2]; Cao, Yijia ^[2];

^[3];

^[3]; Dang, Yanliu ^[3]; Nam, Chang-Yong ^[4]; Suib, Steven L. ^[3];

^[3]

Sichuan University, Chengdu (China); University of Connecticut, Storrs, CT (United States)
Sichuan University, Chengdu (China)
University of Connecticut, Storrs, CT (United States)
Brookhaven National Laboratory (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)

Non-precious metal oxides have great potential in catalytic deep oxidation of emitted hydrocarbons to help address various environmental pollution concerns. However, sintering issue is a stumbling block in practical application upon long-term high-temperature operation or thermal shock experience. Herein, La was applied to modify Mn_1.5Co_1.5O₄ spinel to get a highly active oxidation catalyst with exceptional stability against high-temperature thermal ageing treatment. With thermal ageing at 750 °C for 100 h, the La modified Mn–Co composite reached 90 % conversion in toluene oxidation at 265 °C under the high WHSV of 120,000 mL g^-1 h^-1, while this value increased to 312 °C over blank Mn–Co spinel. The addition of La not only inhibited the growth of spinel nanocrystals, but also brought about perovskite formation through sintering, generating perovskite-spinel interfaces, thus enhancing both activity and stability. Meanwhile, the La modified Mn–Co spinel exhibited superior performance in presence of water or sulfur dioxide after thermal ageing treatment. In conclusion, this work offers a versatile strategy to design anti-sintering and active oxidation nanocatalysts based on non-precious metal oxides for industrial applications.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF); National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: SC0012704

OSTI ID:: 2280505

Report Number(s):: BNL--225141-2023-JAAM

Journal Information:: Chemical Engineering Journal, Journal Name: Chemical Engineering Journal Vol. 477; ISSN 1385-8947

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
Mn1.5Co1.5O4
La modification
Thermal ageing
Spinel-Perovskite interface
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Title: Perovskite evolution on La modified Mn1.5Co1.5O4 spinel through thermal ageing with enhanced oxidation activity: Is sintering always an issue?

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Title: Perovskite evolution on La modified Mn_1.5Co_1.5O₄ spinel through thermal ageing with enhanced oxidation activity: Is sintering always an issue?