Freeze Tape Casting Electrode with Bilayered Architecture for High-Performance Lithium-Ion Batteries

Tao, Runming; Polizos, Georgios; Li, Mengya; Dixit, Marm; Sharma, Jaswinder; Li, Jianlin

doi:10.1021/acsaem.3c02614

Title: Freeze Tape Casting Electrode with Bilayered Architecture for High-Performance Lithium-Ion Batteries

Journal Article · 01 January 2024 · ACS Applied Energy Materials

DOI: https://doi.org/10.1021/acsaem.3c02614 · OSTI ID:2278913

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Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

A facile freeze tape casting (FTC) strategy is utilized to prepare bilayered 4 mAh cm^–2 high-loading LiNi_0.6Co_0.2Mn_0.2O₂ cathodes. The bottom layer is a conventional nonaqueous electrode, which has a dense structure for high-energy purposes. Further, the top layer is prepared by the proposed FTC, exhibiting a porous feature for high-power requirement. With the assistance of FTC, the bilayered electrodes successfully deliver enhanced rate and cyclic performance due to the improved lithium-ion diffusion kinetics and pathways. Therefore, the proposed FTC strategy and its delivered electrodes are promising for energy- and power-density lithium-ion batteries, potentially enlightening the research and development of lithium-ion battery manufacturing.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2278913

Journal Information:: ACS Applied Energy Materials, Journal Name: ACS Applied Energy Materials Journal Issue: 3 Vol. 7; ISSN 2574-0962

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Related Subjects

25 ENERGY STORAGE
bilayered electrode
electrode processing
energy density
freeze tape casting
high-loading electrode
power density

Title: Freeze Tape Casting Electrode with Bilayered Architecture for High-Performance Lithium-Ion Batteries

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