Freeze Tape Casting Electrode with Bilayered Architecture for High-Performance Lithium-Ion Batteries

Tao, Runming; Polizos, Georgios; Li, Mengya; Dixit, Marm; Sharma, Jaswinder; Li, Jianlin

doi:10.1021/acsaem.3c02614

Title: Freeze Tape Casting Electrode with Bilayered Architecture for High-Performance Lithium-Ion Batteries

Journal Article · 02 January 2024 · ACS Applied Energy Materials

DOI: https://doi.org/10.1021/acsaem.3c02614 · OSTI ID:2278913

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Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

A facile freeze tape casting (FTC) strategy is utilized to prepare bilayered 4 mAh cm^–2 high-loading LiNi_0.6Co_0.2Mn_0.2O₂ cathodes. The bottom layer is a conventional nonaqueous electrode, which has a dense structure for high-energy purposes. Further, the top layer is prepared by the proposed FTC, exhibiting a porous feature for high-power requirement. With the assistance of FTC, the bilayered electrodes successfully deliver enhanced rate and cyclic performance due to the improved lithium-ion diffusion kinetics and pathways. Therefore, the proposed FTC strategy and its delivered electrodes are promising for energy- and power-density lithium-ion batteries, potentially enlightening the research and development of lithium-ion battery manufacturing.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2278913

Journal Information:: ACS Applied Energy Materials, Vol. 7, Issue 3; ISSN 2574-0962

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (27)

How we made the Li-ion rechargeable battery Goodenough, John B. Nature Electronics, Vol. 1, Issue 3 https://doi.org/10.1038/s41928-018-0048-6	journal	March 2018
A review of laser electrode processing for development and manufacturing of lithium-ion batteries Pfleging, Wilhelm Nanophotonics, Vol. 7, Issue 3 https://doi.org/10.1515/nanoph-2017-0044	journal	February 2018
High-throughput and high-performance lithium-ion batteries via dry processing Tao, Runming; Steinhoff, Bryan; Sun, Xiao-Guang Chemical Engineering Journal, Vol. 471 https://doi.org/10.1016/j.cej.2023.144300	journal	September 2023
Impact of secondary particle size and two-layer architectures on the high-rate performance of thick electrodes in lithium-ion battery pouch cells Wood, Marissa; Li, Jianlin; Du, Zhijia Journal of Power Sources, Vol. 515 https://doi.org/10.1016/j.jpowsour.2021.230429	journal	December 2021
Review on modeling of the anode solid electrolyte interphase (SEI) for lithium-ion batteries Wang, Aiping; Kadam, Sanket; Li, Hong npj Computational Materials, Vol. 4, Issue 1 https://doi.org/10.1038/s41524-018-0064-0	journal	March 2018
Water based processing of LiFePO4/C cathode material for Li-ion batteries utilizing freeze granulation Orlenius, J.; Lyckfeldt, O.; Kasvayee, K. A. Journal of Power Sources, Vol. 213 https://doi.org/10.1016/j.jpowsour.2012.04.037	journal	September 2012
Freeze Tape Cast Thick Mo Doped Li ₄ Ti ₅ O ₁₂ Electrodes for Lithium-Ion Batteries Ghadkolai, Milad Azami; Creager, Stephen; Nanda, Jagjit Journal of The Electrochemical Society, Vol. 164, Issue 12 https://doi.org/10.1149/2.1311712jes	journal	January 2017
Insight into the Fast‐Rechargeability of a Novel Mo_1.5W_1.5Nb₁₄O₄₄ Anode Material for High‐Performance Lithium‐Ion Batteries (Adv. Energy Mater. 36/2022) Tao, Runming; Zhang, Tianyu; Tan, Susheng Advanced Energy Materials, Vol. 12, Issue 36 https://doi.org/10.1002/aenm.202270151	journal	September 2022
Fabrication of Gradient Pore TiO ₂ Sheets by a Novel Freeze?Tape-Casting Process Ren, Linlin; Zeng, Yu-Ping; Jiang, Dongliang Journal of the American Ceramic Society, Vol. 90, Issue 9 https://doi.org/10.1111/j.1551-2916.2007.01833.x	journal	September 2007
Achieving Ultrahigh‐Rate and High‐Safety Li ⁺ Storage Based on Interconnected Tunnel Structure in Micro‐Size Niobium Tungsten Oxides Yang, Yang; Zhu, He; Xiao, Jinfei Advanced Materials, Vol. 32, Issue 12 https://doi.org/10.1002/adma.201905295	journal	February 2020
Characterization and Laser Structuring of Aqueous Processed Li(Ni0.6Mn0.2Co0.2)O2 Thick-Film Cathodes for Lithium-Ion Batteries Zhu, Penghui; Han, Jiahao; Pfleging, Wilhelm Nanomaterials, Vol. 11, Issue 7 https://doi.org/10.3390/nano11071840	journal	July 2021
Molybdenum Carbide Electrocatalyst In Situ Embedded in Porous Nitrogen‐Rich Carbon Nanotubes Promotes Rapid Kinetics in Sodium‐Metal–Sulfur Batteries (Adv. Mater. 26/2022) Hao, Hongchang; Wang, Yixian; Katyal, Naman Advanced Materials, Vol. 34, Issue 26 https://doi.org/10.1002/adma.202270199	journal	July 2022
A review of fabrication strategies and applications of porous ceramics prepared by freeze-casting method Liu, Ruiping; Xu, Tingting; Wang, Chang-an Ceramics International, Vol. 42, Issue 2 https://doi.org/10.1016/j.ceramint.2015.10.148	journal	February 2016
Strong coordination interaction in amorphous Sn-Ti-ethylene glycol compound for stable Li-ion storage Cai, Yuqing; Liu, Haigang; Li, Haoran Energy Materials and Devices https://doi.org/10.26599/EMD.2023.9370013	journal	November 2023
Two-layer cathode architecture for high-energy density and high-power density solid state batteries Polizos, Georgios; Kalnaus, Sergiy; Chen, Xi Chelsea Materials Today Chemistry, Vol. 33 https://doi.org/10.1016/j.mtchem.2023.101704	journal	October 2023
Bilayer hybrid graphite anodes via freeze tape casting for extreme fast charging applications Parikh, Dhrupad; Li, Jianlin Carbon, Vol. 196 https://doi.org/10.1016/j.carbon.2022.05.023	journal	August 2022
A conformal heat-drying direct ink writing 3D printing for high-performance lithium-ion batteries Tao, R.; Gu, Y.; Sharma, J. Materials Today Chemistry, Vol. 32 https://doi.org/10.1016/j.mtchem.2023.101672	journal	August 2023
Impact of Pore Tortuosity on Electrode Kinetics in Lithium Battery Electrodes: Study in Directionally Freeze-Cast LiNi _0.8 Co _0.15 Al _0.05 O ₂ (NCA) Delattre, Benjamin; Amin, Ruhul; Sander, Jonathan Journal of The Electrochemical Society, Vol. 165, Issue 2 https://doi.org/10.1149/2.1321802jes	journal	January 2018
Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries Thackeray, Michael M.; Wolverton, Christopher; Isaacs, Eric D. Energy & Environmental Science, Vol. 5, Issue 7 https://doi.org/10.1039/c2ee21892e	journal	January 2012
Freeze-Casting of Porous Ceramics: A Review of Current Achievements and Issues Deville, S. Advanced Engineering Materials, Vol. 10, Issue 3, p. 155-169 https://doi.org/10.1002/adem.200700270	journal	March 2008
Design of Battery Electrodes with Dual-Scale Porosity to Minimize Tortuosity and Maximize Performance Bae, Chang-Jun; Erdonmez, Can K.; Halloran, John W. Advanced Materials, Vol. 25, Issue 9 https://doi.org/10.1002/adma.201204055	journal	December 2012
Electrochemical Cycle-Life Characterization of High Energy Lithium-Ion Cells with Thick Li(Ni _0.6 Mn _0.2 Co _0.2 )O ₂ and Graphite Electrodes Leng, Yongjun; Ge, Shanhai; Marple, Dan Journal of The Electrochemical Society, Vol. 164, Issue 6 https://doi.org/10.1149/2.0451706jes	journal	January 2017
Fabrication of cellular and lamellar LiFePO₄/C Cathodes for Li-ion batteries by unidirectional freeze-casting method Zavareh, Sara; Hilger, André; Hirselandt, Kathrin Journal of the Ceramic Society of Japan, Vol. 124, Issue 10 https://doi.org/10.2109/jcersj2.16126	journal	January 2016
Revisiting the promise of Bi-layer graded cathodes for improved Li-ion battery performance Chowdhury, Ridwanur; Zhao, Yan; Xia, Yuhua Sustainable Energy & Fuels, Vol. 5, Issue 20 https://doi.org/10.1039/D1SE01077H	journal	January 2021
Determination of the chemical diffusion coefficient of Li+ in intercalation-type Li3V2(PO4)3 anode material Rui, X. H.; Yesibolati, N.; Li, S. R. Solid State Ionics, Vol. 187, Issue 1 https://doi.org/10.1016/j.ssi.2011.02.013	journal	April 2011
Modeling mass and density distribution effects on the performance of co-extruded electrodes for high energy density lithium-ion batteries Cobb, Corie L.; Blanco, Mario Journal of Power Sources, Vol. 249 https://doi.org/10.1016/j.jpowsour.2013.10.084	journal	March 2014
Weakly solvating electrolytes for next-generation lithium batteries: design principles and recent advances Wang, Zhijie; Zhang, Biao Energy Materials and Devices, Vol. 1, Issue 1 https://doi.org/10.26599/EMD.2023.9370003	journal	September 2023

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25 ENERGY STORAGE
bilayered electrode
electrode processing
energy density
power density
high-loading electrode
freeze tape casting

Title: Freeze Tape Casting Electrode with Bilayered Architecture for High-Performance Lithium-Ion Batteries

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