A Critical Analysis of Chemical and Electrochemical Oxidation Mechanisms in Li-Ion Batteries

Spotte-Smith, Evan Walter Clark; Vijay, Sudarshan; Petrocelli, Thea Bee; Rinkel, Bernardine L. D.; McCloskey, Bryan D.; Persson, Kristin A.

doi:10.1021/acs.jpclett.3c03279

Title: A Critical Analysis of Chemical and Electrochemical Oxidation Mechanisms in Li-Ion Batteries

Journal Article · 04 January 2024 · Journal of Physical Chemistry Letters

DOI: https://doi.org/10.1021/acs.jpclett.3c03279 · OSTI ID:2278728

^[1]; Vijay, Sudarshan ^[2]; Petrocelli, Thea Bee ^[2]; Rinkel, Bernardine L. D. ^[3];

^[3];

^[4]

Department of Materials Science and Engineering, University of California, Berkeley, 210 Hearst Memorial Mining Building, Berkeley, California 94720, United States, Materials Science Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720, United States
Department of Materials Science and Engineering, University of California, Berkeley, 210 Hearst Memorial Mining Building, Berkeley, California 94720, United States
Department of Chemical and Biomolecular Engineering, University of California, Berkeley, 201 Gilman Hall, Berkeley, California 94720, United States, Energy Storage and Distributed Resources, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720, United States
Department of Materials Science and Engineering, University of California, Berkeley, 210 Hearst Memorial Mining Building, Berkeley, California 94720, United States, Molecular Foundry, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720, United States

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Science (SC), Office of Workforce Development for Teachers & Scientists (WDTS)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2278728

Journal Information:: Journal of Physical Chemistry Letters, Journal Name: Journal of Physical Chemistry Letters Journal Issue: 2 Vol. 15; ISSN 1948-7185

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (72)

Face to Face at the Cathode Electrolyte Interphase: From Interface Features to Interphase Formation and Dynamics Kühn, Sebastian P.; Edström, Kristina; Winter, Martin Advanced Materials Interfaces, Vol. 9, Issue 8 https://doi.org/10.1002/admi.202102078	journal	January 2022
Structural and Chemical Evolution of the Layered Li-Excess Li _x MnO ₃ as a Function of Li Content from First-Principles Calculations Lee, Eunseok; Persson, Kristin A. Advanced Energy Materials, Vol. 4, Issue 15 https://doi.org/10.1002/aenm.201400498	journal	June 2014
Improved Cycling Performance of Li-Excess Cation-Disordered Cathode Materials upon Fluorine Substitution Lun, Zhengyan; Ouyang, Bin; Kitchaev, Daniil A. Advanced Energy Materials, Vol. 9, Issue 2 https://doi.org/10.1002/aenm.201802959	journal	November 2018
Quantitative Decoupling of Oxygen‐Redox and Manganese‐Redox Voltage Hysteresis in a Cation‐Disordered Rock Salt Cathode Huang, Tzu‐Yang; Cai, Zijian; Crafton, Matthew J. Advanced Energy Materials, Vol. 13, Issue 21 https://doi.org/10.1002/aenm.202300241	journal	April 2023
Research Progress in Lithium‐Excess Disordered Rock‐Salt Oxides Cathode Wang, Manxi; Chen, Xiaochuan; Yao, Hurong ENERGY & ENVIRONMENTAL MATERIALS, Vol. 5, Issue 4 https://doi.org/10.1002/eem2.12413	journal	October 2022
Review of Chemical Reactivity of Singlet Oxygen with Organic Fuels and Contaminants Al‐Nu'airat, Jomana; Oluwoye, Ibukun; Zeinali, Nassim The Chemical Record, Vol. 21, Issue 2 https://doi.org/10.1002/tcr.202000143	journal	December 2020
In Situ Structural and Electrochemical Study of Ni1−xCoxO2 Metastable Oxides Prepared by Soft Chemistry Tarascon, J. M.; Vaughan, G.; Chabre, Y. Journal of Solid State Chemistry, Vol. 147, Issue 1 https://doi.org/10.1006/jssc.1999.8465	journal	October 1999
Dissociative electron transfer reactions Maletin, Yurii A.; Cannon, Roderick D. Theoretical and Experimental Chemistry, Vol. 34, Issue 2, p. 57-68 https://doi.org/10.1007/BF02764428	journal	March 1998
New Mechanistic and Synthetic Aspects of Singlet Oxygen Chemistry Clennan, Edward L. Tetrahedron, Vol. 56, Issue 47 https://doi.org/10.1016/S0040-4020(00)00794-8	journal	November 2000
LiPF6–EC–EMC electrolyte for Li-ion battery Zhang, S. S.; Jow, T. R.; Amine, K. Journal of Power Sources, Vol. 107, Issue 1 https://doi.org/10.1016/S0378-7753(01)00968-5	journal	April 2002
Electrolytes for advanced batteries Blomgren, George E. Journal of Power Sources, Vol. 81-82 https://doi.org/10.1016/S0378-7753(99)00188-3	journal	September 1999
Python Materials Genomics (pymatgen): A robust, open-source python library for materials analysis Ong, Shyue Ping; Richards, William Davidson; Jain, Anubhav Computational Materials Science, Vol. 68 https://doi.org/10.1016/j.commatsci.2012.10.028	journal	February 2013
A review of gas evolution in lithium ion batteries Rowden, Ben; Garcia-Araez, Nuria Energy Reports, Vol. 6 https://doi.org/10.1016/j.egyr.2020.02.022	journal	May 2020
A disordered rock-salt Li-excess cathode material with high capacity and substantial oxygen redox activity: Li 1.25 Nb 0.25 Mn 0.5 O 2 Wang, Rui; Li, Xin; Liu, Lei Electrochemistry Communications, Vol. 60 https://doi.org/10.1016/j.elecom.2015.08.003	journal	November 2015
Oxygen hole formation controls stability in LiNiO2 cathodes Genreith-Schriever, Annalena R.; Banerjee, Hrishit; Menon, Ashok S. Joule, Vol. 7, Issue 7 https://doi.org/10.1016/j.joule.2023.06.017	journal	July 2023
Functional electrolytes: Novel type additives for cathode materials, providing high cycleability performance Abe, Koji; Ushigoe, Yoshihiro; Yoshitake, Hideya Journal of Power Sources, Vol. 153, Issue 2 https://doi.org/10.1016/j.jpowsour.2005.05.067	journal	February 2006
Singlet oxygen evolution from layered transition metal oxide cathode materials and its implications for lithium-ion batteries Wandt, Johannes; Freiberg, Anna T. S.; Ogrodnik, Alexander Materials Today, Vol. 21, Issue 8 https://doi.org/10.1016/j.mattod.2018.03.037	journal	October 2018
Surface Lithium Carbonate Influences Electrolyte Degradation via Reactive Oxygen Attack in Lithium-Excess Cathode Materials Kaufman, Lori A.; McCloskey, Bryan D. Chemistry of Materials, Vol. 33, Issue 11 https://doi.org/10.1021/acs.chemmater.1c00935	journal	May 2021
Reaction of Singlet Oxygen with the Ethylene Group: Implications for Electrolyte Stability in Li-Ion and Li-O₂ Batteries Mullinax, J. Wayne; Bauschlicher, Charles W.; Lawson, John W. The Journal of Physical Chemistry A, Vol. 125, Issue 14 https://doi.org/10.1021/acs.jpca.1c00605	journal	April 2021
Singlet Oxygen Reactivity with Carbonate Solvents Used for Li-Ion Battery Electrolytes Freiberg, Anna T. S.; Roos, Matthias K.; Wandt, Johannes The Journal of Physical Chemistry A, Vol. 122, Issue 45 https://doi.org/10.1021/acs.jpca.8b08079	journal	October 2018
Theoretical Prediction of the Strong Solvent Effect on Reduced Ethylene Carbonate Ring-Opening and Its Impact on Solid Electrolyte Interphase Evolution Boyer, Mathew J.; Hwang, Gyeong S. The Journal of Physical Chemistry C, Vol. 123, Issue 29 https://doi.org/10.1021/acs.jpcc.9b03146	journal	July 2019
Chemical Reactivity Descriptor for the Oxide-Electrolyte Interface in Li-Ion Batteries Giordano, Livia; Karayaylali, Pinar; Yu, Yang The Journal of Physical Chemistry Letters, Vol. 8, Issue 16 https://doi.org/10.1021/acs.jpclett.7b01655	journal	August 2017
Chemical versus Electrochemical Electrolyte Oxidation on NMC111, NMC622, NMC811, LNMO, and Conductive Carbon Jung, Roland; Metzger, Michael; Maglia, Filippo The Journal of Physical Chemistry Letters, Vol. 8, Issue 19 https://doi.org/10.1021/acs.jpclett.7b01927	journal	September 2017
Solvent Degradation and Polymerization in the Li-Metal Battery: Organic-Phase Formation in Solid-Electrolyte Interphases Kuai, Dacheng; Balbuena, Perla B. ACS Applied Materials & Interfaces, Vol. 14, Issue 2 https://doi.org/10.1021/acsami.1c20487	journal	January 2022
Impact of Selected LiPF ₆ Hydrolysis Products on the High Voltage Stability of Lithium-Ion Battery Cells Wagner, Ralf; Korth, Martin; Streipert, Benjamin ACS Applied Materials & Interfaces, Vol. 8, Issue 45 https://doi.org/10.1021/acsami.6b09164	journal	November 2016
Ab Initio Modeling of Electrolyte Molecule Ethylene Carbonate Decomposition Reaction on Li(Ni,Mn,Co)O ₂ Cathode Surface Xu, Shenzhen; Luo, Guangfu; Jacobs, Ryan ACS Applied Materials & Interfaces, Vol. 9, Issue 24 https://doi.org/10.1021/acsami.7b03435	journal	June 2017
Critical Factors Controlling Superoxide Reactions in Lithium–Oxygen Batteries Wang, Yu; Lu, Ying-Rui; Dong, Chung-Li ACS Energy Letters, Vol. 5, Issue 5 https://doi.org/10.1021/acsenergylett.0c00365	journal	March 2020
Hydrolysis of LiPF ₆ -Containing Electrolyte at High Voltage Liu, Mingzhu; Vatamanu, Jenel; Chen, Xinli ACS Energy Letters, Vol. 6, Issue 6 https://doi.org/10.1021/acsenergylett.1c00707	journal	May 2021
Role of Electrolyte Oxidation and Difluorophosphoric Acid Generation in Crossover and Capacity Fade in Lithium Ion Batteries Jayawardana, Chamithri; Rodrigo, Nuwanthi; Parimalam, Bharathy ACS Energy Letters, Vol. 6, Issue 11 https://doi.org/10.1021/acsenergylett.1c01657	journal	October 2021
Toward a Mechanistic Model of Solid–Electrolyte Interphase Formation and Evolution in Lithium-Ion Batteries Spotte-Smith, Evan Walter Clark; Kam, Ronald L.; Barter, Daniel ACS Energy Letters, Vol. 7, Issue 4 https://doi.org/10.1021/acsenergylett.2c00517	journal	March 2022
Onset Potential for Electrolyte Oxidation and Ni-Rich Cathode Degradation in Lithium-Ion Batteries Dose, Wesley M.; Li, Weiqun; Temprano, Israel ACS Energy Letters, Vol. 7, Issue 10 https://doi.org/10.1021/acsenergylett.2c01722	journal	September 2022
Elementary Decomposition Mechanisms of Lithium Hexafluorophosphate in Battery Electrolytes and Interphases Spotte-Smith, Evan Walter Clark; Petrocelli, Thea Bee; Patel, Hetal D. ACS Energy Letters, Vol. 8, Issue 1 https://doi.org/10.1021/acsenergylett.2c02351	journal	December 2022
Correlation Between Oxygen Vacancy, Microstrain, and Cation Distribution in Lithium-Excess Layered Oxides During the First Electrochemical Cycle Fell, Christopher R.; Qian, Danna; Carroll, Kyler J. Chemistry of Materials, Vol. 25, Issue 9 https://doi.org/10.1021/cm4000119	journal	April 2013
Physical Mechanisms of Generation and Deactivation of Singlet Oxygen Schweitzer, Claude; Schmidt, Reinhard Chemical Reviews, Vol. 103, Issue 5 https://doi.org/10.1021/cr010371d	journal	May 2003
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
Theoretical Studies To Understand Surface Chemistry on Carbon Anodes for Lithium-Ion Batteries: Reduction Mechanisms of Ethylene Carbonate Wang, Yixuan; Nakamura, Shinichiro; Ue, Makoto Journal of the American Chemical Society, Vol. 123, Issue 47 https://doi.org/10.1021/ja0164529	journal	November 2001
Electrolyte Oxidation Pathways in Lithium-Ion Batteries Rinkel, Bernardine L. D.; Hall, David S.; Temprano, Israel Journal of the American Chemical Society, Vol. 142, Issue 35 https://doi.org/10.1021/jacs.0c06363	journal	July 2020
Nanostructure Transformation as a Signature of Oxygen Redox in Li-Rich 3d and 4d Cathodes Grenier, Antonin; Kamm, Gabrielle E.; Li, Yixuan Journal of the American Chemical Society, Vol. 143, Issue 15 https://doi.org/10.1021/jacs.1c00497	journal	April 2021
The Only Stable State of O ₂ ^- Is the X ² Π _g Ground State and It (Still!) Has an Adiabatic Electron Detachment Energy of 0.45 eV Ervin, Kent M.; Anusiewicz, Iwona; Skurski, Piotr The Journal of Physical Chemistry A, Vol. 107, Issue 41 https://doi.org/10.1021/jp0357323	journal	October 2003
Predicting Solvent Stability in Aprotic Electrolyte Li–Air Batteries: Nucleophilic Substitution by the Superoxide Anion Radical (O ₂ ^•– ) Bryantsev, Vyacheslav S.; Giordani, Vincent; Walker, Wesley The Journal of Physical Chemistry A, Vol. 115, Issue 44 https://doi.org/10.1021/jp2073914	journal	November 2011
Lithium Ion Battery Graphite Solid Electrolyte Interphase Revealed by Microscopy and Spectroscopy Nie, Mengyun; Chalasani, Dinesh; Abraham, Daniel P. The Journal of Physical Chemistry C, Vol. 117, Issue 3, p. 1257-1267 https://doi.org/10.1021/jp3118055	journal	January 2013
Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions Marenich, Aleksandr V.; Cramer, Christopher J.; Truhlar, Donald G. The Journal of Physical Chemistry B, Vol. 113, Issue 18, p. 6378-6396 https://doi.org/10.1021/jp810292n	journal	May 2009
Raman Evidence for Late Stage Disproportionation in a Li–O₂ Battery Zhai, Dengyun; Wang, Hsien-Hau; Lau, Kah Chun The Journal of Physical Chemistry Letters, Vol. 5, Issue 15, p. 2705-2710 https://doi.org/10.1021/jz501323n	journal	July 2014
Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen Luo, Kun; Roberts, Matthew R.; Hao, Rong Nature Chemistry, Vol. 8, Issue 7 https://doi.org/10.1038/nchem.2471	journal	March 2016
Metal–oxygen decoordination stabilizes anion redox in Li-rich oxides Hong, Jihyun; Gent, William E.; Xiao, Penghao Nature Materials, Vol. 18, Issue 3 https://doi.org/10.1038/s41563-018-0276-1	journal	February 2019
Quantum chemical calculations of lithium-ion battery electrolyte and interphase species Spotte-Smith, Evan Walter Clark; Blau, Samuel M.; Xie, Xiaowei Scientific Data, Vol. 8, Issue 1 https://doi.org/10.1038/s41597-021-00986-9	journal	August 2021
The intriguing question of anionic redox in high-energy density cathodes for Li-ion batteries Saubanère, M.; McCalla, E.; Tarascon, J. -M. Energy & Environmental Science, Vol. 9, Issue 3 https://doi.org/10.1039/C5EE03048J	journal	January 2016
First-principles study on thermodynamic stability of the hybrid interfacial structure of LiMn ₂ O ₄ cathode and carbonate electrolyte in Li-ion batteries Choi, Daehyeon; Kang, Joonhee; Park, Jinwoo Physical Chemistry Chemical Physics, Vol. 20, Issue 17 https://doi.org/10.1039/C7CP08037A	journal	January 2018
Revealing electrolyte oxidation via carbonate dehydrogenation on Ni-based oxides in Li-ion batteries by in situ Fourier transform infrared spectroscopy Zhang, Yirui; Katayama, Yu; Tatara, Ryoichi Energy & Environmental Science, Vol. 13, Issue 1 https://doi.org/10.1039/C9EE02543J	journal	January 2020
Two electrolyte decomposition pathways at nickel-rich cathode surfaces in lithium-ion batteries Rinkel, Bernardine L. D.; Vivek, J. Padmanabhan; Garcia-Araez, Nuria Energy & Environmental Science, Vol. 15, Issue 8 https://doi.org/10.1039/D1EE04053G	journal	January 2022
Chasing protons in lithium-ion batteries Chen, Zonghai Chemical Communications, Vol. 58, Issue 73 https://doi.org/10.1039/D2CC03970B	journal	January 2022
Predictive stochastic analysis of massive filter-based electrochemical reaction networks Barter, Daniel; Clark Spotte-Smith, Evan Walter; Redkar, Nikita S. Digital Discovery, Vol. 2, Issue 1 https://doi.org/10.1039/D2DD00117A	journal	January 2023
A database of molecular properties integrated in the Materials Project Spotte-Smith, Evan Walter Clark; Cohen, Orion Archer; Blau, Samuel M. Digital Discovery, Vol. 2, Issue 6 https://doi.org/10.1039/D3DD00153A	journal	January 2023
Oxidation induced decomposition of ethylene carbonate from DFT calculations – importance of explicitly treating surrounding solvent Xing, Lidan; Borodin, Oleg Physical Chemistry Chemical Physics, Vol. 14, Issue 37 https://doi.org/10.1039/c2cp41103b	journal	January 2012
Evidence for lithium superoxide-like species in the discharge product of a Li–O₂ battery Yang, Junbing; Zhai, Dengyun; Wang, Hsien-Hau Physical Chemistry Chemical Physics, Vol. 15, Issue 11, p. 3764-3771 https://doi.org/10.1039/c3cp00069a	journal	January 2013
ωB97X-V: A 10-parameter, range-separated hybrid, generalized gradient approximation density functional with nonlocal correlation, designed by a survival-of-the-fittest strategy Mardirossian, Narbe; Head-Gordon, Martin Physical Chemistry Chemical Physics, Vol. 16, Issue 21 https://doi.org/10.1039/c3cp54374a	journal	January 2014
Property-optimized Gaussian basis sets for molecular response calculations Rappoport, Dmitrij; Furche, Filipp The Journal of Chemical Physics, Vol. 133, Issue 13 https://doi.org/10.1063/1.3484283	journal	October 2010
Software for the frontiers of quantum chemistry: An overview of developments in the Q-Chem 5 package Epifanovsky, Evgeny; Gilbert, Andrew T. B.; Feng, Xintian The Journal of Chemical Physics, Vol. 155, Issue 8 https://doi.org/10.1063/5.0055522	journal	August 2021
Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries McCalla, E.; Abakumov, A. M.; Saubanere, M. Science, Vol. 350, Issue 6267 https://doi.org/10.1126/science.aac8260	journal	December 2015
Toward Reliable Values of Electrochemical Stability Limits for Electrolytes Xu, Kang Journal of The Electrochemical Society, Vol. 146, Issue 11 https://doi.org/10.1149/1.1392609	journal	January 1999
Oxygen Transport Properties of Organic Electrolytes and Performance of Lithium/Oxygen Battery Read, J.; Mutolo, K.; Ervin, M. Journal of The Electrochemical Society, Vol. 150, Issue 10 https://doi.org/10.1149/1.1606454	journal	January 2003
Electrochemical Properties of Quaternary Ammonium Salts for Electrochemical Capacitors Ue, Makoto Journal of The Electrochemical Society, Vol. 144, Issue 8 https://doi.org/10.1149/1.1837882	journal	January 1997
Assessing the Oxidation Behavior of EC:DMC Based Electrolyte on Non-Catalytically Active Surface Azcarate, Iban; Yin, Wei; Méthivier, Christophe Journal of The Electrochemical Society, Vol. 167, Issue 8 https://doi.org/10.1149/1945-7111/ab8f57	journal	January 2020
Perspective—Surface Reactions of Electrolyte with LiNi _x Co _y Mn _z O ₂ Cathodes for Lithium Ion Batteries Heiskanen, Satu Kristiina; Laszczynski, Nina; Lucht, Brett L. Journal of The Electrochemical Society, Vol. 167, Issue 10 https://doi.org/10.1149/1945-7111/ab981c	journal	June 2020
Oxygen Release and Its Effect on the Cycling Stability of LiNi _x Mn _y Co _z O ₂ (NMC) Cathode Materials for Li-Ion Batteries Jung, Roland; Metzger, Michael; Maglia, Filippo Journal of The Electrochemical Society, Vol. 164, Issue 7 https://doi.org/10.1149/2.0021707jes	journal	January 2017
Crystal Surface and State of Charge Dependencies of Electrolyte Decomposition on LiMn ₂ O ₄ Cathode Kumar, Nitin; Leung, Kevin; Siegel, Donald J. Journal of The Electrochemical Society, Vol. 161, Issue 8 https://doi.org/10.1149/2.009408jes	journal	January 2014
Quantification of PF ₅ and POF ₃ from Side Reactions of LiPF ₆ in Li-Ion Batteries Solchenbach, Sophie; Metzger, Michael; Egawa, Masamitsu Journal of The Electrochemical Society, Vol. 165, Issue 13 https://doi.org/10.1149/2.0481813jes	journal	January 2018
Anodic Oxidation of Conductive Carbon and Ethylene Carbonate in High-Voltage Li-Ion Batteries Quantified by On-Line Electrochemical Mass Spectrometry Metzger, Michael; Marino, Cyril; Sicklinger, Johannes Journal of The Electrochemical Society, Vol. 162, Issue 7 https://doi.org/10.1149/2.0951506jes	journal	January 2015
The absolute electrode potential: an explanatory note (Recommendations 1986) Trasatti, S. Pure and Applied Chemistry, Vol. 58, Issue 7 https://doi.org/10.1351/pac198658070955	journal	January 1986
The Solid Electrolyte Interphase – The Most Important and the Least Understood Solid Electrolyte in Rechargeable Li Batteries Winter, Martin Zeitschrift für Physikalische Chemie, Vol. 223, Issue 10-11 https://doi.org/10.1524/zpch.2009.6086	journal	December 2009
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