Comparison of direct and CO2-oxidative dehydrogenation of propane

Yuan, Yong; Porter, William N.; Chen, Jingguang G.

doi:10.1016/j.trechm.2023.09.001

Title: Comparison of direct and CO₂-oxidative dehydrogenation of propane

Journal Article · 29 September 2023 · Trends in Chemistry

DOI: https://doi.org/10.1016/j.trechm.2023.09.001 · OSTI ID:2267553

^[1]; Porter, William N. ^[2];

^[3]

Brookhaven National Laboratory (BNL), Upton, NY (United States)
Columbia University, New York, NY (United States)
Brookhaven National Laboratory (BNL), Upton, NY (United States); Columbia University, New York, NY (United States)

Propane dehydrogenation to propylene has received increasing attention due to the fast growth in propylene demand and the exploration of shale gas containing propane. Direct dehydrogenation of propane (DDHP) offers high propylene selectivity but is limited by quick deactivation due to coke formation. CO₂-assisted oxidative dehydrogenation of propane (CO₂-ODHP) can consume CO₂ and meanwhile reduce coke deposition via the reverse Boudouard reaction. Here in the current review, direct and CO₂-assisted dehydrogenation of propane has been compared from three aspects: reaction mechanisms, catalyst compositions, and CO₂ footprint analysis. As the average CO₂ emissions from electricity generation decrease due to the utilization of renewable energy, CO₂-ODHP potentially leads to a net-negative CO₂ footprint while DDHP cannot.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 2267553

Alternate ID(s):: OSTI ID: 2204763

Report Number(s):: BNL-225112-2023-JAAM; GRP-COCAFP-5

Journal Information:: Trends in Chemistry, Vol. 5, Issue 11; ISSN 2589-5974

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (95)

Effect of a Ce Promoter on Nonoxidative Dehydrogenation of Propane over the Commercial Cr/Al ₂ O ₃ Catalyst Zhang, Yaliu; Yang, Shuang; Lu, Jichang Industrial & Engineering Chemistry Research, Vol. 58, Issue 43 https://doi.org/10.1021/acs.iecr.9b03870	journal	October 2019
Interfacial Active Sites for CO2 Assisted Selective Cleavage of C–C/C–H Bonds in Ethane Xie, Zhenhua; Tian, Dong; Xie, Meng Chem, Vol. 6, Issue 10 https://doi.org/10.1016/j.chempr.2020.07.011	journal	October 2020
The nature of active chromium species in Cr-catalysts for dehydrogenation of propane: New insights by a comprehensive spectroscopic study Santhoshkumar, M.; Hammer, N.; Ronning, M. Journal of Catalysis, Vol. 261, Issue 1 https://doi.org/10.1016/j.jcat.2008.11.014	journal	January 2009
Doubly Decorated Platinum–Gallium Intermetallics as Stable Catalysts for Propane Dehydrogenation Nakaya, Yuki; Xing, Feilong; Ham, Hyungwon Angewandte Chemie International Edition, Vol. 60, Issue 36 https://doi.org/10.1002/anie.202107210	journal	July 2021
Rod-shaped porous alumina-supported Cr2O3 catalyst with low acidity for propane dehydrogenation Gao, Xin-Qian; Lu, Wen-Duo; Hu, Shou-Zhao Chinese Journal of Catalysis, Vol. 40, Issue 2 https://doi.org/10.1016/S1872-2067(18)63202-4	journal	February 2019
Can CO2-assisted alkane dehydrogenation lead to negative CO2 emissions? Biswas, Akash N.; Xie, Zhenhua; Chen, Jingguang G. Joule, Vol. 6, Issue 2 https://doi.org/10.1016/j.joule.2021.12.008	journal	February 2022
Regioselective generation and reactivity control of subnanometric platinum clusters in zeolites for high-temperature catalysis Liu, Lichen; Lopez-Haro, Miguel; Lopes, Christian W. Nature Materials, Vol. 18, Issue 8 https://doi.org/10.1038/s41563-019-0412-6	journal	July 2019
Silica-supported isolated gallium sites as highly active, selective and stable propane dehydrogenation catalysts Searles, Keith; Siddiqi, Georges; Safonova, Olga V. Chemical Science, Vol. 8, Issue 4 https://doi.org/10.1039/C6SC05178B	journal	January 2017
Dehydrogenation of propane in the presence of CO2 over GaN/SiO2 catalysts: Relationship between the type of SiO2 and the activity Wang, Zhong-Yu; He, Zhen-Hong; Sun, Yong-Chang Chemical Engineering Journal, Vol. 433 https://doi.org/10.1016/j.cej.2021.134443	journal	April 2022
Elucidating the Support-Size Effect on the Catalytic Stability of CrOx/Silicalite-1 for Oxidative Dehydrogenation of Propane with CO2 Wang, Jian; Song, Yong-Hong; Yuan, En-Hui Catalysis Letters, Vol. 153, Issue 3 https://doi.org/10.1007/s10562-022-04012-4	journal	April 2022
General Descriptors for CO ₂ -Assisted Selective C–H/C–C Bond Scission in Ethane Xie, Zhenhua; Wang, Xuelong; Chen, Xiaobo Journal of the American Chemical Society, Vol. 144, Issue 9 https://doi.org/10.1021/jacs.1c13415	journal	February 2022
Propane Dehydrogenation over Pt Clusters Localized at the Sn Single-Site in Zeolite Framework Xu, Zhikang; Yue, Yuanyuan; Bao, Xiaojun ACS Catalysis, Vol. 10, Issue 1 https://doi.org/10.1021/acscatal.9b03527	journal	December 2019
CrO supported on high-silica HZSM-5 for propane dehydrogenation Hu, Zhong-Pan; Wang, Yansu; Yang, Dandan Journal of Energy Chemistry, Vol. 47 https://doi.org/10.1016/j.jechem.2019.12.010	journal	August 2020
Control of coordinatively unsaturated Zr sites in ZrO2 for efficient C–H bond activation Zhang, Yaoyuan; Zhao, Yun; Otroshchenko, Tatiana Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06174-5	journal	September 2018
Catalytic Dehydrogenation of Light Alkanes on Metals and Metal Oxides Sattler, Jesper J. H. B.; Ruiz-Martinez, Javier; Santillan-Jimenez, Eduardo Chemical Reviews, Vol. 114, Issue 20 https://doi.org/10.1021/cr5002436	journal	August 2014
Catalysts for Production of Lower Olefins from Synthesis Gas: A Review Torres Galvis, Hirsa M.; de Jong, Krijn P. ACS Catalysis, Vol. 3, Issue 9 https://doi.org/10.1021/cs4003436	journal	August 2013
Highly Productive Propane Dehydrogenation Catalyst Using Silica-Supported Ga–Pt Nanoparticles Generated from Single-Sites Searles, Keith; Chan, Ka Wing; Mendes Burak, Jorge Augusto Journal of the American Chemical Society, Vol. 140, Issue 37 https://doi.org/10.1021/jacs.8b05378	journal	August 2018
Castanea mollissima shell-derived porous carbons as metal-free catalysts for highly efficient dehydrogenation of propane to propylene Hu, Zhong-Pan; Zhao, Hui; Chen, Chong Catalysis Today, Vol. 316 https://doi.org/10.1016/j.cattod.2018.01.010	journal	October 2018
Propane Dehydrogenation Catalyzed by Isolated Pt Atoms in ≡SiOZn–OH Nests in Dealuminated Zeolite Beta Qi, Liang; Babucci, Melike; Zhang, Yanfei Journal of the American Chemical Society, Vol. 143, Issue 50 https://doi.org/10.1021/jacs.1c10261	journal	December 2021
Catalyst design and tuning for oxidative dehydrogenation of propane – A review Gambo, Yahya; Adamu, Sagir; Abdulrasheed, Abdulrahman A. Applied Catalysis A: General, Vol. 609 https://doi.org/10.1016/j.apcata.2020.117914	journal	January 2021
Subnanometer Bimetallic Platinum–Zinc Clusters in Zeolites for Propane Dehydrogenation Sun, Qiming; Wang, Ning; Fan, Qiyuan Angewandte Chemie International Edition, Vol. 59, Issue 44 https://doi.org/10.1002/anie.202003349	journal	May 2020
Isolated Pt Species Anchored by Hierarchical-like Heteroatomic Fe-Silicalite-1 Catalyze Propane Dehydrogenation near the Thermodynamic Limit Liu, Hao; Zhou, Jie; Chen, Tianxiang ACS Catalysis, Vol. 13, Issue 5 https://doi.org/10.1021/acscatal.2c05042	journal	February 2023
Stable Cr-MFI Catalysts for the Nonoxidative Dehydrogenation of Ethane: Catalytic Performance and Nature of the Active Sites De, Sudipta; Ould-Chikh, Samy; Aguilar, Antonio ACS Catalysis, Vol. 11, Issue 7 https://doi.org/10.1021/acscatal.0c05170	journal	March 2021
Propane Dehydrogenation over Alumina-Supported Iron/Phosphorus Catalysts: Structural Evolution of Iron Species Leading to High Activity and Propylene Selectivity Tan, Shuai; Hu, Bo; Kim, Wun-Gwi ACS Catalysis, Vol. 6, Issue 9 https://doi.org/10.1021/acscatal.6b01286	journal	July 2016
Direct dehydrogenation of propane to propylene on surface-oxidized multiwall carbon nanotubes Hu, Zhong-Pan; Chen, Chong; Ren, Jin-Tao Applied Catalysis A: General, Vol. 559 https://doi.org/10.1016/j.apcata.2018.04.017	journal	June 2018
Mechanism and Kinetics of Propane Dehydrogenation and Cracking over Ga/H-MFI Prepared via Vapor-Phase Exchange of H-MFI with GaCl ₃ Phadke, Neelay M.; Mansoor, Erum; Bondil, Matthieu Journal of the American Chemical Society, Vol. 141, Issue 4 https://doi.org/10.1021/jacs.8b11443	journal	December 2018
Ce_xZr_1–xO₂-Supported CrO_x Catalysts for CO₂-Assisted Oxidative Dehydrogenation of Propane─Probing the Active Sites and Strategies for Enhanced Stability Dou, Jian; Funderburg, Joey; Yang, Kunran ACS Catalysis, Vol. 13, Issue 1 https://doi.org/10.1021/acscatal.2c05286	journal	December 2022
Net reduction of CO2 via its thermocatalytic and electrocatalytic transformation reactions in standard and hybrid processes Tackett, Brian M.; Gomez, Elaine; Chen, Jingguang G. Nature Catalysis, Vol. 2, Issue 5 https://doi.org/10.1038/s41929-019-0266-y	journal	April 2019
CeO2-Promoted PtSn/SiO2 as a High-Performance Catalyst for the Oxidative Dehydrogenation of Propane with Carbon Dioxide Wang, Li; Yang, Guo-Qing; Ren, Xing Nanomaterials, Vol. 12, Issue 3 https://doi.org/10.3390/nano12030417	journal	January 2022
Isolated Fe ^II on Silica As a Selective Propane Dehydrogenation Catalyst Hu, Bo; Schweitzer, Neil M.; Zhang, Guanghui ACS Catalysis, Vol. 5, Issue 6 https://doi.org/10.1021/acscatal.5b00248	journal	May 2015
CO2-Assisted Dehydrogenation of Propane to Propene over Zn-BEA Zeolites: Impact of Acid–Base Characteristics on Catalytic Performance Orlyk, Svitlana; Kyriienko, Pavlo; Kapran, Andriy Catalysts, Vol. 13, Issue 4 https://doi.org/10.3390/catal13040681	journal	March 2023
Size Dependence of Pt Catalysts for Propane Dehydrogenation: from Atomically Dispersed to Nanoparticles Zhang, Wei; Wang, Haizhi; Jiang, Jiawei ACS Catalysis, Vol. 10, Issue 21 https://doi.org/10.1021/acscatal.0c03286	journal	October 2020
Subsurface-Regulated PtGa Nanoparticles Confined in Silicalite-1 for Propane Dehydrogenation Zhang, Bofeng; Zheng, Lirong; Zhai, Ziwei ACS Applied Materials & Interfaces, Vol. 13, Issue 14 https://doi.org/10.1021/acsami.0c22865	journal	April 2021
Oxide–Zeolite-Based Composite Catalyst Concept That Enables Syngas Chemistry beyond Fischer–Tropsch Synthesis Pan, Xiulian; Jiao, Feng; Miao, Dengyun Chemical Reviews, Vol. 121, Issue 11 https://doi.org/10.1021/acs.chemrev.0c01012	journal	May 2021
Active Centers of Catalysts for Higher Alcohol Synthesis from Syngas: A Review Ao, Min; Pham, Gia Hung; Sunarso, Jaka ACS Catalysis, Vol. 8, Issue 8 https://doi.org/10.1021/acscatal.8b01391	journal	June 2018
Direct conversion of CO₂ into aromatics over multifunctional heterogeneous catalysts Sibi, Malayil Gopalan; Verma, Deepak; Kim, Jaehoon Catalysis Reviews https://doi.org/10.1080/01614940.2022.2099058	journal	July 2022
Ternary platinum–cobalt–indium nanoalloy on ceria as a highly efficient catalyst for the oxidative dehydrogenation of propane using CO2 Xing, Feilong; Nakaya, Yuki; Yasumura, Shunsaku Nature Catalysis, Vol. 5, Issue 1 https://doi.org/10.1038/s41929-021-00730-x	journal	January 2022
Oxidative Dehydrogenation of Propane with Carbon Dioxide Catalyzed by Zn_xZr_1–xO_2–x Solid Solutions Yang, Guo-Qing; He, Ya-Jiao; Song, Yong-Hong Industrial & Engineering Chemistry Research, Vol. 60, Issue 49 https://doi.org/10.1021/acs.iecr.1c03476	journal	December 2021
Promoting Propane Dehydrogenation with CO₂ over the PtFe Bimetallic Catalyst by Eliminating the Non-selective Fe(0) Phase Bian, Kai; Zhang, Guanghui; Zhu, Jie ACS Catalysis, Vol. 12, Issue 11 https://doi.org/10.1021/acscatal.2c00649	journal	May 2022
Research progress of CO2 oxidative dehydrogenation of propane to propylene over Cr-free metal catalysts Wang, Zhong-Yu; He, Zhen-Hong; Li, Long-Yao Rare Metals, Vol. 41, Issue 7 https://doi.org/10.1007/s12598-021-01959-y	journal	March 2022
Stable and selective catalysts for propane dehydrogenation operating at thermodynamic limit Motagamwala, Ali Hussain; Almallahi, Rawan; Wortman, James Science, Vol. 373, Issue 6551 https://doi.org/10.1126/science.abg7894	journal	July 2021
Simultaneously upgrading CO ₂ and light alkanes into value‐added products Xie, Zhenhua; Gomez, Elaine; Chen, Jingguang G. AIChE Journal, Vol. 67, Issue 5 https://doi.org/10.1002/aic.17249	journal	March 2021
Breaking the scaling relationship via thermally stable Pt/Cu single atom alloys for catalytic dehydrogenation Sun, Guodong; Zhao, Zhi-Jian; Mu, Rentao Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06967-8	journal	October 2018
Catalytic Behavior of Chromium Oxide Supported on Nanocasting-Prepared Mesoporous Alumina in Dehydrogenation of Propane Węgrzyniak, Adam; Jarczewski, Sebastian; Węgrzynowicz, Adam Nanomaterials, Vol. 7, Issue 9 https://doi.org/10.3390/nano7090249	journal	September 2017
Dehydrogenation of propane marches on Yan, Wenfu; Sun, Qiming; Yu, Jihong Matter, Vol. 4, Issue 8 https://doi.org/10.1016/j.matt.2021.06.031	journal	August 2021
High-entropy intermetallics on ceria as efficient catalysts for the oxidative dehydrogenation of propane using CO2 Xing, Feilong; Ma, Jiamin; Shimizu, Ken-ichi Nature Communications, Vol. 13, Issue 1 https://doi.org/10.1038/s41467-022-32842-8	journal	August 2022
The effects of bimetallic interactions for CO ₂ ‐assisted oxidative dehydrogenation and dry reforming of propane Gomez, Elaine; Xie, Zhenhua; Chen, Jingguang G. AIChE Journal, Vol. 65, Issue 8 https://doi.org/10.1002/aic.16670	journal	June 2019
Cobalt on dealuminated-Siβ as a catalyst for the oxidative dehydrogenation of propane Dzwigaj, Stanislaw; Reja, Diane; Koné-Guira, Saremblé Applied Catalysis A: General, Vol. 657 https://doi.org/10.1016/j.apcata.2023.119119	journal	May 2023
Propane dehydrogenation: catalyst development, new chemistry, and emerging technologies Chen, Sai; Chang, Xin; Sun, Guodong Chemical Society Reviews, Vol. 50, Issue 5 https://doi.org/10.1039/D0CS00814A	journal	January 2021
Design Strategies of Stable Catalysts for Propane Dehydrogenation to Propylene Sun, Ming-Lei; Hu, Zhong-Pan; Wang, Hao-Yu ACS Catalysis, Vol. 13, Issue 7 https://doi.org/10.1021/acscatal.3c00103	journal	March 2023
Tandem In ₂ O ₃ -Pt/Al ₂ O ₃ catalyst for coupling of propane dehydrogenation to selective H ₂ combustion Yan, Huan; He, Kun; Samek, Izabela A. Science, Vol. 371, Issue 6535 https://doi.org/10.1126/science.abd4441	journal	March 2021
Understanding the Role of Fe Doping in Tuning the Size and Dispersion of GaN Nanocrystallites for CO₂-Assisted Oxidative Dehydrogenation of Propane Li, Long-Yao; Wang, Zhong-Yu; Yang, Shao-Yan ACS Catalysis, Vol. 12, Issue 14 https://doi.org/10.1021/acscatal.2c01989	journal	July 2022
Atomic layer deposition of Ga2O3 on γ-Al2O3 catalysts with higher interactions and improved activity and propylene selectivity in CO2-assisted oxidative dehydrogenation of propane Gashoul Daresibi, Fatemeh; Khodadadi, Abbas Ali; Mortazavi, Yadollah Applied Catalysis A: General, Vol. 655 https://doi.org/10.1016/j.apcata.2023.119117	journal	April 2023
Unraveling the Origins of the Synergy Effect between ZrO ₂ and CrO _x in Supported CrZrO _x for Propene Formation in Nonoxidative Propane Dehydrogenation Han, Shanlei; Zhao, Yun; Otroshchenko, Tatiana ACS Catalysis, Vol. 10, Issue 2 https://doi.org/10.1021/acscatal.9b05063	journal	December 2019
Lewis–Brønsted Acid Pairs in Ga/H-ZSM-5 To Catalyze Dehydrogenation of Light Alkanes Schreiber, Moritz W.; Plaisance, Craig P.; Baumgärtl, Martin Journal of the American Chemical Society, Vol. 140, Issue 14 https://doi.org/10.1021/jacs.7b12901	journal	February 2018
Carbon dioxide reduction in tandem with light-alkane dehydrogenation Gomez, Elaine; Yan, Binhang; Kattel, Shyam Nature Reviews Chemistry, Vol. 3, Issue 11 https://doi.org/10.1038/s41570-019-0128-9	journal	September 2019
Single-atom Pt in intermetallics as an ultrastable and selective catalyst for propane dehydrogenation Nakaya, Yuki; Hirayama, Jun; Yamazoe, Seiji Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-16693-9	journal	June 2020
Nature of active phase of VO catalysts supported on SiBeta for direct dehydrogenation of propane to propylene Chen, Chong; Sun, Minglei; Hu, Zhongpan Chinese Journal of Catalysis, Vol. 41, Issue 2 https://doi.org/10.1016/S1872-2067(19)63444-3	journal	February 2020
Facile synthesis of SiO2 supported GaN as an active catalyst for CO2 enhanced dehydrogenation of propane Zhang, Lin; Wang, Zhong-Yu; Song, Jian Journal of CO2 Utilization, Vol. 38 https://doi.org/10.1016/j.jcou.2020.02.010	journal	May 2020
Shale gas revolution: Catalytic conversion of C1–C3 light alkanes to value-added chemicals Li, Xinyu; Pei, Chunlei; Gong, Jinlong Chem, Vol. 7, Issue 7 https://doi.org/10.1016/j.chempr.2021.02.002	journal	July 2021
Defect-Dependent Selective C–H/C–C Bond Cleavage of Propane in the Presence of CO₂ over FeNi/Ceria Catalysts Wang, Yehong; Zhang, Zhixin; Lei, Lijun ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 51 https://doi.org/10.1021/acssuschemeng.1c06095	journal	December 2021
Propane Dehydrogenation on Single-Site [PtZn4] Intermetallic Catalysts Chen, Sai; Zhao, Zhi-Jian; Mu, Rentao Chem, Vol. 7, Issue 2 https://doi.org/10.1016/j.chempr.2020.10.008	journal	February 2021
The nature of VOx structures in HMS supported vanadium catalysts for non-oxidative propane dehydrogenation Li, Yuming; Yu, Xuezhi; Zhang, Qiyang Journal of Catalysis, Vol. 413 https://doi.org/10.1016/j.jcat.2022.07.017	journal	September 2022
Molecular-level investigation on supported CrOx catalyst for oxidative dehydrogenation of propane with carbon dioxide Wang, Jian; Zhu, Min-Li; Song, Yong-Hong Journal of Catalysis, Vol. 409 https://doi.org/10.1016/j.jcat.2022.03.027	journal	May 2022
The promotion effects of Ni on the properties of Cr/Al catalysts for propane dehydrogenation reaction Li, Pei-Pei; Lang, Wan-Zhong; Xia, Ke Applied Catalysis A: General, Vol. 522 https://doi.org/10.1016/j.apcata.2016.05.007	journal	July 2016
Facilitating the reduction of V–O bonds on VO _x /ZrO ₂ catalysts for non-oxidative propane dehydrogenation Xie, Yufei; Luo, Ran; Sun, Guodong Chemical Science, Vol. 11, Issue 15 https://doi.org/10.1039/D0SC00690D	journal	January 2020
Zinc Speciation and Propane Dehydrogenation in Zn/H-ZSM-5 Catalysts Yuan, Yong; Lobo, Raul F. ACS Catalysis, Vol. 13, Issue 7 https://doi.org/10.1021/acscatal.2c05898	journal	March 2023
Active and selective nature of supported CrOx for the oxidative dehydrogenation of propane with carbon dioxide Wang, Jian; Song, Yong-Hong; Liu, Zhao-Tie Applied Catalysis B: Environmental, Vol. 297 https://doi.org/10.1016/j.apcatb.2021.120400	journal	November 2021
Effect of CO2 on activity and coke formation over gallium-based catalysts for propane dehydrogenation Zhang, Yaoyuan; Aly, Mostafa Applied Catalysis A: General, Vol. 643 https://doi.org/10.1016/j.apcata.2022.118795	journal	August 2022
Effect of alumina polymorph on the dehydrogenation activity of supported chromia/alumina catalysts Nazimov, D. A.; Klimov, O. V.; Danilova, I. G. Journal of Catalysis, Vol. 391 https://doi.org/10.1016/j.jcat.2020.08.006	journal	November 2020
Isolated boron in zeolite for oxidative dehydrogenation of propane Zhou, Hang; Yi, Xianfeng; Hui, Yu Science, Vol. 372, Issue 6537 https://doi.org/10.1126/science.abe7935	journal	April 2021
Nanostructured Catalysts toward Efficient Propane Dehydrogenation Chen, Sai; Pei, Chunlei; Sun, Guodong Accounts of Materials Research, Vol. 1, Issue 1 https://doi.org/10.1021/accountsmr.0c00012	journal	September 2020
Finned Zn-MFI zeolite encapsulated noble metal nanoparticle catalysts for the oxidative dehydrogenation of propane with carbon dioxide Yuan, En-Hui; Niu, Yiming; Huang, Xing Journal of Energy Chemistry, Vol. 80 https://doi.org/10.1016/j.jechem.2023.01.055	journal	May 2023
Subsurface nickel boosts the low-temperature performance of a boron oxide overlayer in propane oxidative dehydrogenation Gao, Xiaofeng; Zhu, Ling; Yang, Feng Nature Communications, Vol. 14, Issue 1 https://doi.org/10.1038/s41467-023-37261-x	journal	March 2023
Oxidative Dehydrogenation of Propane to Propylene with Soft Oxidants via Heterogeneous Catalysis Jiang, Xiao; Sharma, Lohit; Fung, Victor ACS Catalysis, Vol. 11, Issue 4 https://doi.org/10.1021/acscatal.0c03999	journal	February 2021
Real-Time Quantitative Operando Raman Spectroscopy of a CrO _x /Al ₂ O ₃ Propane Dehydrogenation Catalyst in a Pilot-Scale Reactor Sattler, Jesper J. H. B.; Mens, Ad M.; Weckhuysen, Bert M. ChemCatChem, Vol. 6, Issue 11 https://doi.org/10.1002/cctc.201402649	journal	October 2014
Enhancing propane direct dehydrogenation performances through temperature induced VOx dispersion and alumina support phase transformation Shan, Yu-Ling; Sun, Huai-Lu; Zhao, Shi-Lei Chemical Engineering Journal, Vol. 450 https://doi.org/10.1016/j.cej.2022.137969	journal	December 2022
Combining CO2 reduction with propane oxidative dehydrogenation over bimetallic catalysts Gomez, Elaine; Kattel, Shyam; Yan, Binhang Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03793-w	journal	April 2018
Recent advances in carbon dioxide hydrogenation to produce olefins and aromatics Wang, Dong; Xie, Zhenhua; Porosoff, Marc D. Chem, Vol. 7, Issue 9 https://doi.org/10.1016/j.chempr.2021.02.024	journal	September 2021
Designing single-site alloy catalysts using a degree-of-isolation descriptor Chang, Xin; Zhao, Zhi-Jian; Lu, Zhenpu Nature Nanotechnology, Vol. 18, Issue 6 https://doi.org/10.1038/s41565-023-01344-z	journal	March 2023
Structural modulation and direct measurement of subnanometric bimetallic PtSn clusters confined in zeolites Liu, Lichen; Lopez-Haro, Miguel; Lopes, Christian W. Nature Catalysis, Vol. 3, Issue 8 https://doi.org/10.1038/s41929-020-0472-7	journal	June 2020
Structure and catalytic consequence of Mg‐modified VO_x/Al₂O₃ catalysts for propane dehydrogenation Wu, Tengfang; Liu, Gang; Zeng, Liang AIChE Journal, Vol. 63, Issue 11 https://doi.org/10.1002/aic.15836	journal	June 2017
Antiexfoliating h-BN⊃In₂O₃ Catalyst for Oxidative Dehydrogenation of Propane in a High-Temperature and Water-Rich Environment Cao, Lei; Yan, Pu; Wen, Sheng Journal of the American Chemical Society, Vol. 145, Issue 11 https://doi.org/10.1021/jacs.2c12136	journal	March 2023
Current status and perspectives in oxidative, non-oxidative and CO ₂ -mediated dehydrogenation of propane and isobutane over metal oxide catalysts Otroshchenko, Tatiana; Jiang, Guiyuan; Kondratenko, Vita A. Chemical Society Reviews, Vol. 50, Issue 1 https://doi.org/10.1039/D0CS01140A	journal	January 2021
Light olefin synthesis from a diversity of renewable and fossil feedstocks: state-of the-art and outlook Chernyak, Sergei A.; Corda, Massimo; Dath, Jean-Pierre Chemical Society Reviews, Vol. 51, Issue 18 https://doi.org/10.1039/D1CS01036K	journal	January 2022
CO2-mediated oxidative dehydrogenation of light alkanes to olefins: Advances and perspectives in catalyst design and process improvement Gambo, Yahya; Adamu, Sagir; Tanimu, Gazali Applied Catalysis A: General, Vol. 623 https://doi.org/10.1016/j.apcata.2021.118273	journal	August 2021
Descriptor-based identification of bimetallic-derived catalysts for selective activation of ethane with CO₂ Guo, Haoyue; Xie, Zhenhua; Wang, Xuelong EES Catalysis, Vol. 1, Issue 1 https://doi.org/10.1039/D2EY00051B	journal	January 2023
Roles of V−O sites for non-oxidative propane dehydrogenation over supported vanadium oxides Wang, Yang; Chen, Sai; Sun, Jiachen Science China Materials, Vol. 66, Issue 3 https://doi.org/10.1007/s40843-022-2214-8	journal	November 2022
Support effect in dehydrogenation of propane in the presence of CO2 over supported gallium oxide catalysts Xu, B.; Zheng, B.; Hua, W. Journal of Catalysis, Vol. 239, Issue 2 https://doi.org/10.1016/j.jcat.2006.02.017	journal	April 2006
CO2 hydrogenation to high-value products via heterogeneous catalysis Ye, Run-Ping; Ding, Jie; Gong, Weibo Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13638-9	journal	December 2019
Behavior of active sites on Cr-MCM-41 catalysts during the dehydrogenation of propane with CO2 Takehira, Katsuomi; Ohishi, Yoshihiko; Shishido, Tetsuya Journal of Catalysis, Vol. 224, Issue 2 https://doi.org/10.1016/j.jcat.2004.03.014	journal	June 2004
Tailoring Single‐Atom Platinum for Selective and Stable Catalysts in Propane Dehydrogenation Nakaya, Yuki; Furukawa, Shinya ChemPlusChem, Vol. 87, Issue 4 https://doi.org/10.1002/cplu.202100560	journal	February 2022
Single Co Sites in Ordered SiO₂ Channels for Boosting Nonoxidative Propane Dehydrogenation Wang, Wenyu; Wu, Yue; Liu, Tianyang ACS Catalysis, Vol. 12, Issue 4 https://doi.org/10.1021/acscatal.1c05921	journal	February 2022
ZrO 2 -based unconventional catalysts for non-oxidative propane dehydrogenation: Factors determining catalytic activity Otroshchenko, Tatyana; Kondratenko, Vita A.; Rodemerck, Uwe Journal of Catalysis, Vol. 348 https://doi.org/10.1016/j.jcat.2017.02.016	journal	April 2017
Ga ⁺ -Chabazite Zeolite: A Highly Selective Catalyst for Nonoxidative Propane Dehydrogenation Yuan, Yong; Lee, Jason S.; Lobo, Raul F. Journal of the American Chemical Society https://doi.org/10.1021/jacs.2c03941	journal	July 2022

Similar Records

Oxidative Dehydrogenation of Propane to Propylene with Soft Oxidants via Heterogeneous Catalysis

Journal Article · 2021 · ACS Catalysis · OSTI ID:1866713

Jiang, Xiao; Sharma, Lohit; Fung, Victor; +5 more

Combining CO₂ reduction with propane oxidative dehydrogenation over bimetallic catalysts

Journal Article · 2018 · Nature Communications · OSTI ID:1439297

Gomez, Elaine; Kattel, Shyam; Yan, Binhang; +3 more

CO₂-Assisted Oxidative Dehydrogenation of Propane over VO_x/In₂O₃ Catalysts: Interplay between Redox Property and Acid–Base Interactions

Journal Article · 2022 · ACS Catalysis · OSTI ID:1886495

Jiang, Xiao; Lis, Bar Mosevitzky; Purdy, Stephen C.; +10 more

Related Subjects

58 GEOSCIENCES
direct dehydrogenation of propane
CO2-oxidative dehydrogenation of propane
metal-based catalysts
metal oxide-based catalysts
net CO2 emissions

Title: Comparison of direct and CO2-oxidative dehydrogenation of propane

Citation Formats

References (95)

Similar Records

Related Subjects

Title: Comparison of direct and CO₂-oxidative dehydrogenation of propane