DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Electrochemical exsolution of metal nanoparticles from perovskite oxide upon electrolysis

Journal Article · · Applied Catalysis. B, Environmental

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
FG02–07ER15896; AC02–06CH11357
OSTI ID:
2263489
Journal Information:
Applied Catalysis. B, Environmental, Journal Name: Applied Catalysis. B, Environmental Vol. 344 Journal Issue: C; ISSN 0926-3373
Publisher:
ElsevierCopyright Statement
Country of Publication:
Netherlands
Language:
English

References (41)

Atomic‐Scale Insight into Exsolution of CoFe Alloy Nanoparticles in La 0.4 Sr 0.6 Co 0.2 Fe 0.7 Mo 0.1 O 3− δ with Efficient CO 2 Electrolysis journal June 2020
Effect of NiO/YSZ cathode support pore structure on CO2 electrolysis via solid oxide electrolysis cells journal December 2018
Isotopic Tracer Studies of Reaction Pathways for Propane Oxidative Dehydrogenation on Molybdenum Oxide Catalysts journal January 2001
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal June 2005
Perovskites as Substitutes of Noble Metals for Heterogeneous Catalysis: Dream or Reality journal September 2014
Pure CO2 electrolysis over an Ni/YSZ cathode in a solid oxide electrolysis cell journal January 2018
Cation-swapped homogeneous nanoparticles in perovskite oxides for high power density journal February 2019
Infiltrated mesoporous oxygen electrodes for high temperature co-electrolysis of H 2 O and CO 2 in solid oxide electrolysis cells journal January 2018
Electrical Resistivity of Nickel, Cobalt and Their Alloys journal January 1988
In-situ nano-alloying Pd-Ni for economical control of syngas production from high-temperature thermo-electrochemical reduction of steam/CO2 journal January 2017
Investigation of hetero-phases grown via in-situ exsolution on a Ni-doped (La,Sr)FeO3 cathode and the resultant activity enhancement in CO2 reduction journal June 2021
Understanding the occurrence of the individual CO2 electrolysis during H2O-CO2 co-electrolysis in classic planar Ni-YSZ/YSZ/LSM-YSZ solid oxide cells journal September 2019
In situ growth of nanoparticles through control of non-stoichiometry journal October 2013
Nanostructured Double Perovskite Cathode With Low Sintering Temperature For Intermediate Temperature Solid Oxide Fuel Cells journal July 2015
Production of synthesis gas (H2 and CO) by high-temperature Co-electrolysis of H2O and CO2 journal August 2015
Production of syngas with controllable H2/CO ratio by high temperature co-electrolysis of CO2 and H2O over Ni and Co- doped lanthanum strontium ferrite perovskite cathodes journal July 2019
GSAS-II : the genesis of a modern open-source all purpose crystallography software package journal March 2013
Anodic Shock-Triggered Exsolution of Metal Nanoparticles from Perovskite Oxide journal April 2022
Temperature-induced changes in the synthesis gas composition in a high-temperature H2O and CO2 co-electrolysis system journal July 2020
Validation of the Crystallography Open Database using the Crystallographic Information Framework journal February 2021
Nanoscale and nano-structured electrodes of solid oxide fuel cells by infiltration: Advances and challenges journal January 2012
Switching on electrocatalytic activity in solid oxide cells journal August 2016
A-site deficient perovskite: the parent for in situ exsolution of highly active, regenerable nano-particles as SOFC anodes journal January 2015
Understanding electrochemical switchability of perovskite-type exsolution catalysts journal September 2020
Enhancing Perovskite Electrocatalysis of Solid Oxide Cells Through Controlled Exsolution of Nanoparticles journal August 2017
In Situ Observation of Nanoparticle Exsolution from Perovskite Oxides: From Atomic Scale Mechanistic Insight to Nanostructure Tailoring journal October 2019
Incident-angle dependent operando XAS cell design: investigation of the electrochemical cells under operating conditions at various incidence angles journal January 2021
Effect of composition on the polarization and ohmic resistances of LSM/YSZ composite cathodes in solid oxide fuel cell journal June 2017
La0.8Sr0.2Co0.8Ni0.2O3-δ impregnated oxygen electrode for H2O/CO2 co-electrolysis in solid oxide electrolysis cells journal April 2018
Exsolved Nickel Nanoparticles Acting as Oxygen Storage Reservoirs and Active Sites for Redox CH 4 Conversion journal September 2019
Stable and selective perovskite catalyst for dehydrogenation of propane working with redox mechanism journal October 2013
High temperature solid oxide H2O/CO2 co-electrolysis for syngas production journal June 2017
A Highly Efficient Multi-phase Catalyst Dramatically Enhances the Rate of Oxygen Reduction journal May 2018
Growth Kinetics of Individual Co Particles Ex-solved on SrTi 0.75 Co 0.25 O 3-δ Polycrystalline Perovskite Thin Films journal April 2019
In-situ exsolution of bimetallic CoFe nanoparticles on (La,Sr)FeO3 perovskite: Its effect on electrocatalytic oxidative coupling of methane journal February 2023
A highly active, CO 2 -tolerant electrode for the oxygen reduction reaction journal January 2018
A nanostructured ceramic fuel electrode for efficient CO 2 /H 2 O electrolysis without safe gas journal January 2016
An all-oxide electrolysis cells for syngas production with tunable H2/CO yield via co-electrolysis of H2O and CO2 journal January 2021
An emerging platform for electrocatalysis: perovskite exsolution journal December 2016
Co-electrolysis of steam and CO 2 in full-ceramic symmetrical SOECs: a strategy for avoiding the use of hydrogen as a safe gas journal January 2015
Nano-socketed nickel particles with enhanced coking resistance grown in situ by redox exsolution journal September 2015