Iodide oxidation by ozone at the surface of aqueous microdroplets

Prophet, Alexander M.; Polley, Kritanjan; Van Berkel, Gary J.; Limmer, David T.; Wilson, Kevin R.

doi:10.1039/D3SC04254E

Title: Iodide oxidation by ozone at the surface of aqueous microdroplets

Journal Article · 02 January 2024 · Chemical Science

DOI: https://doi.org/10.1039/D3SC04254E · OSTI ID:2229948

Prophet, Alexander M. ^[1]; Polley, Kritanjan ^[1];

^[2]; Limmer, David T. ^[3];

^[4]

Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA, Department of Chemistry, University of California, Berkeley, CA 94720, USA
Van Berkel Ventures, LLC, Oak Ridge, TN 37830, USA
Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA, Department of Chemistry, University of California, Berkeley, CA 94720, USA, Materials Science Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA, Kavli Energy NanoScience Institute, Berkeley, California 94720, USA
Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA

The kinetics of iodide oxidation by ozone are studied in single microdroplets to explore chemical reactivity at the air–water interface. Molecular simulations and kinetic modeling are employed to understand the underlying multiphase mechanism.

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; AC02-05CH11231

OSTI ID:: 2229948

Alternate ID(s):: OSTI ID: 2345168

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 2 Vol. 15; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (97)

Surfactant Adsorption to Spherical Particles: the Intrinsic Length Scale Governing the Shift from Diffusion to Kinetic-Controlled mass Transfer Jin, Fang; Balasubramaniam, R.; Stebe, Kathleen J. The Journal of Adhesion, Vol. 80, Issue 9 https://doi.org/10.1080/00218460490480770	journal	September 2004
A revisit of the interaction of gaseous ozone with aqueous iodide. Estimating the contributions of the surface and bulk reactions Moreno, Carolina G.; Gálvez, Oscar; López-Arza Moreno, Vicente Physical Chemistry Chemical Physics, Vol. 20, Issue 43 https://doi.org/10.1039/C8CP04394A	journal	January 2018
Collisions of protic and aprotic gases with hydrogen bonding and hydrocarbon liquids Saecker, Mary E.; Nathanson, Gilbert M. The Journal of Chemical Physics, Vol. 99, Issue 9 https://doi.org/10.1063/1.465425	journal	November 1993
Spherical Monovalent Ions at Aqueous Liquid–Vapor Interfaces: Interfacial Stability and Induced Interface Fluctuations Ou, Shuching; Hu, Yuan; Patel, Sandeep The Journal of Physical Chemistry B, Vol. 117, Issue 39 https://doi.org/10.1021/jp406001b	journal	September 2013
“Breaking” and “Making” of Water Structure at the Air/Water−Electrolyte (NaXO₃; X = Cl, Br, I) Interface Roy, Subhadip; Mondal, Jahur Alam The Journal of Physical Chemistry Letters, Vol. 12, Issue 7 https://doi.org/10.1021/acs.jpclett.0c03827	journal	February 2021
The heterogeneous reaction of hydroxyl radicals with sub-micron squalane particles: a model system for understanding the oxidative aging of ambient aerosols Smith, J. D.; Kroll, J. H.; Cappa, C. D. Atmospheric Chemistry and Physics, Vol. 9, Issue 9 https://doi.org/10.5194/acp-9-3209-2009	journal	January 2009
Specific Anion Effects on Na ⁺ Adsorption at the Aqueous Solution–Air Interface: MD Simulations, SESSA Calculations, and Photoelectron Spectroscopy Experiments Olivieri, Giorgia; Parry, Krista M.; D’Auria, Raffaella The Journal of Physical Chemistry B, Vol. 122, Issue 2 https://doi.org/10.1021/acs.jpcb.7b06981	journal	November 2017
Reactive Uptake of Cl2(g) and Br2(g) by Aqueous Surfaces as a Function of Br- and I- Ion Concentration: The Effect of Chemical Reaction at the Interface Hu, J. H.; Shi, Q.; Davidovits, P. The Journal of Physical Chemistry, Vol. 99, Issue 21 https://doi.org/10.1021/j100021a050	journal	May 1995
Direct field evidence of autocatalytic iodine release from atmospheric aerosol Tham, Yee Jun; He, Xu-Cheng; Li, Qinyi Proceedings of the National Academy of Sciences, Vol. 118, Issue 4 https://doi.org/10.1073/PNAS.2009951118	journal	January 2021
Molecular Dynamics Simulations of Atmospheric Oxidants at the Air−Water Interface: Solvation and Accommodation of OH and O₃ Vieceli, John; Roeselová, Martina; Potter, Nicholas The Journal of Physical Chemistry B, Vol. 109, Issue 33 https://doi.org/10.1021/jp051361+	journal	August 2005
Adsorption of Atmospherically Relevant Gases at the Air/Water Interface: Free Energy Profiles of Aqueous Solvation of N 2 , O 2 , O 3 , OH, H 2 O, HO 2 , and H 2 O 2 Vácha, Robert; Slavíček, Petr; Mucha, Martin The Journal of Physical Chemistry A, Vol. 108, Issue 52 https://doi.org/10.1021/jp046268k	journal	December 2004
The Formation of Hypoiodous Acid and Hydrated Iodine Cation by the Hydrolysis of Iodine Allen, T. L.; Keefer, R. M. Journal of the American Chemical Society, Vol. 77, Issue 11 https://doi.org/10.1021/ja01616a008	journal	June 1955
Triiodide ion formation equilibrium and activity coefficients in aqueous solution Palmer, Donald A.; Ramette, R. W.; Mesmer, R. E. Journal of Solution Chemistry, Vol. 13, Issue 9 https://doi.org/10.1007/BF00650374	journal	September 1984
Compilation of Henry's law constants (version 4.0) for water as solvent Sander, R. Atmospheric Chemistry and Physics, Vol. 15, Issue 8 https://doi.org/10.5194/acp-15-4399-2015	journal	January 2015
Exploring Chemistry in Microcompartments Using Guided Droplet Collisions in a Branched Quadrupole Trap Coupled to a Single Droplet, Paper Spray Mass Spectrometer Jacobs, Michael I.; Davies, James F.; Lee, Lance Analytical Chemistry, Vol. 89, Issue 22 https://doi.org/10.1021/acs.analchem.7b03704	journal	October 2017
Uptake of Ozone to Deliquesced KI and Mixed KI/NaCl Aerosol Particles Rouvière, Aurélie; Sosedova, Yulia; Ammann, Markus The Journal of Physical Chemistry A, Vol. 114, Issue 26 https://doi.org/10.1021/JP103257D	journal	June 2010
Computational Study of Ion Binding to the Liquid Interface of Water ^† Dang, Liem X. The Journal of Physical Chemistry B, Vol. 106, Issue 40 https://doi.org/10.1021/jp021871t	journal	October 2002
Low ozone in the marine boundary layer of the tropical Pacific Ocean: Photochemical loss, chlorine atoms, and entrainment Singh, H. B.; Gregory, G. L.; Anderson, B. Journal of Geophysical Research: Atmospheres, Vol. 101, Issue D1 https://doi.org/10.1029/95JD01028	journal	January 1996
Iodine chemistry in the +1 oxidation state. II. A Raman and uv–visible spectroscopic study of the disproportionation of hypoiodite in basic solutions Wren, J. C.; Paquette, J.; Sunder, S. Canadian Journal of Chemistry, Vol. 64, Issue 12 https://doi.org/10.1139/v86-375	journal	December 1986
Atmosphere‐ocean ozone exchange: A global modeling study of biogeochemical, atmospheric, and waterside turbulence dependencies Ganzeveld, L.; Helmig, D.; Fairall, C. W. Global Biogeochemical Cycles, Vol. 23, Issue 4 https://doi.org/10.1029/2008GB003301	journal	November 2009
Transmission geometry laser ablation into a non-contact liquid vortex capture probe for mass spectrometry imaging Ovchinnikova, Olga S.; Bhandari, Deepak; Lorenz, Matthias Rapid Communications in Mass Spectrometry, Vol. 28, Issue 15, p. 1665-1673 https://doi.org/10.1002/rcm.6946	journal	June 2014
Photoemission of Iodide from Aqueous Aerosol Particle Surfaces Woods, Ephraim; Konys, Casey A.; Rossi, Sean R. The Journal of Physical Chemistry A, Vol. 123, Issue 13 https://doi.org/10.1021/acs.jpca.8b12323	journal	March 2019
Photoemission from Aqueous Alkali-Metal−Iodide Salt Solutions Using EUV Synchrotron Radiation Weber, R.; Winter, B.; Schmidt, P. M. The Journal of Physical Chemistry B, Vol. 108, Issue 15 https://doi.org/10.1021/jp030776x	journal	April 2004
Quantitative electronic structure and work-function changes of liquid water induced by solute Credidio, Bruno; Pugini, Michele; Malerz, Sebastian Physical Chemistry Chemical Physics, Vol. 24, Issue 3 https://doi.org/10.1039/D1CP03165A	journal	January 2022
Connecting the Elementary Reaction Pathways of Criegee Intermediates to the Chemical Erosion of Squalene Interfaces during Ozonolysis Heine, Nadja; Houle, Frances A.; Wilson, Kevin R. Environmental Science & Technology, Vol. 51, Issue 23 https://doi.org/10.1021/acs.est.7b04197	journal	November 2017
A kinetic description of how interfaces accelerate reactions in micro-compartments Wilson, Kevin R.; Prophet, Alexander M.; Rovelli, Grazia Chemical Science, Vol. 11, Issue 32 https://doi.org/10.1039/D0SC03189E	journal	January 2020
Volatility of iodine in dilute aqueous solutions Lin, Chien-Chang Journal of Inorganic and Nuclear Chemistry, Vol. 43, Issue 12 https://doi.org/10.1016/0022-1902(81)80094-2	journal	January 1981
On the hydrolysis of iodine in alkaline solution: A radiation chemical study Buxton, George V.; Mulazzani, Quinto G. Radiation Physics and Chemistry, Vol. 76, Issue 6 https://doi.org/10.1016/j.radphyschem.2006.06.009	journal	June 2007
Probing the Interfacial Structure of Aqueous Electrolytes with Femtosecond Second Harmonic Generation Spectroscopy Petersen, Poul B.; Saykally, Richard J. The Journal of Physical Chemistry B, Vol. 110, Issue 29 https://doi.org/10.1021/jp0601825	journal	July 2006
Glancing-angle Raman spectroscopic probe for reaction kinetics at water surfaces Wren, Sumi N.; Donaldson, D. J. Physical Chemistry Chemical Physics, Vol. 12, Issue 11 https://doi.org/10.1039/B922254E	journal	January 2010
Kinetics of Proton-transfer Reactions Barker, G. C.; Sammon, D. C. Nature, Vol. 213, Issue 5071 https://doi.org/10.1038/213065b0	journal	January 1967
A Kinetic Model for Predicting Trace Gas Uptake and Reaction Wilson, Kevin R.; Prophet, Alexander M.; Willis, Megan D. The Journal of Physical Chemistry A, Vol. 126, Issue 40 https://doi.org/10.1021/acs.jpca.2c03559	journal	September 2022
A polarizable model of water for molecular dynamics simulations of biomolecules Lamoureux, Guillaume; Harder, Edward; Vorobyov, Igor V. Chemical Physics Letters, Vol. 418, Issue 1-3 https://doi.org/10.1016/j.cplett.2005.10.135	journal	January 2006
Coupled Interfacial and Bulk Kinetics Govern the Timescales of Multiphase Ozonolysis Reactions Willis, Megan D.; Wilson, Kevin R. The Journal of Physical Chemistry A, Vol. 126, Issue 30 https://doi.org/10.1021/acs.jpca.2c03059	journal	July 2022
Atmospheric chemistry of iodine anions: elementary reactions of I ⁻ , IO ⁻ , and IO ₂ ⁻ with ozone studied in the gas-phase at 300 K using an ion trap Teiwes, Ricky; Elm, Jonas; Handrup, Karsten Physical Chemistry Chemical Physics, Vol. 20, Issue 45 https://doi.org/10.1039/C8CP05721D	journal	January 2018
Oxidation of Iodide and Hypoiodous Acid in the Disinfection of Natural Waters Bichsel, Yves; von Gunten, Urs Environmental Science & Technology, Vol. 33, Issue 22 https://doi.org/10.1021/es990336c	journal	September 1999
Iodine in the Marine Boundary Layer Carpenter, Lucy J. Chemical Reviews, Vol. 103, Issue 12 https://doi.org/10.1021/cr0206465	journal	December 2003
Direct Emission of I ₂ Molecule and IO Radical from the Heterogeneous Reactions of Gaseous Ozone with Aqueous Potassium Iodide Solution Sakamoto, Yosuke; Yabushita, Akihiro; Kawasaki, Masahiro The Journal of Physical Chemistry A, Vol. 113, Issue 27 https://doi.org/10.1021/jp903486u	journal	June 2009
Untersuchungen über die Kinetik der Neutralisation. I Eigen, M.; De Maeyer, L. Zeitschrift für Elektrochemie, Berichte der Bunsengesellschaft für physikalische Chemie, Vol. 59, Issue 10 https://doi.org/10.1002/bbpc.19550591020	journal	December 1955
Immediate drop on demand technology (I-DOT) coupled with mass spectrometry via an open port sampling interface Van Berkel, Gary J.; Kertesz, Vilmos; Boeltz, Harry Bioanalysis, Vol. 9, Issue 21 https://doi.org/10.4155/bio-2017-0104	journal	November 2017
Is the Free Energy Change of Adsorption Correctly Calculated? Liu, Yu Journal of Chemical & Engineering Data, Vol. 54, Issue 7 https://doi.org/10.1021/je800661q	journal	July 2009
Kinetics and Mechanisms of Aqueous Ozone Reactions with Bromide, Sulfite, Hydrogen Sulfite, Iodide, and Nitrite Ions Liu, Qian; Schurter, Lynn M.; Muller, Charles E. Inorganic Chemistry, Vol. 40, Issue 17 https://doi.org/10.1021/ic000919j	journal	July 2001
Dynamics and Kinetics at the Gas−Liquid Interface Nathanson, Gilbert M.; Davidovits, Paul; Worsnop, Douglas R. The Journal of Physical Chemistry, Vol. 100, Issue 31 https://doi.org/10.1021/jp953548e	journal	January 1996
Measurements of ozone concentrations on a commercial vessel in the marine boundary layer over the northern North Pacific Ocean Watanabe, Koichi; Nojiri, Yukihiro; Kariya, Shigeru Journal of Geophysical Research: Atmospheres, Vol. 110, Issue D11 https://doi.org/10.1029/2004JD005514	journal	June 2005
An Open Port Sampling Interface for the Chemical Characterization of Levitated Microparticles Kaur Kohli, Ravleen; Van Berkel, Gary J.; Davies, James F. Analytical Chemistry, Vol. 94, Issue 8 https://doi.org/10.1021/acs.analchem.1c05550	journal	February 2022
Ozone solubility in concentrated aqueous solutions of salts Panich, N. M.; Ershov, B. G.; Seliverstov, A. F. Russian Journal of Applied Chemistry, Vol. 80, Issue 11 https://doi.org/10.1134/S1070427207110067	journal	November 2007
Extreme surface propensity of halide ions in water Piatkowski, Lukasz; Zhang, Zhen; Backus, Ellen H. G. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5083	journal	June 2014
An open port sampling interface for liquid introduction atmospheric pressure ionization mass spectrometry: Open port sampling interface Van Berkel, Gary J.; Kertesz, Vilmos Rapid Communications in Mass Spectrometry, Vol. 29, Issue 19 https://doi.org/10.1002/rcm.7274	journal	August 2015
A chemical kinetic model for reactive transformations of aerosol particles: REACTIVE TRANSFORMATION OF AEROSOL PARTICLES Worsnop, D. R.; Morris, J. W.; Shi, Q. Geophysical Research Letters, Vol. 29, Issue 20 https://doi.org/10.1029/2002GL015542	journal	October 2002
Analytical description of gas transport across an interface with coupled diffusion in two phases Huthwelker, Thomas; Peter, Thomas The Journal of Chemical Physics, Vol. 105, Issue 4 https://doi.org/10.1063/1.472025	journal	July 1996
Theoretical consideration on sticking probabilities Clement, Charles F.; Kulmala, Markku; Vesala, Timo Journal of Aerosol Science, Vol. 27, Issue 6 https://doi.org/10.1016/0021-8502(96)00032-8	journal	September 1996
On the Speciation of Iodine in Marine Aerosol Gómez Martín, Juan Carlos; Saiz‐Lopez, Alfonso; Cuevas, Carlos A. Journal of Geophysical Research: Atmospheres, Vol. 127, Issue 4 https://doi.org/10.1029/2021JD036081	journal	February 2022
The distribution of iodide at the sea surface Chance, Rosie; Baker, Alex R.; Carpenter, Lucy Environ. Sci.: Processes Impacts, Vol. 16, Issue 8 https://doi.org/10.1039/C4EM00139G	journal	January 2014
Acidity across the interface from the ocean surface to sea spray aerosol Angle, Kyle J.; Crocker, Daniel R.; Simpson, Rebecca M. C. Proceedings of the National Academy of Sciences, Vol. 118, Issue 2 https://doi.org/10.1073/pnas.2018397118	journal	December 2020
Rate constants of reactions of ozone with organic and inorganic compounds in water—III. Inorganic compounds and radicals Hoigné, J.; Bader, H.; Haag, W. R. Water Research, Vol. 19, Issue 8 https://doi.org/10.1016/0043-1354(85)90368-9	journal	January 1985
Insights into the Chemistry of Iodine New Particle Formation: The Role of Iodine Oxides and the Source of Iodic Acid Gómez Martín, Juan Carlos; Lewis, Thomas R.; James, Alexander D. Journal of the American Chemical Society, Vol. 144, Issue 21 https://doi.org/10.1021/jacs.1c12957	journal	May 2022
Marine iodine emissions in a changing world Carpenter, Lucy J.; Chance, Rosie J.; Sherwen, Tomás Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 477, Issue 2247 https://doi.org/10.1098/RSPA.2020.0824	journal	March 2021
Chemical Fractionation at the Air/Sea Interface Duce, R. A.; Hoffman, E. J. Annual Review of Earth and Planetary Sciences, Vol. 4, Issue 1 https://doi.org/10.1146/annurev.ea.04.050176.001155	journal	May 1976
A surface-stabilized ozonide triggers bromide oxidation at the aqueous solution-vapour interface Artiglia, Luca; Edebeli, Jacinta; Orlando, Fabrizio Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00823-x	journal	September 2017
Ions at the Air/Water Interface Jungwirth, Pavel; Tobias, Douglas J. The Journal of Physical Chemistry B, Vol. 106, Issue 25 https://doi.org/10.1021/jp020242g	journal	June 2002
Gas phase reactions of iodide and bromide anions with ozone: evidence for stepwise and reversible reactions Bhujel, Mahendra; Marshall, David L.; Maccarone, Alan T. Physical Chemistry Chemical Physics, Vol. 22, Issue 18 https://doi.org/10.1039/D0CP01498B	journal	January 2020
Kinetics and mechanism of the hydrolytic disproportionation of iodine Sebők‐Nagy, Krisztina; Körtvélyesi, Tamás International Journal of Chemical Kinetics, Vol. 36, Issue 11 https://doi.org/10.1002/kin.20033	journal	August 2004
Iodine speciation in rain, snow and aerosols Gilfedder, B. S.; Lai, S. C.; Petri, M. Atmospheric Chemistry and Physics, Vol. 8, Issue 20 https://doi.org/10.5194/acp-8-6069-2008	journal	October 2008
Diffusive confinement of free radical intermediates in the OH radical oxidation of semisolid aerosols Wiegel, Aaron A.; Liu, Matthew J.; Hinsberg, William D. Physical Chemistry Chemical Physics, Vol. 19, Issue 9 https://doi.org/10.1039/C7CP00696A	journal	January 2017
Atmospheric iodine levels influenced by sea surface emissions of inorganic iodine Carpenter, Lucy J.; MacDonald, Samantha M.; Shaw, Marvin D. Nature Geoscience, Vol. 6, Issue 2 https://doi.org/10.1038/ngeo1687	journal	January 2013
Atmospheric Chemistry of Iodine Saiz-Lopez, Alfonso; Plane, John M. C.; Baker, Alex R. Chemical Reviews, Vol. 112, Issue 3 https://doi.org/10.1021/cr200029u	journal	October 2011
The reaction of hydrated iodide I(H₂O)⁻ with ozone: a new route to IO₂⁻ products Teiwes, Ricky; Elm, Jonas; Bilde, Merete Physical Chemistry Chemical Physics, Vol. 21, Issue 32 https://doi.org/10.1039/C9CP01734H	journal	January 2019
Iodine emission from the reactive uptake of ozone to simulated seawater Schneider, Stephanie R.; Lakey, Pascale S. J.; Shiraiwa, Manabu Environmental Science: Processes & Impacts, Vol. 25, Issue 2 https://doi.org/10.1039/D2EM00111J	journal	January 2023
A theoretical study on the reaction of ozone with aqueous iodide Gálvez, Óscar; Teresa Baeza-Romero, M.; Sanz, Mikel Physical Chemistry Chemical Physics, Vol. 18, Issue 11 https://doi.org/10.1039/C5CP06440F	journal	January 2016
Thermodynamics of iodide adsorption at the instantaneous air-water interface Stern, Abraham C.; Baer, Marcel D.; Mundy, Christopher J. The Journal of Chemical Physics, Vol. 138, Issue 11 https://doi.org/10.1063/1.4794688	journal	March 2013
Reactive Uptake of Ozone to Simulated Seawater: Evidence for Iodide Depletion Schneider, Stephanie R.; Lakey, Pascale S. J.; Shiraiwa, Manabu The Journal of Physical Chemistry A, Vol. 124, Issue 47 https://doi.org/10.1021/acs.jpca.0c08917	journal	November 2020
Rapid, Untargeted Chemical Profiling of Single Cells in Their Native Environment Cahill, John F.; Riba, Julian; Kertesz, Vilmos Analytical Chemistry, Vol. 91, Issue 9 https://doi.org/10.1021/acs.analchem.9b00680	journal	April 2019
Exploring the influence of particle phase in the ozonolysis of oleic and elaidic acid Kaur Kohli, Ravleen; Reynolds, Ryan S.; Wilson, Kevin R. Aerosol Science and Technology https://doi.org/10.1080/02786826.2023.2226183	journal	June 2023
Influence of water surface properties on the heterogeneous reaction between O3(g) and I(aq)− Reeser, Dorea I.; Donaldson, D. J. Atmospheric Environment, Vol. 45, Issue 34 https://doi.org/10.1016/J.ATMOSENV.2011.08.042	journal	November 2011
Mass-transport limitation to the rate of reaction of gases in liquid droplets: Application to oxidation of SO2 in aqueous solutions Schwartz, S. E.; Freiberg, J. E. Atmospheric Environment (1967), Vol. 15, Issue 7 https://doi.org/10.1016/0004-6981(81)90303-6	journal	January 1981
Direct experimental validation of the Jones–Ray effect Petersen, Poul B.; Johnson, Justin C.; Knutsen, Kelly P. Chemical Physics Letters, Vol. 397, Issue 1-3 https://doi.org/10.1016/j.cplett.2004.08.048	journal	October 2004
Mass, charge, and radius of droplets in a linear quadrupole electrodynamic balance Davies, James F. Aerosol Science and Technology, Vol. 53, Issue 3 https://doi.org/10.1080/02786826.2018.1559921	journal	January 2019
The mechanism for dry deposition of ozone to seawater surfaces Garland, J. A.; Elzerman, A. W.; Penkett, S. A. Journal of Geophysical Research: Oceans, Vol. 85, Issue C12 https://doi.org/10.1029/JC085IC12P07488	journal	December 1980
Relation between Surface Tension and Ion Adsorption at the Air−Water Interface: A Molecular Dynamics Simulation Study D’Auria, Raffaella; Tobias, Douglas J. The Journal of Physical Chemistry A, Vol. 113, Issue 26 https://doi.org/10.1021/jp810488p	journal	May 2009
Fluid Dynamics of the Open Port Interface for High-Speed Nanoliter Volume Sampling Mass Spectrometry Liu, Chang; Van Berkel, Gary J.; Kovarik, Peter Analytical Chemistry, Vol. 93, Issue 24 https://doi.org/10.1021/acs.analchem.1c01312	journal	June 2021
The Adsorption of Gases on Plane Surfaces of Glass, mica and Platinum. Langmuir, Irving Journal of the American Chemical Society, Vol. 40, Issue 9 https://doi.org/10.1021/ja02242a004	journal	September 1918
Ozone in the remote marine boundary layer: A possible role for halogens Dickerson, Russell R.; Rhoads, Kevin P.; Carsey, Thomas P. Journal of Geophysical Research: Atmospheres, Vol. 104, Issue D17 https://doi.org/10.1029/1999JD900023	journal	September 1999
Polyatomic Iodine Species at the Air–Water Interface and Its Relevance to Atmospheric Iodine Chemistry: An HD-VSFG and Raman-MCR Study Saha, Subhamoy; Roy, Subhadip; Mathi, P. The Journal of Physical Chemistry A, Vol. 123, Issue 13 https://doi.org/10.1021/acs.jpca.9b00828	journal	March 2019
A gas-to-particle conversion mechanism helps to explain atmospheric particle formation through clustering of iodine oxides Gómez Martín, Juan Carlos; Lewis, Thomas R.; Blitz, Mark A. Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-18252-8	journal	September 2020
Kinetics of Hypoiodite Decomposition¹ Li, Choh Hao; White, Carolyn F. Journal of the American Chemical Society, Vol. 65, Issue 3 https://doi.org/10.1021/ja01243a011	journal	March 1943
A laboratory study of iodine enrichment on atmospheric sea-salt particles produced by bubbles Seto, Fred Y. B.; Duce, Robert A. Journal of Geophysical Research, Vol. 77, Issue 27 https://doi.org/10.1029/JC077i027p05339	journal	September 1972
A kinetic model for ozone uptake by solutions and aqueous particles containing I⁻and Br⁻, including seawater and sea-salt aerosol Moreno, Carolina; Baeza-Romero, María Teresa Physical Chemistry Chemical Physics, Vol. 21, Issue 36 https://doi.org/10.1039/C9CP03430G	journal	January 2019
The reaction of isotope-substituted hydrated iodide I(H182O)⁻ with ozone: the reactive influence of the solvent water molecule Pedersen, Henrik B.; Elm, Jonas; Frederiksen, Christian H. Physical Chemistry Chemical Physics, Vol. 22, Issue 34 https://doi.org/10.1039/D0CP03219K	journal	January 2020
Photoelectron spectroscopy of liquid water and aqueous solution: Electron effective attenuation lengths and emission-angle anisotropy Ottosson, Niklas; Faubel, Manfred; Bradforth, Stephen E. Journal of Electron Spectroscopy and Related Phenomena, Vol. 177, Issue 2-3 https://doi.org/10.1016/j.elspec.2009.08.007	journal	March 2010
The Kinetics of Halogen Hydrolysis Eigen, Manfred.; Kustin, Kenneth. Journal of the American Chemical Society, Vol. 84, Issue 8 https://doi.org/10.1021/ja00867a005	journal	April 1962
Investigation of the Uptake Rate of Ozone and Methyl Hydroperoxide by Water Surfaces Magi, Laurent; Schweitzer, Francis; Pallares, Cyril The Journal of Physical Chemistry A, Vol. 101, Issue 27 https://doi.org/10.1021/jp970646m	journal	July 1997
Kinetics of iodine hydrolysis Lengyel, Istvan; Epstein, Irving R.; Kustin, Kenneth Inorganic Chemistry, Vol. 32, Issue 25 https://doi.org/10.1021/ic00077a036	journal	December 1993
Iodide conversion to iodate in aqueous and solid aerosols exposed to ozone Moreno, Carolina; Baeza-Romero, María-Teresa; Sanz, Mikel Physical Chemistry Chemical Physics, Vol. 22, Issue 10 https://doi.org/10.1039/C9CP05601G	journal	January 2020
Equilibrium Solubilities of Iodine Vapor in Water Sanemasa, Isao; Kobayashi, Toyohisa; Piao, Cheng Yun Bulletin of the Chemical Society of Japan, Vol. 57, Issue 5 https://doi.org/10.1246/bcsj.57.1352	journal	May 1984
The effect of fatty acid surfactants on the uptake of ozone to aqueous halogenide particles Rouvière, A.; Ammann, M. Atmospheric Chemistry and Physics, Vol. 10, Issue 23 https://doi.org/10.5194/acp-10-11489-2010	journal	December 2010
Ozone in the marine boundary layer over the Pacific and Indian Oceans: Latitudinal gradients and diurnal cycles Johnson, James E.; Gammon, Richard H.; Larsen, Jimmy Journal of Geophysical Research: Atmospheres, Vol. 95, Issue D8 https://doi.org/10.1029/JD095iD08p11847	journal	July 1990
Predicting Aerosol Reactivity Across Scales: from the Laboratory to the Atmosphere Houle, Frances A.; Wiegel, Aaron A.; Wilson, Kevin R. Environmental Science & Technology, Vol. 52, Issue 23 https://doi.org/10.1021/acs.est.8b04688	journal	November 2018

Similar Records

Negative ion photoelectron spectra of ISO₃^–, IS₂O₃^–, and IS₂O₄^– intermediates formed in interfacial reactions of ozone and iodide/sulfite aqueous microdroplets

Journal Article · 2016 · Journal of Chemical Physics · OSTI ID:1344655

Qin, Zhengbo; Hou, Gao-Lei; Yang, Zheng; +2 more

Distinguishing Surface and Bulk Reactivity: Concentration-Dependent Kinetics of Iodide Oxidation by Ozone in Microdroplets

Journal Article · 2024 · Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory · OSTI ID:2496256

Prophet, Alexander M.; Polley, Kritanjan; Brown, Emily K.; +2 more

Can electric fields drive chemistry for an aqueous microdroplet?

Journal Article · 2022 · Nature Communications · OSTI ID:1839486

Hao, Hongxia; Leven, Itai; Head-Gordon, Teresa

Title: Iodide oxidation by ozone at the surface of aqueous microdroplets

Citation Formats

References (97)

Similar Records

Related Subjects