Hydrogen spillover and substrate–support hydrogen bonding mediate hydrogenation of phenol catalyzed by palladium on reducible metal oxides

An, Yeongseo; Chatterjee, Puranjan; Naik, Pranjali; Banerjee, Sayak; Huang, Wenyu; Slowing, Igor I.; Venditti, Vincenzo

doi:10.1039/D3SC02913A

Title: Hydrogen spillover and substrate–support hydrogen bonding mediate hydrogenation of phenol catalyzed by palladium on reducible metal oxides

Journal Article · 12 December 2023 · Chemical Science

DOI: https://doi.org/10.1039/D3SC02913A · OSTI ID:2222840

An, Yeongseo ^[1]; Chatterjee, Puranjan ^[2];

^[2]; Banerjee, Sayak ^[1];

^[2]; Slowing, Igor I. ^[2];

^[3]

Department of Chemistry, Iowa State University, Hach Hall, 2438 Pammel Drive, Ames, Iowa 50011, USA
Department of Chemistry, Iowa State University, Hach Hall, 2438 Pammel Drive, Ames, Iowa 50011, USA, Department of Energy, Ames Laboratory, Ames, Iowa 50011, USA
Department of Chemistry, Iowa State University, Hach Hall, 2438 Pammel Drive, Ames, Iowa 50011, USA, Roy J. Carver Department of Biochemistry, Biophysics and Molecular Biology, Iowa State University, Ames, Iowa 50011, USA

Surface contrast solution NMR and reaction kinetic assays reveal an active role for H ₂ spillover in the phenol hydrogenation reaction catalyzed by Pd on reducible metal oxides.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; AC02-07CH11358

OSTI ID:: 2222840

Alternate ID(s):: OSTI ID: 2234280

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 48 Vol. 14; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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