Batch Scale Production of 3D Printed Extraction Sorbents Using a Low-Cost Modification to a Desktop Printer

Hsieh, Shu-An; Shamsaei, Danial; Ocaña-Rios, Iran; Anderson, Jared L.

doi:10.1021/acs.analchem.3c02679

Title: Batch Scale Production of 3D Printed Extraction Sorbents Using a Low-Cost Modification to a Desktop Printer

Journal Article · 30 August 2023 · Analytical Chemistry

DOI: https://doi.org/10.1021/acs.analchem.3c02679 · OSTI ID:2216916

Hsieh, Shu-An ^[1]; Shamsaei, Danial ^[2]; Ocaña-Rios, Iran ^[2];

^[1]

Ames Lab., and Iowa State Univ., Ames, IA (United States)
Iowa State Univ., Ames, IA (United States)

This study reports a simple modification to a commercial resin 3D printer that significantly reduces the amount of prepolymer material needed for the production of extraction sorbents. Here, the modified printing platform is demonstrated in the printing of two imidazolium-based ionic liquid (IL) monomers. Two geometries resembling a blade-type polymeric ionic liquid (PIL) sorbent used in thin-film microextraction and a fiber-type sorbent used in solid-phase microextraction (SPME) were printed. The SPME PIL sorbents were used to extract 10 organic contaminants, including plasticizers, antimicrobial agents, UV filters, and pesticides, from water followed by high-performance liquid chromatographic (HPLC) analysis. To compare the extraction performance of the SPME sorbents, seven fibers printed with the same prepolymer composition from the same printing batch as well as different batches were evaluated. The results revealed highly reproducible extraction efficiencies for all tested sorbents with no statistical difference in their extraction performance. Method validation showed acceptable linearity ($$R$$² > 0.92) for all analytes with limits of detection and limits of quantification ranging from 0.13 to 45 μg L^–1 and 0.43 to 150 μg L^–1, respectively.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: National Science Foundation; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 2216916

Report Number(s):: IS-J--11145

Journal Information:: Analytical Chemistry, Journal Name: Analytical Chemistry Journal Issue: 36 Vol. 95; ISSN 0003-2700

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
3D printing
extraction
fibers
materials
sorbents

Title: Batch Scale Production of 3D Printed Extraction Sorbents Using a Low-Cost Modification to a Desktop Printer

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