Penetrant shape effects on activated dynamics and selectivity in polymer melts and networks based on self-consistent cooperative hopping theory

Mei, Baicheng; Schweizer, Kenneth S.

doi:10.1039/D3SM01139A

Title: Penetrant shape effects on activated dynamics and selectivity in polymer melts and networks based on self-consistent cooperative hopping theory

Journal Article · 22 November 2023 · Soft Matter

DOI: https://doi.org/10.1039/D3SM01139A · OSTI ID:2205122

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Department of Materials Science, University of Illinois, Urbana, IL 61801, USA, Materials Research Laboratory, University of Illinois, Urbana, IL 61801, USA
Department of Materials Science, University of Illinois, Urbana, IL 61801, USA, Department of Chemistry, University of Illinois, Urbana, IL 61801, USA, Department of Chemical and Biomolecular Engineering, University of Illinois, Urbana, IL 61801, USA, Materials Research Laboratory, University of Illinois, Urbana, IL 61801, USA

We generalize and apply the microscopic self-consistent cooperative hopping theory for activated penetrant dynamics in polymer melts and crosslinked networks to address the role of highly variable non-spherical molecular shape.

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Sponsoring Organization:: USDOE

OSTI ID:: 2205122

Journal Information:: Soft Matter, Journal Name: Soft Matter Vol. 19 Journal Issue: 45; ISSN 1744-683X

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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