DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Interfacial doping of semiconducting polymers with phenothiazine-based polymeric ionic liquids

Journal Article · · Journal of Materials Chemistry C
DOI: https://doi.org/10.1039/D3TC03176D · OSTI ID:2204769
ORCiD logo [1]; ORCiD logo [2];  [1];  [2];  [1]; ORCiD logo [3]; ORCiD logo [1];  [2];  [4];  [1]; ORCiD logo [5]
  1. Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA, 93106-5050, USA
  2. Department of Chemical Engineering, University of California, Santa Barbara, CA, 93106-5050, USA
  3. Mitsubishi Center for Advanced Materials, University of California, Santa Barbara, CA, 93106-5050, USA
  4. Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA, 93106-5050, USA, Department of Chemical Engineering, University of California, Santa Barbara, CA, 93106-5050, USA
  5. Materials Department, University of California, Santa Barbara, California 93106, USA

Interfacial doping of conjugated polymers is enabled by sequentially casting phenothiazine-based redox-active polymeric ionic liquids with TFSI counterions.

Sponsoring Organization:
USDOE
OSTI ID:
2204769
Journal Information:
Journal of Materials Chemistry C, Journal Name: Journal of Materials Chemistry C Vol. 11 Journal Issue: 44; ISSN 2050-7526
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (50)

Efficient molecular doping of polymeric semiconductors driven by anion exchange journal August 2019
Phenothiazine Derivatives: Mono-oxygenated Compounds journal November 1949
Photocrosslinking polymeric ionic liquids via anthracene cycloaddition for organic electronics journal January 2018
Sequential Processing for Organic Photovoltaics: Design Rules for Morphology Control by Tailored Semi-Orthogonal Solvent Blends journal March 2015
A fast, inexpensive method for predicting overcharge performance in lithium-ion batteries journal January 2014
Thermoelectric Properties of Poly(3-hexylthiophene) (P3HT) Doped with 2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F 4 TCNQ) by Vapor-Phase Infiltration journal January 2018
Double Doping of a Low-Ionization-Energy Polythiophene with a Molybdenum Dithiolene Complex journal June 2022
Contact Doping with Sub-Monolayers of Strong Polyelectrolytes for Organic Photovoltaics journal May 2014
Tuning of the elastic modulus of a soft polythiophene through molecular doping journal January 2022
Diffusion of Brønsted acidic dopants in conjugated polymers journal January 2023
Chemical Doping of Conjugated Polymers with the Strong Oxidant Magic Blue journal July 2020
Enhanced Electrical Conductivity of Molecularly p-Doped Poly(3-hexylthiophene) through Understanding the Correlation with Solid-State Order journal October 2017
Quantitative Analysis of Doping-Induced Polarons and Charge-Transfer Complexes of Poly(3-hexylthiophene) in Solution journal June 2020
Controlling Molecular Doping in Organic Semiconductors journal September 2017
Branched Side Chains Govern Counterion Position and Doping Mechanism in Conjugated Polythiophenes journal November 2018
Redox-Active Polymeric Ionic Liquids with Pendant N-Substituted Phenothiazine journal January 2021
Solution-based electrical doping of semiconducting polymer films over a limited depth journal December 2016
Tailoring Two-Electron-Donating Phenothiazines To Enable High-Concentration Redox Electrolytes for Use in Nonaqueous Redox Flow Batteries journal May 2019
Lewis acid–base pair doping of p-type organic semiconductors journal January 2022
Phenothiazine derivatives for efficient organic dye-sensitized solar cells journal January 2007
Charge storage on a conducting polymer in solution journal July 1989
Mutual electrical doping in polymers journal March 2020
Redox Active Polymers as Soluble Nanomaterials for Energy Storage journal September 2016
25th Anniversary Article: Organic Field-Effect Transistors: The Path Beyond Amorphous Silicon journal January 2014
Ground-state electron transfer in all-polymer donor–acceptor heterojunctions journal March 2020
Comparison of solution-mixed and sequentially processed P3HT:F4TCNQ films: effect of doping-induced aggregation on film morphology journal January 2016
Effects of Counter‐Ion Size on Delocalization of Carriers and Stability of Doped Semiconducting Polymers journal October 2020
Impact of the Doping Method on Conductivity and Thermopower in Semiconducting Polythiophenes journal October 2014
The Role of Ordering on the Thermoelectric Properties of Blends of Regioregular and Regiorandom Poly(3‐hexylthiophene) journal April 2019
Interface Doping for Ohmic Organic Semiconductor Contacts Using Self‐Aligned Polyelectrolyte Counterion Monolayer journal March 2017
High current density, long duration cycling of soluble organic active species for non-aqueous redox flow batteries journal January 2016
A stable two-electron-donating phenothiazine for application in nonaqueous redox flow batteries journal January 2017
Double doping of conjugated polymers with monomer molecular dopants journal January 2019
Some Derivatives of Phenothiazine journal June 1944
A search for blues brothers: X-ray crystallographic/spectroscopic characterization of the tetraarylbenzidine cation radical as a product of aging of solid magic blue journal January 2016
HOMO–HOMO Electron Transfer: An Elegant Strategy for p‐Type Doping of Polymer Semiconductors toward Thermoelectric Applications journal September 2020
Flexible organic electronic devices: Materials, process and applications journal August 2008
Inner-sphere electron transfer in organic chemistry. Relevance to electrophilic aromatic nitration journal January 1992
Surface Doping of Organic Single‐Crystal Semiconductors to Produce Strain‐Sensitive Conductive Nanosheets journal December 2020
2D coherent charge transport in highly ordered conducting polymers doped by solid state diffusion journal May 2016
Overcoming Film Quality Issues for Conjugated Polymers Doped with F 4 TCNQ by Solution Sequential Processing: Hall Effect, Structural, and Optical Measurements journal November 2015
N -Substituted Phenothiazine Derivatives: How the Stability of the Neutral and Radical Cation Forms Affects Overcharge Performance in Lithium-Ion Batteries journal December 2014
The impact of aggregation on the p-doping kinetics of poly(3-hexylthiophene) journal January 2017
Redox-Active Polymers for Energy Storage Nanoarchitectonics journal December 2017
X-Ray Scattering Reveals Ion-Induced Microstructural Changes During Electrochemical Gating of Poly(3-Hexylthiophene) journal September 2018
Controlling the Doping Mechanism in Poly(3-hexylthiophene) Thin-Film Transistors with Polymeric Ionic Liquid Dielectrics journal October 2019
Recent advancements in rational design of non-aqueous organic redox flow batteries journal January 2020
Semiconducting π-Conjugated Systems in Field-Effect Transistors: A Material Odyssey of Organic Electronics journal November 2011
Chemical Redox Agents for Organometallic Chemistry journal January 1996
Polymer-Based Organic Batteries journal August 2016