Role of Transition Metals in Pt Alloy Catalysts for the Oxygen Reduction Reaction

Lim, Chaewon; Fairhurst, Alasdair R.; Ransom, Benjamin J.; Haering, Dominik; Stamenkovic, Vojislav R.

doi:10.1021/acscatal.3c03321

Title: Role of Transition Metals in Pt Alloy Catalysts for the Oxygen Reduction Reaction

Journal Article · 03 November 2023 · ACS Catalysis

DOI: https://doi.org/10.1021/acscatal.3c03321 · OSTI ID:2204754

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^[1]; Ransom, Benjamin J. ^[1];

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University of California, Irvine, CA (United States)

In pursuit of higher activity and stability of electrocatalysts toward the oxygen reduction reaction, it has become standard practice to alloy platinum in various structural configurations. Transition metals have been extensively studied for their ability to tune catalyst functionality through strain, ligand, and ensemble effects. The origin of these effects and potential for synergistic application in practical materials have been the subject of many theoretical and experimental analyses in recent years. Here, a comprehensive overview of these phenomena is provided regarding the impact on reaction mechanisms and kinetics through combined experimental and theoretical approaches. Experimental approaches to electrocatalysis are discussed.

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Research Organization:: Univ. of California, Irvine, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Hydrogen Fuel Cell Technologies Office (HFTO); USDOE

OSTI ID:: 2204754

Alternate ID(s):: OSTI ID: 2470341

Journal Information:: ACS Catalysis, Vol. 13, Issue 22; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
chemistry
electrocatalysis
oxygen reduction reaction
platinum alloy
transition metal
ligand effect
strain effect
surface science
spectroscopy
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dissolution
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Title: Role of Transition Metals in Pt Alloy Catalysts for the Oxygen Reduction Reaction

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