Simulation of Impedance Changes with Aging in Lithium Titanate-based Cells Using Physics-Based Dimensionless Modeling

Mallarapu, Anudeep; Santhanagopalan, Shriram; Uno, Wataru; Kanai, Yuta; Uemura, Yohei; Yagi, Ryosuke; Uchikoga, Shuichi

doi:10.1149/1945-7111/acf52a

Title: Simulation of Impedance Changes with Aging in Lithium Titanate-based Cells Using Physics-Based Dimensionless Modeling

Journal Article · 13 September 2023 · Journal of the Electrochemical Society

DOI: https://doi.org/10.1149/1945-7111/acf52a · OSTI ID:2204026

^[1]; Santhanagopalan, Shriram ^[1]; Uno, Wataru ^[2]; Kanai, Yuta ^[2];

^[2]; Yagi, Ryosuke ^[2]; Uchikoga, Shuichi ^[2]

National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Toshiba Corporation (Japan)

Quantifying aging effects in lithium-ion cells with chemistries that have a flat open circuit potential is challenging. We implement a physics-based electrochemical model to track changes in the electrochemical impedance response of lithium titanate-based cells. Frequency domain equations of a pseudo two-dimensional model are made dimensionless, and the corresponding non-dimensional parameters are estimated using a Levenberg-Marquardt routine. The model weighs the relative contributions of changes in diffusion, ionic conduction within the electrolyte phase against solid phase electronic conduction towards cell aging. Solid-phase diffusion, charge transfer resistance and double layer capacitance at the solid-liquid interface are accounted for in the particle impedance. The estimation routine tracks dimensionless parameters using accelerated cycling data from full cells over 1000 cycles. The model can be deployed within a short time for state estimation using physics-based models without requiring prior knowledge of the battery chemistry, format, or capacity.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 2204026

Report Number(s):: NREL/JA--5700-87885; MainId:88660; UUID:4e5105cb-e078-4509-b29b-b8b992cbe48f; MainAdminID:70964

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 9 Vol. 170; ISSN 0013-4651

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

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