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Title: Tellurolate: an effective Te-atom transfer reagent to prepare the triad of group 5 metal bis(tellurides)

Journal Article · · Chemical Science
DOI: https://doi.org/10.1039/D3SC03470D · OSTI ID:2203307
 [1];  [2]; ORCiD logo [3]; ORCiD logo [3]; ORCiD logo [1];  [1];  [1]; ORCiD logo [4]; ORCiD logo [3]; ORCiD logo [1]
  1. Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104, USA
  2. Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea, Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS), Daejeon 34141, Republic of Korea
  3. Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York 14853, USA
  4. Center for Catalytic Hydrocarbon Functionalizations, Institute for Basic Science (IBS), Daejeon 34141, Republic of Korea, Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea
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We show in this work how lithium tellurolate Li(X) n TeCH 2 SiMe 3 (X = THF, n = 1, 1; X = 12- crown -4, n = 2, 2), can serve as an effective Te-atom transfer reagent to all group 5 transition metal halide precursors irrespective of their oxidation state.

Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-76SF00515
OSTI ID:
2203307
Alternate ID(s):
OSTI ID: 2471729
Journal Information:
Chemical Science, Journal Name: Chemical Science Journal Issue: 43 Vol. 14; ISSN 2041-6520; ISSN CSHCBM
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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New reagents for the synthesis of compounds containing metal-tellurium bonds: sterically hindered silyltellurolate derivatives and the x-ray crystal structures of [(THF)2LiTeSi(SiMe3)3]2 and [(12-crown-4)2Li][TeSi(SiMe3)3] journal June 1992
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Ditelluride, Terminal Tellurido, and Bis(tellurido) Motifs of Titanium journal July 2022
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