Synthesis of fluorinated aminium cations coupled with carborane anions for use as strong one-electron oxidants

Davidson, Jillian J.; Gunther, S. Olivia; Leong, Derek W.; Ozerov, Oleg V.

doi:10.1039/D3DT02127K

Title: Synthesis of fluorinated aminium cations coupled with carborane anions for use as strong one-electron oxidants

Journal Article · 06 November 2023 · Dalton Transactions

DOI: https://doi.org/10.1039/D3DT02127K · OSTI ID:2202863

Davidson, Jillian J. ^[1]; Gunther, S. Olivia ^[1]; Leong, Derek W. ^[1];

^[1]

Department of Chemistry, Texas A&M University, College Station, TX 77842, USA

Synthesis of a series of hydrocarbon-soluble triarylamines bearing F, CF ₃ , and Br substituents showing quasi-reversible redox events in the 0.59–1.32 V range is reported. A few have been isolated as [HCB ₁₁ Cl ₁₁ ] ⁻ salts.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; SC0023280

OSTI ID:: 2202863

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 43 Vol. 52; ISSN 1477-9226; ISSN ICHBD9

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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