Role of Transition Metals in Metal–Organic Frameworks as Nanoporous Ion Emitters for Thermal Ionization Mass Spectrometry

Barpaga, Dushyant; Seo, Ji-Hye; Kumar, Abhishek; Makovsky, Kyle A.; Sinnwell, Michael A.; Krogstad, Eirik J.; McHugh, Kelly

doi:10.1021/acsami.3c09902

Title: Role of Transition Metals in Metal–Organic Frameworks as Nanoporous Ion Emitters for Thermal Ionization Mass Spectrometry

Journal Article · 18 September 2023 · ACS Applied Materials and Interfaces

DOI: https://doi.org/10.1021/acsami.3c09902 · OSTI ID:2008201

^[1]; Seo, Ji-Hye ^[1]; Kumar, Abhishek ^[1]; Makovsky, Kyle A. ^[1]; Sinnwell, Michael A. ^[2]; Krogstad, Eirik J. ^[1];

^[1]

Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
University of Iowa, Iowa City, Iowa (United States)

Thermal ionization mass spectroscopy (TIMS) is a powerful analytical technique that allows for precise determination of isotopic ratios. Analysis on low abundance samples, however, can be limited by the ionization efficiency. Following an investigation into a new type of metal-organic hybrid material devised to promote the emission of analyte ions (nano-PIES) and reduce traditional sample loading problems, this work probes the impact that changing the metal in the material has on the ionization of Uranium-238. Being derived from metal-organic frameworks (MOFs), nano-PIEs inherit the tunability of the parent MOFs; the MOF-74 series has been well studied for probing the impact various framework metals (i.e., Mg, Mn, Co, Ni, Cu, Zn, and Cd) have on material properties, and thus, a series of nano-PIEs with different metals were derived from an isoreticular MOF-74 series. In conclusion, trends in ionization efficiency were studied as a function of ionization potential, volatility, and work function of the framework metals as well as the mechanism of ionization.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA), Office of Defense Nuclear Nonproliferation

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 2008201

Report Number(s):: PNNL-SA-183419

Journal Information:: ACS Applied Materials and Interfaces, Vol. 15, Issue 38; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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