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Title: The influence of processing methods on creep of wrought and additively manufactured CrCoNi multi-principal element alloys

Journal Article · · Acta Materialia
ORCiD logo [1]; ORCiD logo [2];  [3];  [2];  [4]; ORCiD logo [1]
  1. Univ. of California, Davis, CA (United States)
  2. Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Center for Electron Microscopy and Molecular Foundry; Univ. of California, Berkeley, CA (United States)
  3. NASA Glenn Research Center, Cleveland, OH (United States)
  4. Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

The influence of vacuum arc melting and mechanical processing (wrought) versus additive manufacturing (AM) on the creep behavior of multi-principal element alloys (MPEA) is investigated in this study. Annealed wrought and hot isostatically pressed (HIP) AM CrCoNi were creep tested under constant tensile stress of 40 to 200 MPa at temperatures of 1023 to 1173 K. Stress exponents of 4.5 ± 0.2 and 5.9 ± 0.1 and activation energies ranging from 240 to 259 and 320 to 331 kJ/mol were found for wrought and AM CrCoNi, respectively. The results indicate that the AM material exhibits superior creep resistance and inferior creep ductility compared to the wrought alloy. This difference is attributed to the AM material having a higher percentage of Cr-rich oxides, a smaller total low angle grain boundary (LAGB) length on a percentage basis, and a greater total twin boundary (TB) length on a percentage basis. The AM and wrought materials have similar grain sizes; however, the smaller LAGB length and greater TB length in the AM material reduce slip transmission on the other side of the boundaries and contribute to strength. The dislocation structures of the AM and wrought materials consist of individual curved dislocations with dislocation multijunctions and jogs, which is similar to the arrangements previously observed in CrMnFeCoNi.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF); National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-05CH11231; DMR-1725618; AC02–05CH11231
OSTI ID:
2007693
Alternate ID(s):
OSTI ID: 2473030
Journal Information:
Acta Materialia, Vol. 261; ISSN 1359-6454
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (54)

Mechanical behavior of crystalline solids at elevated temperature journal January 1968
Flow stress, subgrain size, and subgrain stability at elevated temperature journal June 1977
Achieving ultra-high strength and ductility in equiatomic CrCoNi with partially recrystallized microstructures journal February 2019
Tensile properties of high- and medium-entropy alloys journal August 2013
The influences of temperature and microstructure on the tensile properties of a CoCrFeMnNi high-entropy alloy journal September 2013
Effect of fabrication methods on microstructures, mechanical properties and strengthening mechanisms of Fe0.25CrNiAl medium-entropy alloy journal December 2021
Understanding creep mechanisms of a Cu-Cr-Nb alloy by testing under constant structure conditions journal January 2021
On the strength of discontinuous silicon carbide reinforced aluminum composites journal January 1986
Effect of a minor titanium addition on the superplastic properties of a CoCrFeNiMn high-entropy alloy processed by high-pressure torsion journal March 2018
A Criterion for Ductile Fracture by the Growth of Holes journal June 1968
Analysis of strengthening due to grain boundaries and annealing twin boundaries in the CrCoNi medium-entropy alloy journal January 2020
High temperature creep of Ni-20Cr-2ThO2 single crystals journal May 1976
Hardened austenite steel with columnar sub-grain structure formed by laser melting journal February 2015
Critical stress for twinning nucleation in CrCoNi-based medium and high entropy alloys journal May 2018
Creep properties of an extruded copper–8% chromium–4% niobium alloy journal March 2004
Microstructural evolution after thermomechanical processing in an equiatomic, single-phase CoCrFeMnNi high-entropy alloy with special focus on twin boundaries journal November 2014
Review of Trace Element Effects on High-Temperature Fracture of Fe- and Ni-Base Alloys journal June 1998
Continuous cavity nucleation and creep fracture journal January 1983
Exceptional damage-tolerance of a medium-entropy alloy CrCoNi at cryogenic temperatures journal February 2016
A precipitation-hardened high-entropy alloy with outstanding tensile properties journal January 2016
Direct observations of defects in quenched gold journal January 1959
Bypassing of dislocations past particles by a climb mechanism journal June 1973
Influence of compositional complexity on interdiffusion in Ni-containing concentrated solid-solution alloys journal March 2018
The evolution of the deformation substructure in a Ni-Co-Cr equiatomic solid solution alloy journal June 2017
Effect of matrix hardness on the creep properties of a 12CrMoVNb steel journal September 1999
Intermediate-Temperature Creep Deformation and Microstructural Evolution of an Equiatomic FCC-Structured CoCrFeNiMn High-Entropy Alloy journal December 2018
Effects of Al and Ti Additions on Irradiation Behavior of FeMnNiCr Multi-Principal-Element Alloy journal October 2019
On the creep rate stress dependence of particle strengthened alloys journal June 1986
Recovery, recrystallization, grain growth and phase stability of a family of FCC-structured multi-component equiatomic solid solution alloys journal March 2014
Effect of annealing on the microstructure and texture of cold rolled CrCoNi medium-entropy alloy journal October 2018
Plasticity induced by nanoindentation in a CrCoNi medium-entropy alloy studied by accurate electron channeling contrast imaging revealing dislocation-low angle grain boundary interactions journal June 2021
Design, phase equilibria, and coarsening kinetics of a new γ/γ′ precipitation-hardened multi-principal element alloy journal November 2021
Mechanisms of creep deformation in a rapidly solidified Al–Fe–V–Si alloy journal February 2021
Creep Deformation of Dispersion-Strengthened Copper journal May 1996
Tensile creep behavior of an equiatomic CoCrNi medium entropy alloy journal June 2020
High-temperature oxidation behaviour of CoCrNi medium-entropy alloy journal August 2020
Tensile creep properties of a CrMnFeCoNi high-entropy alloy journal March 2021
The role of low angle grain boundary in deformation of titanium and its size effect journal April 2019
Cantor-derived medium-entropy alloys: bridging the gap between traditional metallic and high-entropy alloys journal March 2022
Oxide dispersion strengthened CoCrFeNiMn high-entropy alloy journal March 2017
Effects of cold-rolling and subsequent annealing on the nano-mechanical and creep behaviors of CrCoNi medium-entropy alloy journal April 2022
Efficient production of a high-performance dispersion strengthened, multi-principal element alloy journal June 2020
Steady state flow of the FeCoNiCrMn high entropy alloy at elevated temperatures journal December 2014
On the theory of normal and abnormal grain growth journal March 1965
The creep and fracture properties of additively manufactured inconel 625 journal March 2021
Reasons for the superior mechanical properties of medium-entropy CrCoNi compared to high-entropy CrMnFeCoNi journal April 2017
A high-entropy alloy with hierarchical nanoprecipitates and ultrahigh strength journal October 2018
Creep cavitation in metals journal October 2003
A new model-based creep equation for dispersion strengthened materials journal April 1990
Influence of annealing on the creep behavior of GlidCop Al-15 journal March 2020
Nucleation and growth of cavities at defined grain boundaries in bicrystals journal March 1990
High Temperature Creep Behavior of SiC/2124Al Metal Matrix Composites journal July 1995
Microstructure evolution and critical stress for twinning in the CrMnFeCoNi high-entropy alloy journal October 2016
Overview no. 65 journal March 1988