DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Hydrogen evolution catalysis by a cobalt porphyrin peptide: A proposed role for porphyrin propionic acid groups

Journal Article · · Journal of Inorganic Biochemistry

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0002106
OSTI ID:
2007671
Journal Information:
Journal of Inorganic Biochemistry, Journal Name: Journal of Inorganic Biochemistry Vol. 249 Journal Issue: C; ISSN 0162-0134
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (59)

USE OF GLASS ELECTRODES TO MEASURE ACIDITIES IN DEUTERIUM OXIDE 1,2 journal January 1960
Molecular Structures and Magnetic Resonance Spectroscopic Investigations of Highly Distorted Six-Coordinate Low-Spin Iron(III) Porphyrinate Complexes journal June 2001
Biological Significance and Applications of Heme c Proteins and Peptides journal June 2015
The preparation of N-acetyl-Co(III)-microperoxidase-8 (NAcCoMP8) and its ligand substitution reactions: A comparison with aquacobalamin (vitamin B12a) journal June 2013
Proton Relay in Iron Porphyrins for Hydrogen Evolution Reaction journal June 2021
Proton-coupled electron transfer kinetics for the hydrogen evolution reaction of hangman porphyrins journal January 2012
Multidisciplinary approaches to solar hydrogen journal June 2015
Hydrogen Generation by Hangman Metalloporphyrins journal June 2011
The Dark Side of Molecular Catalysis: Diimine–Dioxime Cobalt Complexes Are Not the Actual Hydrogen Evolution Electrocatalyst in Acidic Aqueous Solutions journal May 2016
Proton-Coupled Electron Transfer journal April 2012
Cobaloximes as Functional Models for Hydrogenases. 2. Proton Electroreduction Catalyzed by Difluoroborylbis(dimethylglyoximato)cobalt(II) Complexes in Organic Media journal March 2007
Modulating the mechanism of electrocatalytic CO2 reduction by cobalt phthalocyanine through polymer coordination and encapsulation journal April 2019
[Ni(P Ph 2 N C6H4X 2 ) 2 ] 2+ Complexes as Electrocatalysts for H 2 Production: Effect of Substituents, Acids, and Water on Catalytic Rates journal April 2011
Power of the Secondary Sphere: Modulating Hydrogenase Activity in Nickel-Substituted Rubredoxin journal August 2019
Inclusion of Peripheral Basic Groups Activates Dormant Cobalt-Based Molecular Complexes for Catalytic H 2 Evolution in Water journal January 2019
Enzyme-Inspired Synthetic Proton Relays Generate Fast and Acid-Stable Cobalt-Based H2 Production Electrocatalysts journal September 2019
Use of the glass electrode in deuterium oxide and the relation between the standardized pD (paD) scale and the operational pH in heavy water journal April 1968
Homogeneous Catalysis for Sustainable Energy: Hydrogen and Methanol Economies, Fuels from Biomass, and Related Topics journal November 2021
Assignment of the ferriheme resonances of high- and low-spin forms of the symmetrical hemin-reconstituted nitrophorins 1–4 by 1H and 13C NMR spectroscopy: the dynamics of heme ruffling deformations journal May 2008
Increasing the rate of the hydrogen evolution reaction in neutral water with protic buffer electrolytes journal December 2020
Protein secondary-shell interactions enhance the photoinduced hydrogen production of cobalt protoporphyrin IX journal January 2014
Tuning the reactivity of cobalt-based H2 production electrocatalysts via the incorporation of the peripheral basic functionalities journal August 2020
Linear Free Energy Relationships in Hydrogen Evolution Catalysis by a Cobalt Tripeptide in Water journal May 2021
A molecular mediator for reductive concerted proton-electron transfers via electrocatalysis journal August 2020
Molecular Cobalt Complexes with Pendant Amines for Selective Electrocatalytic Reduction of Carbon Dioxide to Formic Acid journal March 2017
Powering the planet with solar fuel journal April 2009
Beyond the Active Site: The Impact of the Outer Coordination Sphere on Electrocatalysts for Hydrogen Production and Oxidation journal June 2014
Engineered Enzymes and Bioinspired Catalysts for Energy Conversion journal August 2019
Buffer p K a Impacts the Mechanism of Hydrogen Evolution Catalyzed by a Cobalt Porphyrin-Peptide journal May 2020
Tuning Mechanism through Buffer Dependence of Hydrogen Evolution Catalyzed by a Cobalt Mini-enzyme journal March 2020
Theoretical Analysis of Cobalt Hangman Porphyrins: Ligand Dearomatization and Mechanistic Implications for Hydrogen Evolution journal November 2014
Electrocatalytic Hydrogen Evolution under Acidic Aqueous Conditions and Mechanistic Studies of a Highly Stable Molecular Catalyst journal July 2016
Determining Proton-Coupled Standard Potentials and X–H Bond Dissociation Free Energies in Nonaqueous Solvents Using Open-Circuit Potential Measurements journal May 2020
Minimal Proton Channel Enables H 2 Oxidation and Production with a Water-Soluble Nickel-Based Catalyst journal November 2013
Activating the Fe(I) State of Iron Porphyrinoid with Second-Sphere Proton Transfer Residues for Selective Reduction of CO 2 to HCOOH via Fe(III/II)–COOH Intermediate(s) journal August 2021
Linear Free Energy Relationships in the Hydrogen Evolution Reaction: Kinetic Analysis of a Cobaloxime Catalyst journal April 2016
Amine Groups in the Second Sphere of Iron Porphyrins Allow for Higher and Selective 4e/4H+ Oxygen Reduction Rates at Lower Overpotentials journal February 2023
Hydrogen Evolution from Neutral Water under Aerobic Conditions Catalyzed by Cobalt Microperoxidase-11 journal December 2013
Probing Protein Folding with Substitution-Inert Metal Ions. Folding Kinetics of Cobalt(III)-Cytochrome c journal December 1999
Solar fuels generation and molecular systems: is it homogeneous or heterogeneous catalysis? journal January 2013
Artificial hydrogenases: biohybrid and supramolecular systems for catalytic hydrogen production or uptake journal April 2015
Mimicking hydrogenases: From biomimetics to artificial enzymes journal July 2014
Decoding Proton-Coupled Electron Transfer with Potential–p K a Diagrams journal January 2017
Enhanced Photocatalytic Hydrogen Production by Hybrid Streptavidin‐Diiron Catalysts journal April 2020
Update 1 of: Electrochemical Approach to the Mechanistic Study of Proton-Coupled Electron Transfer journal December 2010
Photochemical hydrogen evolution from cobalt microperoxidase-11 journal April 2021
Proton Relays in Molecular Catalysis of Electrochemical Reactions: Origin and Limitations of the Boosting Effect journal February 2019
Homogeneous Molecular Catalysis of Electrochemical Reactions: Manipulating Intrinsic and Operational Factors for Catalyst Improvement journal November 2018
Homogeneous redox catalysis of electrochemical reaction journal August 1984
Molecular Catalysis of H 2 Evolution: Diagnosing Heterolytic versus Homolytic Pathways journal September 2014
Resolution of Key Roles for the Distal Pocket Histidine in Cytochrome c Nitrite Reductases journal February 2015
Recent progress on metalloporphyrin-based hydrogen evolution catalysis journal May 2020
Electrocatalytic Hydrogen Evolution with a Cobalt Complex Bearing Pendant Proton Relays: Acid Strength and Applied Potential Govern Mechanism and Stability journal November 2019
Use of Platinum as the Counter Electrode to Study the Activity of Nonprecious Metal Catalysts for the Hydrogen Evolution Reaction journal April 2017
Light‐driven catalysis with engineered enzymes and biomimetic systems journal July 2020
Potential- and Buffer-Dependent Selectivity for the Conversion of CO2 to CO by a Cobalt Porphyrin-Peptide Electrocatalyst in Water journal November 2022
PROTON-COUPLED ELECTRON TRANSFER: A Reaction Chemist's View journal June 2004
Controlling a burn: outer-sphere gating of hydroxylamine oxidation by a distal base in cytochrome P460 journal January 2019
Artificial photosynthesis: opportunities and challenges of molecular catalysts journal January 2019